Category: 882-33-7

Thomas, Sajesh P.; Thomas, Reshmi; Groenbech, Thomas Bjoern E.; Bondesgaard, Martin; Mamakhel, Aref H.; Birkedal, Victoria; Iversen, Bo B. published their research in Journal of Physical Chemistry Letters in 2021. The article was titled 《Bandgap tuning in molecular alloy crystals formed by weak chalcogen interactions》.Related Products of 882-33-7 The article contains the following contents:

We demonstrate systematic tuning in the optical bandgaps of mol. crystals achieved by the generation of mol. alloys/solid solutions of a series of di-Ph dichalcogenides-characterized by weak chalcogen bonding interactions involving S, Se, and Te atoms. Despite the variety in chalcogen bonding interactions found in this series of dichalcogenide crystals, they show isostructural interaction topologies, enabling the formation of solid solutions The alloy crystals exhibit Vegard’s law-like trends of variation in their unit cell dimensions and a nonlinear trend for the variation in optical bandgaps with respect to their compositions Energy-dispersive X-ray and spatially resolved Raman spectroscopic studies indicate significant homogeneity in the domain structure of the solid solutions Quantum periodic calculations of the projected d. of states provide insights into the bandgap tuning in terms of the mixing of states in the alloy crystal phases. The results came from multiple reactions, including the reaction of 1,2-Diphenyldisulfane(cas: 882-33-7Related Products of 882-33-7)

1,2-Diphenyldisulfane(cas: 882-33-7) belongs to ethers. Ethers lack the hydroxyl groups of alcohols. Related Products of 882-33-7 Without the strongly polarized O―H bond, ether molecules cannot engage in hydrogen bonding with each other.

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

《Effect of Propanol-1 on the Reaction between Thiophenol and N,N’-Diphenyl-1,4-Benzoquinone Diimine in Chlorobenzene》 was written by Varlamov, V. T.. Synthetic Route of C12H10S2This research focused onthiophenol diphenyl benzoquinone diimine addition reaction kinetics. The article conveys some information:

Abstract: It is found that the interaction between thiophenol and N,N’-diphenyl-1,4-benzoquinone diimine proceeds by two routes, one of which is a radical chain reaction and the other is a nonchain reaction between the reagents. The kinetic patterns of the reaction depend substantially on the concentration of propanol-1 in mixtures of it and chlorobenzene. It is shown that at 343 K, replacing chlorobenzene with propanol-1 results in an almost twentyfold increase in the total rate of the reaction. Increasing the concentration of propanol-1 raises the rate of both routes of the reaction, but that of the nonchain route grows more than that of the chain route. It is concluded that increasing the concentration of propanol-1 results in a simultaneous 20-30 times rise in the rate constants of both the stage of radical generation by the reaction between the reagents as well as the rate constant of the nonchain bimol. reaction, and the chain length of the chain reaction is shortened. When chlorobenzene is replaced with propanol-1, the rate constant of the limiting stage of chain propagation (the reaction of quinone diimine with a phenylthiyl radical) is halved, due to the formation of H complexes between the π system of quinone diimine and the proton of propanol-1.1,2-Diphenyldisulfane(cas: 882-33-7Synthetic Route of C12H10S2) was used in this study.

1,2-Diphenyldisulfane(cas: 882-33-7) belongs to ethers.Although ethers resist hydrolysis, they are cleaved by hydrobromic acid and hydroiodic acid. Hydrogen chloride cleaves ethers only slowly. Synthetic Route of C12H10S2

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

In 2019,Angewandte Chemie, International Edition included an article by Kang, Yan-Shang; Zhang, Ping; Li, Min-Yan; Chen, You-Ke; Xu, Hua-Jin; Zhao, Jing; Sun, Wei-Yin; Yu, Jin-Quan; Lu, Yi. Electric Literature of C12H10S2. The article was titled 《Ligand-Promoted RhIII-Catalyzed Thiolation of Benzamides with a Broad Disulfide Scope》. The information in the text is summarized as follows:

A ligand-promoted RhIII-catalyzed C(sp2)-H activation/thiolation of benzamides has been developed. Using bidentate mono-N-protected amino acid ligands led to the first example of RhIII-catalyzed aryl thiolation reactions directed by weakly coordinating directing amide groups. The reaction tolerates a broad range of amides and disulfide reagents. The experimental part of the paper was very detailed, including the reaction process of 1,2-Diphenyldisulfane(cas: 882-33-7Electric Literature of C12H10S2)

1,2-Diphenyldisulfane(cas: 882-33-7) belongs to ethers.Oxygen is more electronegative than carbon, thus the alpha hydrogens of ethers are more acidic than those of simple hydrocarbons. Electric Literature of C12H10S2 They are far less acidic than alpha hydrogens of carbonyl groups (such as in ketones or aldehydes), however.

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

In 2019,Journal of Metals, Materials and Minerals included an article by Worlee, Anuwat; Saiwari, Sitisaiyidah; Dierkes, Wilma; Sarkawi, Siti Salina; Nakason, Charoen. Safety of 1,2-Diphenyldisulfane. The article was titled 《Influence of filler network on thermo-chemical de-vulcanization efficiency of carbon black filled natural rubber》. The information in the text is summarized as follows:

Carbon black is often used as the reinforcing filler in tires since it plays an important role in improvement of tires mech. properties such as abrasion, stiffness, modulus and fatigue life. In this study, natural rubber (NR) filled with various loadings of carbon black was prepared Then, the NR vulcanizates were de-vulcanized via thermo-chem. method using di-Ph disulfide as de-vulcanization aid. The de-vulcanization efficiency was analyzed by relationship between sol fraction and crosslink d. of the de-vulcanizates. It is found that the de-vulcanization efficiency is influenced by filler loading. This is attributed to the degree of filler network formation in a rubber matrix which is depended on the filler loadings. In the unfilled de-vulcanizates the results showed that almost 100% of sol fraction and the crosslink d. reduced to almost zero are observed Adding carbon black results in a decrease of sol fraction and increase of crosslink densities. This is due to during de-vulcanization some occurred reactive radicals reacted with active site of carbon black surfaces in filler network to form gels of complex compound Hence, the de-vulcanization efficiency is lower with increasing carbon black loadings. After reading the article, we found that the author used 1,2-Diphenyldisulfane(cas: 882-33-7Safety of 1,2-Diphenyldisulfane)

1,2-Diphenyldisulfane(cas: 882-33-7) belongs to ethers. Ethers lack the hydroxyl groups of alcohols. Safety of 1,2-Diphenyldisulfane Without the strongly polarized O―H bond, ether molecules cannot engage in hydrogen bonding with each other.

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

In 2019,Angewandte Chemie, International Edition included an article by Pitts, Cody Ross; Bornemann, Dustin; Liebing, Phil; Santschi, Nico; Togni, Antonio. Quality Control of 1,2-Diphenyldisulfane. The article was titled 《Making the SF5 Group More Accessible: A Gas-Reagent-Free Approach to Aryl Tetrafluoro-λ6-sulfanyl Chlorides》. The information in the text is summarized as follows:

A series of aryl tetrafluoro-λ6-sulfanyl chlorides R-X [R = Ph, 4-BzOC6H4, 5-Br-2-pyridyl, 5-Br-2-pyrimidinyl, etc.; X = SF4Cl] was synthesized via trifluoroacetic acid catalyzed gas-reagent-free oxidative polyfluorination of aryl disulfides. This approach overcame the reliance on hazardous fluorinating reagents and/or gas reagents (e.g. Cl2) by employing easy-to-handle trichloroisocyanuric acid, potassium fluoride and catalytic amounts of acid. Furthermore, the same approach provided an access to compounds R-X [X = SF3, SF5, SeF3] which extended the applications of this chem. beyond arene SF5-functionalization and demonstrated its ability to address a more general oxidative fluorination problem. In the experiment, the researchers used many compounds, for example, 1,2-Diphenyldisulfane(cas: 882-33-7Quality Control of 1,2-Diphenyldisulfane)

1,2-Diphenyldisulfane(cas: 882-33-7) belongs to ethers.The C-O bonds that comprise simple ethers are strong. Quality Control of 1,2-Diphenyldisulfane They are unreactive toward all but the strongest bases. Although generally of low chemical reactivity, they are more reactive than alkanes.

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

In 2019,Science (Washington, DC, United States) included an article by Smaligo, Andrew J.; Swain, Manisha; Quintana, Jason C.; Tan, Mikayla F.; Kim, Danielle A.; Kwon, Ohyun. Related Products of 882-33-7. The article was titled 《Hydrodealkenylative C(sp3)-C(sp2) bond fragmentation》. The information in the text is summarized as follows:

1,1-Substituted alkenyl-substituted carbocycles such as I underwent chemoselective hydrodealkenylation of C(sp3)-C(sp2) bonds by treatment with O3 in MeOH at -78° followed by FeSO4 and PhSH with warming to ambient temperature to yield carbocycles such as II. The reactions are performed in nonanhydrous solvents and open to the air, are complete within 30 min, and deliver their products in high yields, even on decagram scales. The method was used for the conversion of terpenes to synthetic intermediates not easily available by other methods; five of the intermediates were used in formal syntheses of natural products and an unnatural steroid. Methylene carbocycles and endocyclic alkenes underwent oxidative cleavage to yield Me esters or lactones and 1,3-dioxolanes (after acetalization with ethylene glycol), resp. The results came from multiple reactions, including the reaction of 1,2-Diphenyldisulfane(cas: 882-33-7Related Products of 882-33-7)

1,2-Diphenyldisulfane(cas: 882-33-7) belongs to ethers.The C-O bonds that comprise simple ethers are strong. They are unreactive toward all but the strongest bases. Although generally of low chemical reactivity, they are more reactive than alkanes. Related Products of 882-33-7

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

HPLC of Formula: 882-33-7In 2019 ,《Sulfonyl Fluoride Synthesis through Electrochemical Oxidative Coupling of Thiols and Potassium Fluoride》 was published in Journal of the American Chemical Society. The article was written by Laudadio, Gabriele; Bartolomeu, Aloisio de A.; Verwijlen, Lucas M. H. M.; Cao, Yiran; de Oliveira, Kleber T.; Noel, Timothy. The article contains the following contents:

Sulfonyl fluorides are valuable synthetic motifs for a variety of applications, among which sulfur(VI) fluoride exchange-based “”click chem.”” is currently the most prominent. Consequently, the development of novel and efficient synthetic methods to access these functional groups is of great interest. Herein, the authors report a mild and environmentally benign electrochem. approach to prepare sulfonyl fluorides using thiols or disulfides, as widely available starting materials, in combination with KF, as an inexpensive, abundant and safe fluoride source. No addnl. oxidants nor addnl. catalysts are required and, due to mild reaction conditions, the reaction displays a broad substrate scope, including a variety of alkyl, benzyl, aryl and heteroaryl thiols or disulfides. The experimental part of the paper was very detailed, including the reaction process of 1,2-Diphenyldisulfane(cas: 882-33-7HPLC of Formula: 882-33-7)

1,2-Diphenyldisulfane(cas: 882-33-7) belongs to ethers.Although ethers resist hydrolysis, they are cleaved by hydrobromic acid and hydroiodic acid. Hydrogen chloride cleaves ethers only slowly. HPLC of Formula: 882-33-7

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

The author of 《Transition Metal-Free Oxidative Coupling of Primary Amines in Polyethylene Glycol at Room Temperature: Synthesis of Imines, Azobenzenes, Benzothiazoles, and Disulfides》 were Hudwekar, Abhinandan D.; Verma, Praveen K.; Kour, Jaspreet; Balgotra, Shilpi; Sawant, Sanghapal D.. And the article was published in European Journal of Organic Chemistry in 2019. Recommanded Product: 882-33-7 The author mentioned the following in the article:

A transition metal-free protocol has been developed for the oxidative coupling of primary amines to imines and azobenzenes, thiols to disulfides, and 2-aminothiophenols to benzothiazoles, offering excellent yields. The advantageous features of the present environmentally benign methodol. include the usage of biocompatible and green reaction conditions such as, solvent, room temperature reactions and transition metal-free approach. Moreover, it offers a broader substrate scope. In the part of experimental materials, we found many familiar compounds, such as 1,2-Diphenyldisulfane(cas: 882-33-7Recommanded Product: 882-33-7)

1,2-Diphenyldisulfane(cas: 882-33-7) belongs to ethers.Oxygen is more electronegative than carbon, thus the alpha hydrogens of ethers are more acidic than those of simple hydrocarbons. They are far less acidic than alpha hydrogens of carbonyl groups (such as in ketones or aldehydes), however. Recommanded Product: 882-33-7

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

《Visible-light induced decarboxylative coupling of redox-active esters with disulfides to construct C-S bonds》 was published in Chemical Communications (Cambridge, United Kingdom) in 2020. These research results belong to Xiao, Zhiwei; Wang, Lu; Wei, Junjie; Ran, Chongzhao; Liang, Steven H.; Shang, Jingjie; Chen, Guang-Ying; Zheng, Chao. COA of Formula: C12H10S2 The article mentions the following:

A novel method was established for the construction of C-S bonds using redox-active esters with disulfides in the presence of Ru-photoredox catalyst. This method exhibited remarkable functional group tolerance across a wide scope of substrates. Under mild conditions, a structurally diverse array of aryl alkyl sulfides was successfully and efficiently obtained through decarboxylative cross-coupling. In the part of experimental materials, we found many familiar compounds, such as 1,2-Diphenyldisulfane(cas: 882-33-7COA of Formula: C12H10S2)

1,2-Diphenyldisulfane(cas: 882-33-7) belongs to ethers.COA of Formula: C12H10S2Although ethers resist hydrolysis, they are cleaved by hydrobromic acid and hydroiodic acid. Hydrogen chloride cleaves ethers only slowly.

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

《Construction of sequence-defined polytriazoles by IrAAC and CuAAC reactions》 was published in Chemical Communications (Cambridge, United Kingdom) in 2020. These research results belong to Ju, Changhong; Meng, Congcong; Ma, Jiahao; Zhang, Xueyan; Ding, Shengtao. Application In Synthesis of 1,2-Diphenyldisulfane The article mentions the following:

Here we report the first synthesis of sequence-defined polytriazoles, in which different side groups are sequentially anchored to the C-5 position of 1,2,3-triazole rings. By using efficient synthetic strategies based on IrAAC and CuAAC, different monodispersed polytriazoles with up to ∼5.3 kDa and 31-mer were constructed. Structural characterization via NMR, SEC, MALDI-TOF-MS, tandem MS and FTICR-MS evidenced the formation of polytriazoles with the desired specified sequences and exact chain lengths.1,2-Diphenyldisulfane(cas: 882-33-7Application In Synthesis of 1,2-Diphenyldisulfane) was used in this study.

1,2-Diphenyldisulfane(cas: 882-33-7) belongs to ethers.Application In Synthesis of 1,2-DiphenyldisulfaneAlthough ethers resist hydrolysis, they are cleaved by hydrobromic acid and hydroiodic acid. Hydrogen chloride cleaves ethers only slowly.

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem