Tag: M.W=200-250

Williams, D. Lyn H. published the artcileS-Nitrosation of thiourea and thiocyanate ion. Nitrosyl thiocyanate and the S-nitroso-adduct of thiourea as nitrosating agents, Application In Synthesis of 14807-75-1, the publication is Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999) (1977), 128-32, database is CAplus.

The reaction between H2NCSNH2 (I) and PhN(Me)NO (II) in aqueous acid solution gave PhNHMe (III) and a S-nitroso intermediate (IV) which decomposed to form [(H2N)2C+S]2. The latter two products are the same as those from the reaction of I and HNO2. The nitrosoamine reaction was acid-catalyzed and was first order in both I and II. Added III reduced the reaction rate, showing that the formation of IV was reversible, i.e. it was capable of acting directly as a nitrosating agent. The reactivities (relative to III) of ‘various nitrite’ traps (NH3, H2NN+H3, H2NSO3H, H3N+OH, urea) towards IV were determined, the order of reactivity was the same as for the nitrosating agents NOCl, NOBr, and H2N+O2, but discrimination by IV was greater than for these, implying that IV is a less reactive species. Rate constant ratios obtained for NOSCN are similar to those of IV suggesting that they have almost the same reactivity as nitrosating agents.

Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999) published new progress about 14807-75-1. 14807-75-1 belongs to ethers-buliding-blocks, auxiliary class Salt,Thiourea,Amine,Aliphatic hydrocarbon chain, name is Formamidine disulfide dihydrochloride, and the molecular formula is C8H11BO2, Application In Synthesis of 14807-75-1.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem

Yeh, S. Y. published the artcileN-depyridination and N-dedimethylaminoethylation of tripelennamine and pyrilamine in the rat. New metabolic pathways, Application In Synthesis of 52818-63-0, the publication is Drug Metabolism and Disposition (1990), 18(4), 453-61, database is CAplus and MEDLINE.

N-(2-Dimethylaminoethyl)benzylamine and 2-benzylaminopyridine were identified as two new urinary metabolites of tripelennamine in the rat by GC/MS. 2-(4-Methoxybenzylamino)-pyridine and N-(dimethylaminoethyl)-4-hydroxybenzylamine were identified as new urinary metabolites of pyrilamine by GC/MS. Thus, in addition to N– and O-demethylation, hydroxylation, and glucuronidation, N-debenzylation, N-depyridination and N-dedimethylaminoethylation were shown to be novel pathways for metabolism of tripelennamine and pyrilamine. The mechanism for N-depyridination and N-dealkylation is discussed.

Drug Metabolism and Disposition published new progress about 52818-63-0. 52818-63-0 belongs to ethers-buliding-blocks, auxiliary class Pyridine,Amine,Benzene,Ether, name is N-(4-Methoxybenzyl)pyridin-2-amine, and the molecular formula is C3H5F3O, Application In Synthesis of 52818-63-0.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem

Glicksman, R. published the artcileInvestigation of the electrochemical characteristics of organic compounds. X. Sulfur compounds, Computed Properties of 14807-75-1, the publication is Journal of the Electrochemical Society (1963), 353-7, database is CAplus.

cf. CA 57, 7002d. Anodic half-cell potential discharge data are presented for various classes of organic S compounds, such as the thiophenols, mercaptans, and thioureas in alk. electrolyte. The effect of group substitution and aromaticity on the anode potential of the thiophenol compounds is interpreted in terms of the electron d. distribution in the mol. Half-cell potential discharge data for the reversible thiourea-formamidine disulfide and dithiobiuret-thiuret systems in different electrolytes of varying pH are also presented.

Journal of the Electrochemical Society published new progress about 14807-75-1. 14807-75-1 belongs to ethers-buliding-blocks, auxiliary class Salt,Thiourea,Amine,Aliphatic hydrocarbon chain, name is Formamidine disulfide dihydrochloride, and the molecular formula is C2H8Cl2N4S2, Computed Properties of 14807-75-1.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem

Horlein, Ulrich published the artcileTetrahydrocarboline compounds. I., Synthetic Route of 52818-63-0, the publication is Chemische Berichte (1954), 463-72, database is CAplus.

Several 9-substituted tetrahydro-β- and -γ-carbolines were prepared; some had good antihistamine characteristics. PhCH₂PhNNH₂ (99 g.), 81 g. H₂N(CH₂)₃CH(OEt)₂, and 80 g. anhydrous ZnCl₂ heated 3 h. at 180° gave 40-50% 1-benzyltryptamine (I), b_0.2 194-202°; maleate, C₂₁H₂₂N₂O₄, m. 161-2°. I (40 g.) in 82 cc. 2N HCl and 2.5 l. H₂O and 60 g. AcH, heated 1.5 h. at 90-5°, treated with K₂CO₃, and extracted with Et₂O, gave 34% 1-methyl-9-benzyl-1,2,3,4-tetrahydro-β-carboline (II), b₃ 230-40°. II (27.6 g.) in 25 cc. MeOH treated dropwise at 10° with 450 cc. 95% HCO₂H, left 5-6 h. at room temperature, heated on a water bath, HCO₂Me distilled, the b.p. elevated to 90°, and HCO₂H evaporated in vacuo, gave 76% 1,2-dimethyl-9-benzyl-1,2,3,4-tetrahydro-β-carboline, b_0.5 205-15°; picrate, m. 197° (from HOAc). 1-Methyl-1,2,3,4-tetrahydro-β-carboline (III) was converted with HCHO and HCO₂H to 63.5% 1,2-di-Me analog (IIIa), b_1.5 180-90°, m. 116° (from ligroine). IIIa (20 g.) was boiled 1-2 h. with 4.5 g. PhMe-moistened NaNH₂ in 150 cc. xylene, treated dropwise with 10.8 g. ClCH₂CH₂NMe₂ in xylene, boiled 1-2 h., cooled, extracted with dilute HCl, the aqueous solution made alk. with NaOH, extracted with Et₂O, and the extract distilled giving 59% 1,2-dimethyl-9-(β-dimethylaminoethyl)-1,2,3,4-tetrahydro-β-carboline, b_1.5 205-15°; naphthalene-1,5-disulfonate, monohydrate, C₂₇H₃₃N₃O₆S₂.H₂O, m. 265° (from dilute MeOH-Me₂CO). 9-Substituted 3-methyl-1,2,3,4-tetrahydro-γ-carboline derivatives (IV) were prepared from 1-methyl-4-piperidone (V) and N-substituted phenylhydrazines, RArNNH₂ (VI). MeN(CH₂CH₂CO₂Me)₂ (609 g.) was poured into a solution of 69 g. Na in 1.3 l. MeOH, the MeOH distilled in vacuo, the mixture heated at 110-20°/3-5 mm., the Na salt of Me 1-methyl-4-oxo-3-piperidinecarboxylate dissolved in 900 g. concentrated H₂SO₄ in 2.5 l. H₂O and refluxed 2-3 h. (to decarboxylate), a solution of 255 g. PhCH₂PhNNH₂ (VIa) in 115 g. concentrated H₂SO₄ and 2.3 l. H₂O (which had been clarified with C) added quickly, the mixture refluxed 3-4 h., H₂O added to give 8-9 l. volume, and 69% 3-methyl-9-benzyl-1,2,3,4-tetrahydro-γ-carboline (IVa) (IV, R = PhCH₂, Z = H), b_0 5 205-12°, m. 95° (from ligroine), precipitated as the sulfate; dissolved in MeOH and treated with naphthalene-1,5-disulfonic acid gave the naphthalene-1,5-disulfonate, C₄₈H₄₈N₄O₆S₂ m. 280° (from HCONH₂); HCl salt, m. 235-7° (from alc.). Other IV prepared were (R, Z, % yield, b.p., m.p., salt, and method of isolation of IV given): Ph, H, 62, b_1.5 214-25°, 101.5-2.5° (from ligroine), -, distillation of base; Bu, H, over 60, b_1.5 196-204°, -, maleate [m. 148-9° (from H₂O)], distillation; EtSCH₂CH₂, H, about 70, b₁ 190-206°, -, maleate [m. 138° (from alc.-Et₂O)], distillation; α-pyridylmethyl, H, 60, -, -, di-HCl salt [m. 140-1° (from alc.-Et₂O)], precipitation of HCl salt; PhCH₂, 7(?)-MeO, about 45, -, -, maleate [m. 168° (from alc.-Et₂O)], precipitation of naphthalene-1,5-disulfonate from crude base in 8:2 Me₂CO-MeOH and conversion to maleate; PhCH₂, 7(?)-Cl (IVb), 45-55, -, 139-41°, HCl salt [m. 276° (from H₂O)], naphthalene-1,5-disulfonate [m. 209-11° (from MeOH)], precipitation as HCl salt; EtOCH₂CH₂, H, 60-70, b_0.5 170-80°, -, maleate [m. 141-2° (from alc.-Et₂O)], distillation; Me₂CHOCH₂CH₂, H, 68, b_0.1 165-75°, -, maleate [m. 175-6° (from alc.)], HCl salt [m. 172-4° (from alc.-Et₂O)], distillation; BuOCH₂CH₂, H, 68, -, -, naphthalene-1,5-disulfonate [m. 234° (from alc.-Me₂CO)], precipitation of the naphthalenedisulfonate from base in Me₂CO; Me₂CHCH₂OCH₂CH₂, H, 60-70, -, -, naphthalene-1,5-disulfonate [m. 235-6° (from alc.-Me₂CO)], precipitation of the salt from the base in Me₂CO; PhCH₂, 6-Cl, 65, b_0.1 205-7°, -, methanesulfonate [m. 198-9° (from MeOH-Et₂O, precipitated in EtOAc)], distillation; p-ClC₆H₄CH₂, H, about 70, b₁ 208-15°, 108° (from ligroine), -, distillation; cyclohexyl, H, 59, -, -, HCl salt [m. 251° (from H₂O)], precipitation of HCl salt; PhCH₂CH₂, H, 63, -, -, HCl salt [m. 209-10° (from alc.-Et₂O)], precipitation of HCl salt; PrOCH₂CH₂, H, 70, b_0.5 172-85°, -, maleate [m. 144° (from alc.-Et₂O)], distillation; Me, H, 71, b₃ 174°, 69-70° (from ligroine), maleate [m. 174° (from alc.-Et₂O)], distillation; PhCH₂, 7(?)-Br (IVc), 40-5, -, -, naphthalene-1,5-disulfonate (m. 222-4°), precipitation of HCl salt; cyclohexyloxyethyl, H, 64, -, -, maleate [m. 133° (from alc.-Et₂O)], HCl salt [m. 209-10° (from alc.-Et₂O)], precipitation of the maleate from crude base in EtOAc; PhOCH₂CH₂, H, 60-70, -, 129°, -, recrystallization of base from ligroine; p-ClC₆H₄CH₂, 6-Cl, 72, -, 123-4° (from ligroine), methanesulfonate [m. 195-6° (from alc.)], precipitation of HCl salt; PhCH₂, 5(?)-Cl (IVd) 10-20, -, 112° (from ligroine), naphthalene-1,5-disulfonate (m. about 300°), crystallization of salt on addition of MeOH and naphthalenedisulfonic acid to alc.-HCl mother liquor of IVb; PhCH₂, 5(?)-Br, about 20, -, -, naphthalene-1,5-disulfonate (m. 303°), treatment of the mother liquor of IVc as for IVd; p-ClC₆H₄CH₂, 7(?)-Cl, about 55, -, -, HCl salt [m. 280-2° (from H₂O)], precipitation of HCl salt. The following new VI and RArNH (VII) were prepared (R, Ar, and b.ps. of VI and VII, resp., given): EtSCH₂CH₂, Ph, b₈ 173-80°, b₂₀ 165-75°; α-pyridylmethyl, Ph, b_2-3 165-75°, b₈ 168-72°; PhCH₂, m-MeOC₆H₄, b₆ 192-4°, b₅ 183-7°; PhCH₂, m-ClC₆H₄, b₅ 190-5°, b₅ 182-6°; EtOCH₂CH₂, Ph, b₅ 136-42°, -; Me₂CHOCH₂CH₂, Ph, b₅ 138-45°, b₅ 130-5°; BuOCH₂CH₂, Ph, b_4-5 158-63°, b₅ 150-8°; Me₂CHCH₂OCH₂CH₂, Ph, b₃ 148-56°, b₅ 145-51°; PhCH₂, p-ClC₆H₄, b₄ 187-93°, -; p-ClC₆H₄CH₂, Ph, b_2-3 180-5°, -; PhCH₂CH₂, Ph, b₅ 178-88°, -; PrOCH₂CH₂, Ph, b₄ 134-42°, b₂₀ 156-62°; PhCH₂, m-BrC₆H₄, b_0.1 210-20°, b_0.1 160-8°; cyclohexyloxyethyl, Ph, b₅ 170-85°, b₅ 160-70°; PhOCH₂CH₂, Ph, b₅ 180-92°, -; p-ClC₆H₄CH₂, p-ClC₆H₄, – (methanesulfonate, m. 201°), -; p-ClC₆H₄CH₂, m-ClC₆H₄, b_1.5 218-22°, b₅ 210°. VI were mainly obtained by nitrosation of VII and Zn dust reduction; VIa and p-ClC₆H₄CH₂PhNNH₂ were prepared from PhNHNH₂ and the corresponding benzyl chloride. VII were prepared mainly from RCl or RBr with 2 mol ArNH₂ without a solvent above 100°, but some were obtained by reduction of the corresponding Schiff bases. IV (R = Z = H) (18.6 g.) converted to its Na derivative by boiling 1-2 h. with 4.5 g. PhMe-moistened NaNH₂ in 150 cc. absolute PhMe or xylene, with ClCH₂CH₂NMe₂ added, and the crude base distilled, gave 70% IV (R = Me₂NCH₂CH₂, Z = H), b_2.5 200-5°; maleate, C₂₄H₃₁N₃O₈, m. 164-5° (from MeOH-Et₂O); 73% IV (R = Et₂NCO, Z = H) (VIIa) was similarly obtained using Et₂NCOCl and precipitating from solution in Me₂CO or MeOH as the naphthalene-1,5-disulfonate, m. 265-7° (from HOAc-Me₂CO) [VIIa.HCl, m. 202-3° (from alc.-Et₂O)]. Similar reactions using PhCH₂Cl succeeded poorly or not at all, apparently as the result of extensive quaternization at the 3-position. IVa (27.6 g.) in 250 cc. Me₂CO, refluxed 24 h. with 18 g. PhCH₂Cl, gave 81% 3-methyl-3,9-dibenzyl-1,2,3,4-tetrahydro-γ-carbolinium chloride, m. 211-12° (from alc.-Et₂O); at room temperature IVa treated with 14 g. Me₂SO₄ and the product precipitated by 250 cc. Et₂O gave 90% 3,3-dimethyl-9-benzyl-1,2,3,4-tetrahydro-γ-carbolinium methosulfate, m. 217-18° (from alc.-Et₂O). The Na derivative of 1-methyl-4-imino-3-cyanopiperidine (from 69 g. MeN(CH₂CH₂CN)₂ in PhMe, filtered off under N, and washed with PhMe) was added carefully under CO₂ to 250 g. concentrated H₂SO₄ in 1 l. H₂O, the aqueous layer separated, 35 g. PhNHNH₂, and 100 g. 20% H₂SO₄ added, the mixture refluxed 6-8 h., and made alk. giving C₁₃H₁₆N₄, m. 123° (from C₆H₆), which may be the phenylhydrazone of 1-methyl-3-cyano-4-piperidone or VIII. α-(p-Methoxybenzylamino)pyridine (IX), m. 128°, was converted to the nitroso derivative, m. 56-7° (from ligroine), and reduced with Zn dust; some IX was recovered from the concentrated Et₂O extracts by precipitation with ligroine and crude N,N-(p-methoxybenzyl)-α-pyridylhydrazine (X) was obtained by evaporation of the filtrate. X (20 g.) in 120 cc. alc. was treated in the cold with HCl, 14 g. V.HCl added, the mixture heated slightly on the water bath, then 2-3 h. at 70-80°, and Me₂CO added to precipitate 5 g. V α-pyridylhydrazone-HCl, m. 224-5° (from MeOH-Me₂CO); this was converted through the free base to the dimaleate, m. 142-3° (from alc. Et₂O), and the dipicrate, m. 202-3° (from 90% HOAc-Et₂O).

Chemische Berichte published new progress about 52818-63-0. 52818-63-0 belongs to ethers-buliding-blocks, auxiliary class Pyridine,Amine,Benzene,Ether, name is N-(4-Methoxybenzyl)pyridin-2-amine, and the molecular formula is C13H14N2O, Synthetic Route of 52818-63-0.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem

Kishida, Yoshikazu published the artcileDepigmentation of planarian eye treated with salts of dithiocarbamide and related chemicals, Synthetic Route of 14807-75-1, the publication is Sci. Repts. Kanazawa Univ. (1961), 7(No. 2), 151-7, database is CAplus.

Salts of dithiocarbamide depigment the eye of Euplanaria gonocephala within 4 days. Thiocarbamide, phenylthiocarbamide, and their salts need over 30 days. Cystine, carbamide, guanidine, and monoiodoacetic acid are not effective.

Sci. Repts. Kanazawa Univ. published new progress about 14807-75-1. 14807-75-1 belongs to ethers-buliding-blocks, auxiliary class Salt,Thiourea,Amine,Aliphatic hydrocarbon chain, name is Formamidine disulfide dihydrochloride, and the molecular formula is C2H8Cl2N4S2, Synthetic Route of 14807-75-1.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem

Lozinskii, M. O. published the artcileSynthesis, structure and properties of 1-(p-R-phenacyl)-2-[(p-methoxybenzyl)amino]pyridinium bromides, SDS of cas: 52818-63-0, the publication is Khimiya Geterotsiklicheskikh Soedinenii (1995), 644-9, database is CAplus.

The title salts, obtained by reaction of 2-[(p-methoxybenzyl)amino]pyridine with p-substituted phenacyl bromides, were shown to exist as their cyclic tautomers I (R = H, Me, Cl, Br, NO₂). The chem. shifts of the OH protons in I obeyed an LFER.

Khimiya Geterotsiklicheskikh Soedinenii published new progress about 52818-63-0. 52818-63-0 belongs to ethers-buliding-blocks, auxiliary class Pyridine,Amine,Benzene,Ether, name is N-(4-Methoxybenzyl)pyridin-2-amine, and the molecular formula is C13H14N2O, SDS of cas: 52818-63-0.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem

Ma, Ming-you published the artcileSynthesis of 1-[(2-ethylhexyl)oxy]-4-methoxybenzene under ultrasound conditions, Quality Control of 146370-51-6, the publication is Huaxue Shiji (2006), 28(8), 501-502, database is CAplus.

1-[(2-Ethylhexyl)oxy]-4-methoxybenzene (MOEHOB) was synthesized by the reaction of 4-methoxyphenol (MOPh) with 2-ethylhexyl bromide in argon atm. under supersonic irradiation in the solution of sodium ethoxide. Reaction yields reached 86-88%. The optimum reaction conditions: molar ratio of MOPh/ethylhexyl bromide was 1:1.5, the concentration of sodium ethoxide was 2.5 mol/L, the frequency of the ultrasound was 40 kHz, the reaction time was 5-6 h.

Huaxue Shiji published new progress about 146370-51-6. 146370-51-6 belongs to ethers-buliding-blocks, auxiliary class Benzene,Ether, name is 1-((2-Ethylhexyl)oxy)-4-methoxybenzene, and the molecular formula is C15H24O2, Quality Control of 146370-51-6.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem

Sahasrabudhey, R. H. published the artcileThiocyanamides and sulfonitriles: their constitution and identity, SDS of cas: 14807-75-1, the publication is Journal of the Indian Chemical Society (1950), 524-6, database is CAplus.

Thiocyanamide-HCl (I) was made from “amidothiotriazole” (II) by the Freund and Schander procedure [Ber. 29, 2500(1896)]. Oliveri-Mandalà (C.A. 9, 71) showed the “amidothiotriazoles” were really thiocarbamic acid azides; he made the HCl salts of phenyl-, tolyl-, and ethylthiocarbamic acid azides and the salts of the corresponding thiocyanamides, which he called sulfonitriles. I has saline characteristics, shown by its solubility in H₂O and alc. and insolubility in ether, CHCl₃, CCl₄, and C₆H₆. Aqueous solutions were highly acid because of hydrolysis. The free base could not be isolated, but addition of alkali precipitates S, and thiourea and NH₂CN are formed in solution Thiocyanamide salts liberate iodine from aqueous KI solutions Reduction of I in H₂O with Zn and HCl evolved large quantities of H₂S, and when a portion treated with excess NaOH solution gave no precipitate of S, absence of unreduced thiocyanamide was indicated. The remainder was made ammoniacal, the Zn precipitated as ZnS with H₂S, and filtered; the filtrate on concentration deposited crystals of thiourea in a sirupy residue of NH₂CN. Thiocyanamide salts: nitrate, m. 82° or 140° (decomposition); picrate, m. 154° or 164° (decomposition); HBr salt, m. 185-90° (decomposition); HCl salt, m. 186° (decompose). The m.ps. were identical with, and did not depress, those of the corresponding salts of [H₂NC(:NH)S]₂ (II) (Proc. Indian Sci. Congress, 1948, Pt. III, p. 25). Formation of thiocyanamide from H₂NCSN₃ and the identity of its empirical composition with that of II (HCl salt, CSN₂H₄Cl (?)), the oxidation product of thiourea suggests that they may be identical. The constitution is still being investigated. The aromatic thiocyanamides or sulfonitriles can not be the same as the corresponding formamidine disulfides because the aryl derivatives of the latter are known not to exist, while the free bases from the salts of the former have been made and the mol. weights determined O.-M. (C.A. 17, 738) suggested pentacovalent N structures, which is untenable. Fischer and Besthorn [Ann. 212, 316(1882)] and Hugershoff [Ber. 36, 3134(1903)] say that they are the same as the corresponding 2-aminobenzothiazoles. Comparison of m.ps. given by O.-M. (C.A. 9, 71) with corresponding arylaminothiazoles almost proves identity. Aniline sulfonitrile, C₇H₆N₂S, m. 122-3°, 2-aminobenzothiazole, C₇H₆N₂S, m. 123°; ο-toluidine sulfonitrile, C₈H₈N₂S, m. 138-40°, 2-amino-4-methylbenzothiazole, C₈H₈N₂S, m. 140°.

Journal of the Indian Chemical Society published new progress about 14807-75-1. 14807-75-1 belongs to ethers-buliding-blocks, auxiliary class Salt,Thiourea,Amine,Aliphatic hydrocarbon chain, name is Formamidine disulfide dihydrochloride, and the molecular formula is C2H8Cl2N4S2, SDS of cas: 14807-75-1.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem

Plavich, M. L. published the artcileInformation display devices based on organic luminophors, Product Details of C15H24O2, the publication is Zhurnal Nauchnoi i Prikladnoi Fotografii (2003), 48(3), 52-60, database is CAplus.

The development and properties of light-emitting devices based on the organic luminophors have been studied in the State Research University of Phys. Problems named after F.V. Lukin for more than 7 yr. The development of such devices is a relatively new field of optoelectronics, and some problems which encountered in this field are discussed in the present paper. The description of matrix monochrome indicator having 16×16 pixels size based on the recent studies is given. Exptl. elec. current-potential relationships and elec. current-brightness relationships for different light-emitting materials are considered.

Zhurnal Nauchnoi i Prikladnoi Fotografii published new progress about 146370-51-6. 146370-51-6 belongs to ethers-buliding-blocks, auxiliary class Benzene,Ether, name is 1-((2-Ethylhexyl)oxy)-4-methoxybenzene, and the molecular formula is C15H24O2, Product Details of C15H24O2.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem

Plavich, M. L. published the artcileTechnologies for preparation of stable monochrome displays based on organic electroluminescent materials, Application of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene, the publication is Elektronnaya Promyshlennost (2004), 101-108, database is CAplus.

OLEDs were prepared consisting of an ITO anode, PNAB hole-transport layer, organic luminophor [e.g., Alq₃ or poly(phenylenevinylenes)], and two-layer cathode comprising an Al/Ca alloy (≤10% Ca) and a pure Al layer. Current-voltage (5-6 V threshold) and intensity-current relationships were given.

Elektronnaya Promyshlennost published new progress about 146370-51-6. 146370-51-6 belongs to ethers-buliding-blocks, auxiliary class Benzene,Ether, name is 1-((2-Ethylhexyl)oxy)-4-methoxybenzene, and the molecular formula is C15H24O2, Application of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem