Category: 929-37-3

On July 31, 2021, Trusiano, Giuseppe; Vitale, Alessandra; Pulfer, Jason; Newton, Josiah; Joly-Duhamel, Christine; Friesen, Chadron M.; Bongiovanni, Roberta published an article.Product Details of 929-37-3 The title of the article was Novel perfluoropolyalkylethers monomers: synthesis and photo-induced cationic polymerization. And the article contained the following:

Abstract: Several difunctional oligomers were synthesized by functionalizing perfluoropolyalkylether (PFPAE) chains with different vinyl ethers and epoxides end-groups. Due to their innate synthetic challenges and demanding purification protocols, the PFPAE derivatives were obtained in low yield and with an average functionality lower than 2. However, the functionalized PFPAE oligomers were successful in being used in photo-induced cationic polymerization processes, obtaining transparent and soft films. The influences of the fluorinated chains, and various end-groups on the photopolymerization process were investigated, as well their chem. stability, thermal degradation, and surface properties. The experimental process involved the reaction of 2-(2-(Vinyloxy)ethoxy)ethanol(cas: 929-37-3).Product Details of 929-37-3

The Article related to perfluoropolyalkylether epoxy photo induced cationic polymerization, fluoropolymers, functionalized perfluoropolyalkylethers, photopolymerization, Chemistry of Synthetic High Polymers: Monomers and Reagents Used In Polymerization and other aspects.Product Details of 929-37-3

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Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On May 31, 2002, Raskulova, T. V.; Volkova, L. I.; Danilevich, Yu. S.; Shainyan, B. A.; Khaliullin, A. K. published an article.HPLC of Formula: 929-37-3 The title of the article was Formation of Diol Divinyl Diethers in the Synthesis of 1,2-Epoxy-3-(vinyloxyalkoxy)propanes. And the article contained the following:

The reaction of vinyl oxyalkoxy ethers in presence of epichlorohydrin yielded 1,2-epoxy-3-(vinyloxyalkoxy)propanes CH2=CH-O-X-CH2-CH(-O-)-CH2 (X = (CH2CH2O)n, n = 2, 3, 4), usable as monomers. No 1,3-bis(vinyloxyalkoxy)glycerol ethers were found. In the absence of epichlorohydrin divinyl ethers CH2=CH-O-X-CH=CH2 (X = (CH2CH2O)n, n = 2, 5, 4) were prepared 11,12-Epoxy-3,6,9-trioxa-1-dodecene, 14,15-epoxy-3,6,9,12-tetraoxa-1-pentadecene, 17,18-epoxy-3,6,9,12,15-pentaoxa-1-octadecene, bis(2-vinyloxyethyl) ether, 3,6,9,12,15,18-hexaoxa-1,19-eicosadiene, and 3,6,9,12,15-pentaoxa-1,16-heptadecadiene were prepared and characterized. The experimental process involved the reaction of 2-(2-(Vinyloxy)ethoxy)ethanol(cas: 929-37-3).HPLC of Formula: 929-37-3

The Article related to vinyloxyalkoxypropane epoxide monomer preparation, oligoether vinyl ether epichlorohydrin substitution, divinyl ether oligoether containing preparation, Chemistry of Synthetic High Polymers: Monomers and Reagents Used In Polymerization and other aspects.HPLC of Formula: 929-37-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On February 27, 2013, Briones, Rodrigo; Serrano, Luis; Sequeiros, Ane; Labidi, Jalel published an article.SDS of cas: 929-37-3 The title of the article was Influence of Microwave Heating on Chemical Properties of Liquefied Lignocellulosic Residues. And the article contained the following:

The chem. composition of liquid products obtained from liquefaction of several agro-industrial wastes was analyzed and the effects of microwave treatments were investigated, evaluating changes in chem. composition, structure, and phys. properties, looking forward to exploring new utilization routes or processing paths for these liquid products. Gas chromatog.-mass spectrometry (GC-MS) showed that the chem. components of liquefied products can be divided into several groups: furans, alcs., and esters and acid derivatives The microwave evaluation showed that irradiation at constant power levels affects the compositions of liquefied products. Fourier transform IR (FT-IR) spectroscopic anal. showed increases in the absorption bands of carbonyl and CH groups, which suggests that microwaves induced more intensive oxidation of hydroxyl groups into carbonyl groups. Elemental anal. indicated higher carbon and lower oxygen contents and higher heat heating value (20 MJ/kg) in treated products with respect to untreated samples. The use of liquefied products as a new energy source has advantages such as their liquid state, convenient energy value, and renewability. The experimental process involved the reaction of 2-(2-(Vinyloxy)ethoxy)ethanol(cas: 929-37-3).SDS of cas: 929-37-3

The Article related to liquefied agricultural waste microwave heating chem composition, Cellulose, Lignin, Paper, and Other Wood Products: Wood and Other Cellulosic Materials and other aspects.SDS of cas: 929-37-3

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Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Kucuk, Asuman C.; Matsui, Jun; Miyashita, Tokuji published an article in 2012, the title of the article was Proton-conducting electrolyte film of double-decker-shaped polyhedral silsesquioxane containing covalently bonded phosphonic acid groups.Synthetic Route of 929-37-3 And the article contains the following content:

As described phosphonic-acid-containing double-decker polyhedral silsesquioxane (PHOS-DDSQ) was synthesized and the p conductivity of the PHOS-DDSQ cast film was studied under humid and non-humid conditions. To synthesize PHOS-DDSQ, double-decker-shaped polyhedral silsesquioxane (DDSQ) was reacted with di(ethylene glycol) (DEG) vinyl ether using hydrosilylation reaction to attach 4 DEG units to one DDSQ (4DEG-DDSQ). Subsequently, a phosphate esterification of hydroxyl groups in 4DEG-DDSQ was carried out using POCl3. NMR, XPS, and MALDI-TOF MS spectra and titration measurements revealed that the phosphate esterification connected 2 DEG units to form a crown-ether-like structure. This structure prevents hydrolysis of the phosphate ester bond. PHOS-DDSQ showed high thermal stability, with decomposition temperature exceeding 220°, because of its inorganic DDSQ core. A uniform film of PHOS-DDSQ can be fabricated by drop casting. The cast film showed high p conductivity (0.12 S/cm) under humid conditions, which is comparable to that of a Nafion membrane. Also, the cast film offered good p conductivity under non-humid conditions (3.6 × 10-4 S/cm at 170°). The conductivity and thermal stability indicate that PHOS-DDSQ is a good candidate for use as a p-conductive membrane in hydrated type fuel cells as well as fuel cells operated at intermediate temperatures (100-200°) under non-humid conditions. The experimental process involved the reaction of 2-(2-(Vinyloxy)ethoxy)ethanol(cas: 929-37-3).Synthetic Route of 929-37-3

The Article related to proton conductor electrolyte silsesquioxane phosphonate fuel cell, Electrochemical, Radiational, and Thermal Energy Technology: Energy-Conversion Devices and Their Components and other aspects.Synthetic Route of 929-37-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Yan, Suting; Xie, Jianda; Wu, Qingshi; Zhou, Shiming; Qu, Anqi; Wu, Weitai published an article in 2015, the title of the article was Highly efficient solid polymer electrolytes using ion containing polymer microgels.SDS of cas: 929-37-3 And the article contains the following content:

A solid polymer electrolyte exhibiting high ionic conductivity (reaching ca. 10-4.8 S cm-1 at 25 °C) is fabricated using ion containing polymer microgels of lithium tris(perfluorophenyl) (2,3,5,6-tetrafluoro-4-(2-(2-(vinyloxy)ethoxy)ethoxy)phenyl) borate. This solid polymer electrolyte shows great possibilities for use in large-capacity lithium ion batteries. The experimental process involved the reaction of 2-(2-(Vinyloxy)ethoxy)ethanol(cas: 929-37-3).SDS of cas: 929-37-3

The Article related to solid polymer electrolyte ion containing microgel, Electrochemical, Radiational, and Thermal Energy Technology: Energy-Conversion Devices and Their Components and other aspects.SDS of cas: 929-37-3

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Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Lin, Yan; Stansbury, Jeffrey W. published an article in 2003, the title of the article was In situ characterization of hybrid polymerization by NIR.Recommanded Product: 929-37-3 And the article contains the following content:

The effect of water on cationic photopolymerization of vinyl ethers was studied by real time FT-NIR (Fourier transform near IR) spectroscopy. The following vinyl ethers were used: tri(ethylene glycol)methyl, bis(ethylene glycol), and Et. The photopolymerization of the vinyl ethers was followed in situ and the water absorbance and environment changes during polymerization were investigated. The formation of acetaldehyde and aldehydic end groups was confirmed and attributed to a water-driven chain transfer reaction. The experimental process involved the reaction of 2-(2-(Vinyloxy)ethoxy)ethanol(cas: 929-37-3).Recommanded Product: 929-37-3

The Article related to vinyl ether photopolymerization water effect near ir spectroscopy, Chemistry of Synthetic High Polymers: Polymerization Kinetics, Mechanisms, Thermodynamics, Catalysis, Catalysts and other aspects.Recommanded Product: 929-37-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On September 26, 2022, Sudhakaran, Swetha; Siddiki, S. M. A. Hakim; Kitiyanan, Boonyarach; Nomura, Kotohiro published an article.Application In Synthesis of 2-(2-(Vinyloxy)ethoxy)ethanol The title of the article was CaO Catalyzed Transesterification of Ethyl 10-Undecenoate as a Model Reaction for Efficient Conversion of Plant Oils and Their Application to Depolymerization of Aliphatic Polyesters. And the article contained the following:

Transesterification of Et 10-undecenoate (derived from castor oil) with cyclohexanemethanol over a CaO catalyst (prebaked at 300°C) gave undec-10-enoate exclusively (yield 92%, selectivity 95-98%) at 100°C, and the activity increased at 120°C with maintaining the high selectivity (97-98%). The transesterification with other alcs., especially primary alcs. (2-ethyl-1-butanol, 1-hexanol, 3-buten-1-ol, and 10-undecen-1-ol), afforded the corresponding esters with high selectivity, indicating the possibility for application of efficient conversion of plant oils to various fine chems. including the monomer for the synthesis of polyesters. Efficient acid-, base-free depolymerization of aliphatic polyesters, poly(ethylene adipate) and poly(butylene adipate), has been demonstrated in this catalysis by transesterification with ethanol and cyclohexanemethanol, affording corresponding adipates and ethylene glycol or butylene glycol exclusively: the reusability of a CaO catalyst has also been demonstrated. The experimental process involved the reaction of 2-(2-(Vinyloxy)ethoxy)ethanol(cas: 929-37-3).Application In Synthesis of 2-(2-(Vinyloxy)ethoxy)ethanol

The Article related to cao transesterification ethyl undecenoate plant oil depolymerization polyester, Chemistry of Synthetic High Polymers: Polymerization Kinetics, Mechanisms, Thermodynamics, Catalysis, Catalysts and other aspects.Application In Synthesis of 2-(2-(Vinyloxy)ethoxy)ethanol

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On December 31, 2018, Maji, Arun; Dahiya, Amit; Lu, Gang; Bhattacharya, Trisha; Brochetta, Massimo; Zanoni, Giuseppe; Liu, Peng; Maiti, Debabrata published an article.Safety of 2-(2-(Vinyloxy)ethoxy)ethanol The title of the article was H-bonded reusable template assisted para-selective ketonisation using soft electrophilic vinyl ethers. And the article contained the following:

Herein, a directed para-selective ketonisation technique of arenes was disclosed, overriding electronic bias and structural congestion, in the presence of a polar protic solvent. The concept of hard-soft interaction along with in situ activation techniques is utilized to suppress the competitive routes. Mechanistic pathways are investigated both exptl. and computationally to establish the hypothesis. Synthetic utility of the protocol is highlighted in formal synthesis of drugs, drug cores, and bioactive mols. The experimental process involved the reaction of 2-(2-(Vinyloxy)ethoxy)ethanol(cas: 929-37-3).Safety of 2-(2-(Vinyloxy)ethoxy)ethanol

The Article related to benzylsilyl ether regioselective ketonisation electrophilic vinyl ether, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ketones and Derivatives, Including Quinones and Sulfur Analogs and other aspects.Safety of 2-(2-(Vinyloxy)ethoxy)ethanol

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On January 2, 2015, Mongin, Cedric; Pianet, Isabelle; Jonusauskas, Gediminas; Bassani, Dario M.; Bibal, Brigitte published an article.Category: ethers-buliding-blocks The title of the article was Supramolecular Photocatalyst for the Reduction of Au(III) to Au(I) and High-Turnover Generation of Gold Nanocrystals. And the article contained the following:

A photocatalyst composed of a diphenylanthracene core appended with two lipophilic thioether side-chains that binds gold(III) chloride is reported. Upon excitation using visible light, the AuIII ions are smoothly reduced to AuI which, in the presence of water, lead to the formation of crystalline gold nanoparticles of 20-50 nm diameter that are devoid of sulfur-containing capping agents. Ultrafast transient absorption spectroscopy shows that the anthracene excited state is quenched with a rate k = 3.5 × 1010 s-1, assigned to intramol. energy transfer to the bound gold ions, which then oxidizes the solvent to produce an intermediate low-valency gold(I) species. In the absence of water, the latter is stable and can be used as a homogeneous AuI catalyst. When employed in a biphasic reactor, the photocatalyst shows average turnover numbers of 150 atoms of AuIII reduced to Au0 per mol. of photocatalyst. The experimental process involved the reaction of 2-(2-(Vinyloxy)ethoxy)ethanol(cas: 929-37-3).Category: ethers-buliding-blocks

The Article related to supramol photocatalyst photocatalysis gold photoreduction nanoparticle, Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes: Radiation Chemistry and Photochemistry and other aspects.Category: ethers-buliding-blocks

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Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On October 5, 2011, Arumugam, Selvanathan; Popik, Vladimir V. published an article.HPLC of Formula: 929-37-3 The title of the article was Patterned Surface Derivatization Using Diels-Alder Photoclick Reaction. And the article contained the following:

The utility of photochem. induced hetero-Diels-Alder reaction for the light-directed surface derivatization and patterning was demonstrated. Glass slides functionalized with vinyl ether moieties are covered with aqueous solution of substrates conjugated to 3-(hydroxymethyl)-2-naphthol (NQMP). Subsequent irradiation via shadow mask results in an efficient conversion of the latter functionality into reactive 2-naphthoquinone-3-methide (oNQM) in the exposed areas. ONQM undergoes very facile hetero Diels-Alder addition (kD-A ≈ 4 × 104 M-1s-1) to immobilized vinyl ether mols. resulting in a photochem. stable covalent link between a substrate and a surface. Unreacted oNQM groups are rapidly hydrated to regenerate NQMP. The click chem. based on the addition of photochem. generated oNQM to vinyl ether works well in aqueous solution, proceeds at high rate under ambient conditions, and does not require catalyst or addnl. reagents. This photoclick strategy represents an unusual paradigm in photopatterning: the surface itself is photochem. inert, while photoreactive component is present in the solution The short lifetime (τ ≈ 7 ms in H2O) of the active form of a photoclick reagent in aqueous solution prevents its migration from the site of irradiation, thus allowing for the spatial control of surface derivatization. Both o-naphthoquinone methide precursors and vinyl ethers are stable in dark and the reaction is orthogonal to other derivatization techniques, such as acetylene-azide click reaction. The experimental process involved the reaction of 2-(2-(Vinyloxy)ethoxy)ethanol(cas: 929-37-3).HPLC of Formula: 929-37-3

The Article related to photoinduced patterned surface derivatization hetero diels alder photoclick reaction, Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes: Radiation Chemistry and Photochemistry and other aspects.HPLC of Formula: 929-37-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem