Category: 929-37-3

On March 15, 2012, Chen, Hua; Yang, Jinliang; Guo, Dongfang; Wang, Liyuan; Nie, Jun published an article.Product Details of 929-37-3 The title of the article was Photopolymerization kinetics of α-disulfone cationic photoinitiator. And the article contained the following:

An α-disulfone cationic photoinitiator called 4-tolyl Me disulfone was synthesized and characterized by UV-vis absorption spectroscopy, LCMS, IR and NMR. Eight vinyl ether monomers were chosen to study the kinetics of photopolymerization by real-time IR spectroscopy (FT-IR). It showed that 4-tolyl Me disulfone was an effective cationic photoinitiator. The rate of polymerization and ultimate conversion increased with increase of 4-tolyl Me disulfone concentration and light intensity. The experimental process involved the reaction of 2-(2-(Vinyloxy)ethoxy)ethanol(cas: 929-37-3).Product Details of 929-37-3

The Article related to disulfone cationic photoinitiator photopolymerization vinyl ether monomer, photolysis disulfone photopolymerization catalyst, Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes: Radiation Chemistry and Photochemistry and other aspects.Product Details of 929-37-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Cao, Zhen; Bassani, Dario M.; Bibal, Brigitte published an article in 2018, the title of the article was Photoreduction of thioether gold(III) complexes: mechanistic insight and homogeneous catalysis.SDS of cas: 929-37-3 And the article contains the following content:

Complexes formed between AuCl3 and thioether ligands underwent a photoinduced reductive elimination under homogeneous conditions in dichloromethane and toluene solutions to afford the corresponding AuI complexes. All the gold(III) complexes were rapidly reduced to the gold(I) chloride complexes under 365 nm irradiation or ambient light while being thermally stable below 55 °C. The mechanism of photoreduction through Cl2 elimination is discussed based on a kinetic study and the chem. trapping of chlorine species: Cl2, radical Cl., and possibly Cl+. The catalytic activities of the gold(III) chloride complexes and the corresponding gold(I) complexes obtained by in situ reduction were evaluated in the cyclization of N-propargylic amides to oxazoles. The merits of such photoreducible complexes in homogeneous gold catalysis are illustrated by a cascade reaction catalyzed by thioether gold complexes that affords a 4H-quinolizin-4-one in high yields. The experimental process involved the reaction of 2-(2-(Vinyloxy)ethoxy)ethanol(cas: 929-37-3).SDS of cas: 929-37-3

The Article related to photoreduction gold cyclization catalyst amide oxazole thioether, gold, homogeneous catalysis, photoreduction, reaction mechanisms, reduction, thioether ligand, Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes: Radiation Chemistry and Photochemistry and other aspects.SDS of cas: 929-37-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On March 31, 2021, Trusiano, Giuseppe; Vitale, Alessandra; Bonneaud, Celine; Pugliese, Diego; Dalle Vacche, Sara; Joly-Duhamel, Christine; Friesen, Chadron M.; Bongiovanni, Roberta published an article.Quality Control of 2-(2-(Vinyloxy)ethoxy)ethanol The title of the article was Vinyl ethers and epoxides photoinduced copolymerization with perfluoropolyalkylether monomers. And the article contained the following:

New perfluoropolyalkylether (PFPAE) monomers, chain extended with different alkyl groups and functionalized with vinyl ether or epoxide end-groups, were employed, together with trimethylolpropane trivinyl ether or trimethylolpropane triglycidyl ether, to produce fluorinated copolymers. The photoinduced cationic polymerization was investigated, and the PFPAE-based copolymer properties were thoroughly characterized. Interesting surface properties and two different values of refractive index were observed: thus, these fluorinated copolymers can be suitable materials for the manufacture of self-cleaning coatings and optical waveguides. The experimental process involved the reaction of 2-(2-(Vinyloxy)ethoxy)ethanol(cas: 929-37-3).Quality Control of 2-(2-(Vinyloxy)ethoxy)ethanol

The Article related to perfluoropolyalkylether monomer vinyl ether epoxide photoinduced copolymerization thermal property, cationic polymerization, perfluoropolyalkylethers, refractive index, sliding angle, uv curing and other aspects.Quality Control of 2-(2-(Vinyloxy)ethoxy)ethanol

