Category: 93-04-9

On August 3, 2022, Caldarelli, Marina; Laze, Loris; Piazza, Lavinia; Caputo, Giulia; De Amici, Marco; Papeo, Gianluca published an article.Computed Properties of 93-04-9 The title of the article was Use of acridinium-based photocatalyst in the Giese-type coupling of arylboronic acids with electron poor olefins. And the article contained the following:

The development of a visible light-mediated Giese-type reaction using arylboronic acids as aryl radical source was described. The synthetic protocol capitalizes on the employment of environmentally benign metal-free catalyst to forge Csp2-Csp3 bonds. Applications of the methodol. to the synthesis of aminoesters and the anti-inflammatory drug nabumetone, either in batch or in flow, was also reported. The experimental process involved the reaction of 2-Methoxynaphthalene(cas: 93-04-9).Computed Properties of 93-04-9

The Article related to alkene arylboronic acid mesityl acridinium photocatalyst giese coupling, aryl alkane preparation green chem, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Hydrocarbons (Saturated and Unsaturated Side Chains) and other aspects.Computed Properties of 93-04-9

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Ether – Wikipedia,
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Wu, Yaxing; Ding, Hongliang; Zhao, Ming; Ni, Zhong-Hai; Cao, Jing-Pei published an article in 2020, the title of the article was Electrochemical and direct C-H methylthiolation of electron-rich aromatics.Synthetic Route of 93-04-9 And the article contains the following content:

The electrochem.-induced C-H methylthiolation of electron-rich aromatics for the synthesis of thiomethylated aromatics ArSR [R = Me, Et, n-Pr; Ar = 4-MeOC6H4, 4-MeNHC6H4, 2-MeO-1-naphthyl, etc.] was accomplished via a three component cross-coupling strategy. Potassium thiocyanate (KSCN) as both the supporting electrolyte and sulfur source and methanol as the methylation reagent were used. This protocol was versatile for various (hetero)aromatic compounds such as aniline, anisole and indole. The reaction proceeded under mild conditions without any metal catalyst, exogenous oxidant and highly toxic sulfur reagent. Importantly, such an electrochem.-induced methylthiolated reaction could be easily scaled up with good efficiency. The experimental process involved the reaction of 2-Methoxynaphthalene(cas: 93-04-9).Synthetic Route of 93-04-9

The Article related to thiomethylated aromatic compound preparation, electron rich aromatic compound electrochem methylthiolation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Hydrocarbons (Saturated and Unsaturated Side Chains) and other aspects.Synthetic Route of 93-04-9

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On July 1, 2022, Zhao, Lanxiao; Deng, Peng; Gong, Xun; Kang, Xiaohui; Cheng, Jianhua published an article.Name: 2-Methoxynaphthalene The title of the article was Regioselective C-H Alkylation of Aromatic Ethers with Alkenes by a Half-Sandwich Calcium Catalyst. And the article contained the following:

The catalytic ortho-regioselective C-H alkylation of a of alkoxy-substituted benzene derivatives with alkenes could be achieved by the use of a half-sandwich calcium alkyl complex [(CpAr5)Ca{CH(SiMe3)2}(THF)] (CpAr5 = C5Ar5, Ar = 3,5-i-Pr-C6H3) as the precatalyst to form 1-alkoxy-2-phenethylbenzene derivatives I [R = H, 4-Me, 4-SMe, etc.; R1 = OMe, OEt, i-Pr, etc.]. The potential catalytic reaction intermediates, half-sandwich calcium anisyl complexes [(CpAr5)Ca(o-MeO-m-Ph-C6H3) (THF)2] and [(CpAr5)Ca(o-MeO-2-Np) (THF)2] (Np = naphthyl), were isolated and X-ray structurally characterized. DFT calculations were carried out to elucidate the different reaction profiles of sp2 and sp3 C-H activations. The experimental process involved the reaction of 2-Methoxynaphthalene(cas: 93-04-9).Name: 2-Methoxynaphthalene

The Article related to alkoxy phenethylbenzene preparation, arylether alkene regioselective carbon hydrogen alkylation half sandwich calcium, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Name: 2-Methoxynaphthalene

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On March 17, 2021, Hashimoto, Toru; Shiota, Keisuke; Funatsu, Kei; Yamaguchi, Yoshitaka published an article.Recommanded Product: 2-Methoxynaphthalene The title of the article was Cross-Coupling Reactions of Aryl Halides with Primary and Secondary Aliphatic Alcohols Catalyzed by an O,N,N-Coordinated Nickel Complex. And the article contained the following:

A synthesis of alkyl aryl ethers was achieved via the cross-coupling of aryl halides with primary and secondary aliphatic alcs. catalyzed by a bench-stable nickel complex supported by a monoanionic O,N,N-tridentate ligand. This nickel-catalyzed reaction proceeds smoothly in the absence of a phosphine ligand, affording alkyl aryl ethers in moderate to good yields. The experimental process involved the reaction of 2-Methoxynaphthalene(cas: 93-04-9).Recommanded Product: 2-Methoxynaphthalene

The Article related to aryl halide aliphatic alc nickel catalyst cross coupling reaction, alkyl aryl ether preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Recommanded Product: 2-Methoxynaphthalene

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Zhao, Feng; Tan, Qi; Wang, Dahan; Deng, Guo-Jun published an article in 2020, the title of the article was Metal- and solvent-free direct C-H thiolation of aromatic compounds with sulfonyl chlorides.Quality Control of 2-Methoxynaphthalene And the article contains the following content:

A simple, efficient and green method for the direct thiolation of aromatic compounds using com. available sulfonyl chlorides as the sulfur source was developed under metal- and solvent-free conditions. The C-S bond was constructed via direct C-H functionalization of diverse aromatic compounds under an oxygen atm. In this process, various diaryl sulfides were synthesized in moderate to excellent yields. This protocol shows a broad substrate scope and good functional group tolerance. Moreover, a gram-scale experiment was also conducted to prove the prospect of this method for the scale-up synthesis of diaryl sulfides. Mechanistic studies indicate that this procedure probably undergoes a radical pathway. The experimental process involved the reaction of 2-Methoxynaphthalene(cas: 93-04-9).Quality Control of 2-Methoxynaphthalene

The Article related to arene aryl sulfonyl chloride thiolation, sulfide diaryl preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Quality Control of 2-Methoxynaphthalene

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On September 7, 2021, Bhattacharya, Aditya; mani Shukla, Pushpendra; Maji, Biswajit published an article.Recommanded Product: 93-04-9 The title of the article was “Haliranium Ion”-Induced Intermolecular Friedel-Crafts Alkylation in HFIP: Synthesis of β,β-Diaryl α-Halo carbonyl Compounds. And the article contained the following:

Herein, a highly regio- and diastereoselective haliranium ion-induced intermol. Friedel-Crafts reaction of α,β-unsaturated carbonyl compounds in HFIP is reported. The operationally simple and mild method affords the synthetically useful β,β-diarylated α-halo carbonyl compounds in good yields after a very short reaction time. As an application, a few examples of β,β-diarylated olefins are prepared in excellent yields. Based on the exptl. results and a qual. study of 1D-NMR-experiments, a plausible reaction mechanism is proposed. The experimental process involved the reaction of 2-Methoxynaphthalene(cas: 93-04-9).Recommanded Product: 93-04-9

The Article related to halo carbonyl compound preparation regioselective stereoselective, chalcone ester intermol friedel crafts reaction haliranium ion hexafluoropropanol, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ketones and Derivatives, Including Quinones and Sulfur Analogs and other aspects.Recommanded Product: 93-04-9

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Ether – Wikipedia,
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On May 1, 2020, Llopis, Natalia; Baeza, Alejandro published an article.Product Details of 93-04-9 The title of the article was Oxidation of Electron-Rich Arenes Using HFIP-UHP System. And the article contained the following:

The straightforward oxidation of electron-rich arenes, namely, phenols, naphthols, and anisole derivatives, under mild reaction conditions, is described by means of the use of an environmentally benign HFIP-UHP system. The corresponding quinones or hydroxylated arenes were obtained in moderate to good yields. The experimental process involved the reaction of 2-Methoxynaphthalene(cas: 93-04-9).Product Details of 93-04-9

The Article related to oxidation electron rich arene hfip uhp, quinone hydroxylated arene preparation green chem, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ketones and Derivatives, Including Quinones and Sulfur Analogs and other aspects.Product Details of 93-04-9

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Ether – Wikipedia,
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On April 30, 2020, Du, Tianshu; Quina, Frank H.; Tunega, Daniel; Zhang, Jianyu; Aquino, Adelia J. A. published an article.Related Products of 93-04-9 The title of the article was Theoretical O-CH3 bond dissociation enthalpies of selected aromatic and non-aromatic molecules. And the article contained the following:

Although Me transfer reactions are important in both chem. and biol. systems, there is a need for thermodn. parameters related to Me affinity and O-CH3 bond dissociation enthalpies (BDEs) relevant to a full understanding of the mechanisms of Me transfer reactions. As a prelude to the construction of a database of O-CH3 BDEs, the present work examines the reliability of a series of theor. methods for the prediction of O-CH3 BDEs using a set of 25 compounds that included both aromatic and non-aromatic mols. The BDEs calculated by d. functional theory (DFT) with traditional exchange-correlation functions exhibited much larger errors than those obtained by either the M06-2X or G4 methods. For the non-aromatic compounds, M06-2X/def2-TZVP performed slightly better than G4, but G4 was more accurate for the aromatic mols. As a result, we recommend G4 as the preferred method for the theor. estimation of O-CH3 bond dissociation enthalpies, although M06-2X may be a good alternative for large complex mols. when the use of G4 is impractical. The experimental process involved the reaction of 2-Methoxynaphthalene(cas: 93-04-9).Related Products of 93-04-9

The Article related to aromatic compound bond cleavage enthalpy, Physical Organic Chemistry: Theoretical Organic Chemical Concepts, Including Quantum and Molecular Mechanical Studies and other aspects.Related Products of 93-04-9

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Ether – Wikipedia,
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On May 5, 2021, Seki, Rin; Hara, Naofumi; Saito, Teruhiko; Nakao, Yoshiaki published an article.Category: ethers-buliding-blocks The title of the article was Selective C-O Bond Reduction and Borylation of Aryl Ethers Catalyzed by a Rhodium-Aluminum Heterobimetallic Complex. And the article contained the following:

We report the catalytic reduction of a C-O bond and the borylation by a rhodium complex bearing an X-type PAlP pincer ligand. We have revealed the reaction mechanism based on the characterization of the reaction intermediate and deuterium-labeling experiments Notably, this novel catalytic system shows steric-hindrance-dependent chemoselectivity that is distinct from conventional Ni-based catalysts and suggests a new strategy for selective C-O bond activation by heterobimetallic catalysis. The experimental process involved the reaction of 2-Methoxynaphthalene(cas: 93-04-9).Category: ethers-buliding-blocks

The Article related to aromatic hydrocarbon preparation reduction aryl ether rhodium aluminum catalyst, arylboronic ester preparation reduction borylation aryl ether bimetallic catalyst, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Category: ethers-buliding-blocks

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Ether – Wikipedia,
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On May 20, 2022, Li, Yonglong; Wang, Teng; Wang, Ying; Deng, Zhijie; Zhang, Li; Zhu, Aonan; Huang, Yanmin; Zhang, Cancan; Yuan, Mingjian; Xie, Wei published an article.SDS of cas: 93-04-9 The title of the article was Tunable Photocatalytic Two-Electron Shuttle between Paired Redox Sites on Halide Perovskite Nanocrystals. And the article contained the following:

Perovskite semiconductors as advanced solar energy-converting materials are promising catalysts for photoredox organic synthesis. Despite the high concentration of charge carriers generated on the perovskite surface, efficient utilization of these nonequilibrium and shambolic energetic carriers to trigger a chem. reaction remains a hot and challenging subject. Here, we report a photon-mediated electron shuttle between paired redox sites on perovskite nanocrystals for the reformation of highly stable carbon-halogen bonds, where both surface electrons and holes are utilized simultaneously. The photo-redox cascade can be effortlessly tailored by precise control of the surface-reducing/-oxidizing reaction rates, which unlocks the transformation for a wide range of (het)arenes. This work demonstrates colloidal perovskite photocatalysts for the direct installation of more than 10 different synthetically important functional groups onto arenes and heteroarenes. The experimental process involved the reaction of 2-Methoxynaphthalene(cas: 93-04-9).SDS of cas: 93-04-9

The Article related to tunable photocatalytic two electron shuttle halide perovskite nanocrystal photocatalyst, Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes: Radiation Chemistry and Photochemistry and other aspects.SDS of cas: 93-04-9

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Ether – Wikipedia,
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