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Sarapas, Joel M.; Tew, Gregory N. published an article in 2016, the title of the article was Thiol-Ene Step-Growth as a Versatile Route to Functional Polymers.Application In Synthesis of 2-(2-(Vinyloxy)ethoxy)ethanol And the article contains the following content:

A new use of the thiol-ene reaction to generate functional, redox-tunable polymers is described. To illustrate the versatility of this approach, tailored divinyl ether monomers were polymerized with triethylene glycol dithiol to yield polymers containing either a carbonate or zwitterionic phosphocholine within the polymer backbone. Similarly, dithioerythritol was polymerized with triethylene glycol divinyl ether to yield a polymer with pendant diols and show how functional groups can be designed into either the divinyl ether or dithiol monomer. Using the thioether functional group inherent to this polymerization, all three polymers were selectively and quant. oxidized to either sulfoxides or sulfones by treatment with dilute hydrogen peroxide or mCPBA, resp. With these illustrative examples, it is shown that the thiol-ene polymerization is a broad-reaching method to access a class of new redox-active polymers which contain varied and dense functional-group compositions The experimental process involved the reaction of 2-(2-(Vinyloxy)ethoxy)ethanol(cas: 929-37-3).Application In Synthesis of 2-(2-(Vinyloxy)ethoxy)ethanol

The Article related to thiol ene step growth polymerization oxidation sulfoxide sulfone, carbonate zwitterionic phosphocholine polyether backbone preparation, click chemistry, diols, oxidation, polymerization, zwitterions and other aspects.Application In Synthesis of 2-(2-(Vinyloxy)ethoxy)ethanol

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On December 30, 2013, Dong, Xiaomei; Wang, Qingxia; Zhang, Qian; Xu, Shuai; Wang, Zhihong published an article.Application of 929-37-3 The title of the article was Construction of dihydropyran-bridged macrocycles by inverse-electron-demand Diels-Alder reaction. And the article contained the following:

A variety of dihydropyran-bridged macrocyclic structures were constructed by the inverse-electron-demand Diels-Alder reaction of 2-oxo-4-aryl-but-3-enoates. Controlling of the tether length and the position of the activating substituent in the substrates would guide the reaction to the formation of four different types of polycyclic frames, namely bicyclic [n.3.1], bicyclic [n.2.2], tricyclic [n.3.1.1], and tricyclic [n.2.2.2] macrocycles. The intermol./intramol. selectivity of the Diels-Alder reaction was virtually governed by the tether length. The reactions were carried out rapidly under mild conditions, and offered a practical method for creating bridged polycyclic structures with large rings from acyclic precursors. The experimental process involved the reaction of 2-(2-(Vinyloxy)ethoxy)ethanol(cas: 929-37-3).Application of 929-37-3

The Article related to oxoarylbutenoate inverse electron demand diels alder reaction, dihydropyran bridged bicyclic tricyclic macrocycle preparation, tether length control selectivity cyclization dimerization trimerization and other aspects.Application of 929-37-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On March 31, 2022, Wang, Mingqi; Zhou, Jingjing; Zhang, Guoxian; Liu, Qing; Zhang, Qiuyu published an article.Computed Properties of 929-37-3 The title of the article was Pyrrolidinyl ligand motif-assisted bovine serum albumin molecularly imprinted polymers with high specificity. And the article contained the following:

Ideal binding ligands for anchoring proteins are essential for the design and assembly of desirable molecularly imprinted polymers (MIPs). In this study, bovine serum albumin-MIPs (BSA-MIPs) were successfully prepared by orchestrating the involvement of orientation-controllable binding ligands via sequential thiol-ene click and thiol-ene-amine conjugation. We showed that the optimal thiol-ene-amine conjugates and binding ligands were decisive in determining the rebinding capacity and selectivity. The pyrrolidinyl MIPs exhibited the best adsorption capacity of 352 卤 22 mg/g and a superior imprinting factor of 4.72 among MIPs with various binding ligands. These favorable results were further studied by computational simulation and isothermal titration calorimetry (ITC). Mol. docking revealed the preferential binding free energy and H-bonds between BSA residues and the thiol-ene-amine conjugates. Meanwhile, the pyrrolidinyl ligand motif enabled entropy-favorable affinity to be achieved via hydrophobic effects with the BSA template by ITC thermodn. Because of these favorable bindings, the MIPs exhibited excellent adsorption specificity to BSA over competing proteins. The proof-of-concept of MIPs with orientation-controllable conjugates and proven binding ligands for target proteins demonstrates that this material is promising for use with a real biol. sample. The experimental process involved the reaction of 2-(2-(Vinyloxy)ethoxy)ethanol(cas: 929-37-3).Computed Properties of 929-37-3

The Article related to pyrrolidinyl ligand bovine serum albumin molecularly imprinted polymer, adsorption capacity, hydrophobic effect, molecularly imprinted polymers (mips), pyrrolidinyl group, thiol-ene-amine conjugation and other aspects.Computed Properties of 929-37-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Motoyanagi, Jin; Oguri, Ayaha; Minoda, Masahiko published an article in 2020, the title of the article was Synthesis of well-defined alternating copolymer composed of ethylmaleimide and hydroxy-functionalized vinyl ether by raft polymerization and their thermoresponsive properties.Formula: C6H12O3 And the article contains the following content:

Here we report the controlled synthesis of alternating copolymers by reversible addition-fragmentation chain transfer (RAFT) polymerization of hydroxy-functionalized vinyl ether (DEGV) and ethylmaleimide (EtMI) using dithiocarbonate derivative (CPDB) as the RAFT reagent. The resulting alternating copolymer poly[ethylmaleimide-alt-(diethylene glycol mono vinyl ether)] (poly(MalMI-alt-DEGV)) had a relatively narrow mol. weight distribution (Mw/Mn < 1.4). These polymers are fully soluble in cold water (5掳C) and an aqueous solution of poly(MalMI-alt-DEGV) became turbid upon heating (using an incident wavelength of 600 nm and 1.0 mg mL-1 (0.1 weight%) polymer concentration), indicating phase separation above the cloud point temperature (Tcp). The Tcp of the polymer solution ranged from 15-35掳C, depending on the mol. weight and mol. weight distribution of the polymer. The experimental process involved the reaction of 2-(2-(Vinyloxy)ethoxy)ethanol(cas: 929-37-3).Formula: C6H12O3

The Article related to ethylmaleimide vinyl ether copolymer chain transfer polymerization thermoresponsive property, raft copolymerization, alternating copolymer, hydroxy-functionalized vinyl ether, thermoresponsive property and other aspects.Formula: C6H12O3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On September 6, 2021, Quan, Qinzhi; Ma, Mingyu; Wang, Zongtao; Gu, Yu; Chen, Mao published an article.Computed Properties of 929-37-3 The title of the article was Visible-Light-Enabled Organocatalyzed Controlled Alternating Terpolymerization of Perfluorinated Vinyl Ethers. And the article contained the following:

Polymerizations of perfluorinated vinyl ethers (PFVEs) provide an important category of fluoropolymers that have received considerable interests in applications. In this work, we report the development of an organocatalyzed controlled radical alternating terpolymn. of PFVEs and vinyl ethers (VEs) under visible-light irradiation This method not only enables the synthesis of a broad scope of fluorinated terpolymers of low dispersities and high chain-end fidelity, facilitating tuning the chem. compositions by rationally choosing the type and/or ratio of comonomers, but also allows temporal control of chain-growth, as well as the preparation of a variety of novel fluorinated block copolymers. To showcase the versatility of this method, fluorinated alternating terpolymers were synthesized and customized to simultaneously display a variety of desirable properties for solid polymer electrolyte design, creating new opportunities in high-performance energy storage devices. The experimental process involved the reaction of 2-(2-(Vinyloxy)ethoxy)ethanol(cas: 929-37-3).Computed Properties of 929-37-3

The Article related to visible light organocatalyst radical alternating terpolymn perfluorinated vinyl ether, fluoropolymer alternating copolymer block electrolyte solid electrolyte, controlled radical polymerization, fluorine, photocatalysis, synthetic methods, terpolymer and other aspects.Computed Properties of 929-37-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Minoda, Masahiko; Otsubo, Tomomi; Yamamoto, Yohei; Zhao, Jianxin; Honda, Yoshitomo; Tanaka, Tomonari; Motoyanagi, Jin published an article in 2019, the title of the article was The First Synthesis of Periodic and Alternating Glycopolymers by RAFT Polymerization: A Novel Synthetic Pathway for Glycosaminoglycan Mimics.Electric Literature of 929-37-3 And the article contains the following content:

This study concerned the controlled synthesis of periodic glycopolymers by reversible addition-fragmentation chain transfer (RAFT) copolymerization To this end, maltose- and lactose-substituted vinyl ethers (MalVE and LacVE, resp.) and maltose-substituted maleimide (MalMI) were newly synthesized. RAFT copolymerization of MalVE and Et maleimide (EtMI) (monomer feed ratio: MalVE:EtMI = 1:1) afforded periodic glycopolymers (poly(MalVE-co-EtMI)) consisting of major parts of alternating structure (-(MalVE-EtMI)n-) and a small part of consecutive sequences of EtMI (-EtMI-EtMI-). Occurrence of the latter sequences was caused by the homopolymerizability of maleimide under the present polymerization condition, and the formation of the consecutive sequences of EtMI was successfully suppressed by varying the monomer feed ratio. RAFT copolymerization of LacVE and EtMI was also found to proceed and similarly yielded periodic glycopolymers (poly(LacVE-co-EtMI)). Moreover, RAFT copolymerization of LacVE and MalMI (monomer feed ratio: LacVE:MalMI = 1:1) was performed to give copolymers (poly(LacVE-co-MalMI)) having composition ratio of LacVE/MalMI ≈ 36/64. The resultant periodic glycopolymers poly(MalVE-co-EtMI) and poly(LacVE-co-EtMI) were subjected to lectin binding assay using Con A and peanut agglutinin, exhibiting the glycocluster effect. Moreover, these glycopolymers obtained from the copolymerization of VE and MI were found to be non-cytotoxic. The experimental process involved the reaction of 2-(2-(Vinyloxy)ethoxy)ethanol(cas: 929-37-3).Electric Literature of 929-37-3

The Article related to glycosaminoglycan mimics glycopolymer raft polymerization, cuaac click reaction, raft copolymerization, alternating glycopolymer, carbohydrate-substituted maleimide, carbohydrate-substituted vinyl ether, glycosaminoglycan mimics, periodic glycopolymer and other aspects.Electric Literature of 929-37-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On August 17, 2007, Arvela, Riina K.; Pasquini, Serena; Larhed, Mats published an article.Electric Literature of 929-37-3 The title of the article was Highly Regioselective Internal Heck Arylation of Hydroxyalkyl Vinyl Ethers by Aryl Halides in Water. And the article contained the following:

Highly regioselective and fast Pd(0)-catalyzed internal α-arylation of ethylene glycol vinyl ether with aryl halides was shown to be possible in water without the need for any halide scavengers or ionic liquid additives. This presents the first case of water being utilized in the selective arylation of electron-rich olefins. Resulting α-products, e.g. I, were hydrolyzed and isolated as corresponding acetophenones, e.g. II, in good to excellent yields when using aryl bromides and with good to moderate yields in the case of aryl iodides. Microwave irradiation was shown to be beneficial in activation of aryl chlorides toward the internal Heck arylation. The scope of the protocol was further increased to include different hydroxyalkyl vinyl ethers, these all giving selectively only branched α-products. The active role of the hydroxy group in directing the regioselectivity toward internal arylation of electron-rich olefins, even in nonpolar toluene, was revealed. The experimental process involved the reaction of 2-(2-(Vinyloxy)ethoxy)ethanol(cas: 929-37-3).Electric Literature of 929-37-3

The Article related to acetophenone preparation green chem, hydroxyalkyl vinyl ether aryl bromide iodide chloride heck arylation, regioselective internal heck arylation palladium catalysis microwave irradiation, hydroxy neighboring group effect regioselective internal heck arylation and other aspects.Electric Literature of 929-37-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem