Category: 578-58-5

On June 8, 2021, Wang, Tao; Hoffmann, Marvin; Dreuw, Andreas; Hasagic, Edina; Hu, Chao; Stein, Philipp M.; Witzel, Sina; Shi, Hongwei; Yang, Yangyang; Rudolph, Matthias; Stuck, Fabian; Rominger, Frank; Kerscher, Marion; Comba, Peter; Hashmi, A. Stephen K. published an article.Application In Synthesis of 2-Methylanisole The title of the article was A Metal-Free Direct Arene C-H Amination. And the article contained the following:

Here, a metal-free arene e.g., mesitylene C-H amination using hydroxylamine derivatives 4-(CH3)C6H5S(O)2ON(R)R1 (R = H, Me; R1 = Me, Boc, Bn, etc.) under benign conditions was reported. A charge transfer interaction between the aminating reagents and the arene substrates enables the chemoselective amination of the arene, even in the presence of various functional groups. Oxygen was crucial for an effective conversion and its accelerating role for the electron transfer step was proven exptl. In addition, this was rationalized by a theor. study which indicated the involvement of a dioxygen-bridged complex with a “Sandwich-like” arrangement of the aromatic starting materials and the aminating agents at the dioxygen mol. The experimental process involved the reaction of 2-Methylanisole(cas: 578-58-5).Application In Synthesis of 2-Methylanisole

The Article related to aryl amine preparation chemoselective, arene hydroxylamine amination, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Amines, Amine Oxides, Imines, and Quaternary Ammonium Compounds and other aspects.Application In Synthesis of 2-Methylanisole

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On February 5, 2021, Zhao, Ke; Du, Yu; Peng, Qiong; Yu, Wen-Hao; Wang, Bi-Qin; Feng, Chun; Xiang, Shi-Kai published an article.Name: 2-Methylanisole The title of the article was Regiodivergent C-H Arylation of Triphenylene Derivatives Controlled by Electronic Effects of Diaryliodonium Salts. And the article contained the following:

A regiodivergent C-H arylation of triphenylene derivatives with diaryliodonium salts was developed. The regiodivergence was controlled by electronic effects of diaryliodonium salts. When the aryl(mesityl)iodonium salts bearing strong electron-donating groups at the para-position of aryl groups were used, the arylation reactions occurred ortho to amide groups. However, if the aryl(mesityl)iodonium salts bearing electron-withdrawing groups or weak electron-donating groups at the para-position of aryl groups were utilized, the arylation reactions occurred meta to amide groups. The experimental process involved the reaction of 2-Methylanisole(cas: 578-58-5).Name: 2-Methylanisole

The Article related to arylated triphenylene amide preparation regioselective, triphenylene amide diaryliodonium salt regiodivergent ch arylation copper catalyst, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Amines, Amine Oxides, Imines, and Quaternary Ammonium Compounds and other aspects.Name: 2-Methylanisole

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On December 17, 2021, Song, Yan-Ling; Li, Bei; Xie, Zhen-Biao; Wang, Dan; Sun, Hong-Mei published an article.Related Products of 578-58-5 The title of the article was Iron-Catalyzed Oxidative Amination of Benzylic C(sp3)-H Bonds with Anilines. And the article contained the following:

Iron-catalyzed oxidative amination of benzylic C(sp3)-H bonds with anilines bearing electron-withdrawing groups (EWGs) or electron-donating groups (EDGs) has been realized based on simple variations of N-substituents on imidazolium cations in novel ionic Fe(III) complexes. The structural modification of the imidazolium cation resulted in regulation of the redox potential and the catalytic performance of the iron metal center. Using DTBP as oxidant, [HItBu][FeBr4] (1,3-di-tert-butylimidazolium iron tetrabromide) showed the highest catalytic activity for anilines bearing EWGs, while [HIPym][FeBr4] (1,3-bis(pyrimidin-2-yl)imidazolium iron tetrabromide) was more efficient for EDG-substituted anilines. This work provides an alternative access to benzylamines, e.g., RN(R1)CH2Ph [R = 4-O2NC6H4, 2-pyrimidinyl, 8-isoquinolinyl, etc., R1 = H, Me,], with advantages of both a wide substrate scope and iron catalysis. The experimental process involved the reaction of 2-Methylanisole(cas: 578-58-5).Related Products of 578-58-5

The Article related to imidazolium iron complex catalyst preparation oxidative amination, benzylamine preparation, aniline benzylic hydrocarbon iron catalyst oxidative amination, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Amines, Amine Oxides, Imines, and Quaternary Ammonium Compounds and other aspects.Related Products of 578-58-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On July 7, 2022, Misael, Wilken A.; Pean, Emmanuel V.; Borges, Bruno Gabriel A. L.; Mello, Gabriela da Cruz; Wouk, Luana; Davies, Matthew L.; Roman, Lucimara S.; Rocco, Maria Luiza M. published an article.Category: ethers-buliding-blocks The title of the article was Molecular Orientation and Femtosecond Electron Transfer Dynamics in Halogenated and Nonhalogenated, Eco-Friendly Processed PTB7-Th, ITIC, PTB7-Th:ITIC, and PTB7-Th:PCBM Films. And the article contained the following:

Synergistic effects of the electronic structure and morphol. in the PTB7-Th polymer and the nonfullerene acceptor ITIC mol. resulted in state-of-art systems for organic solar cells, achieving over 12% power conversion efficiency (PCE) values. Furthermore, the substitution of harmful halogenated solvents to environmentally friendly solvents that do not compromise PCE values has become a subject of great interest in recent literature. In this work, we employed sulfur K-edge Angle-Resolved Near-Edge X-ray Absorption Fine Structure, Resonant Auger Spectroscopy, and the core-hole clock spectroscopy in an attempt to gain information on the effect of different processing methods on the electronic and morphol. properties of these systems. Comparison with the PTB7-Th:PCBM blend, which uses a conventional acceptor mol., was also performed. Steady-state and time-resolved photoluminescence results were obtained for neat PTB7-Th and blends with ITIC and PCBM. Theor. calculations were performed utilizing restricted-excitation-window time-dependent d. functional theory. Our results shows that ortho-methylanisole is a potential replacement to the conventional halogenated solvent ortho-dichlorobenzene, as they show that in terms of morphol. and charge transfer dynamics, no expressive changes occurred by varying the solvent and by thermal annealing. The experimental process involved the reaction of 2-Methylanisole(cas: 578-58-5).Category: ethers-buliding-blocks

The Article related to organic solar cell solvent charge transfer, Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes: Radiation Chemistry and Photochemistry and other aspects.Category: ethers-buliding-blocks

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On May 15, 2020, Verevkin, Sergey P.; Pimerzin, Andrey A.; Sun, Li-Xian published an article.Recommanded Product: 578-58-5 The title of the article was Structure-property relationships in substituted diphenyl ethers: Non-nearest interactions of methyl-, methoxy-, hydroxyl-, amino-, and nitro-substituents. And the article contained the following:

The standard molar enthalpies of formation, ΔfHom(liq/cr) of di-Ph ether substituted with nitro substituents were measured by the high-precision combustion calorimetry. Enthalpies of vaporisation/sublimation Δgl,crHom(298.15 K) of these compounds were obtained by the transpiration method. Enthalpies of fusion were measured by DSC. Gas-phase enthalpies of formation ΔfHom(g, 298.15 K) of substituted di-Ph ethers calculated by the G4 method were in an excellent agreement with the exptl. results. A set of thermodn. properties of di-Ph ether derivatives of benchmark quality was recommended for thermochem. calculations and for quantification of non-nearest interactions of methyl-, methoxy-, hydroxyl-, amino- and nitro-substituents on the di-Ph ether aromatic system. The experimental process involved the reaction of 2-Methylanisole(cas: 578-58-5).Recommanded Product: 578-58-5

The Article related to diphenyl methyl methoxy hydroxyl nitro ether structure property, Phase Equilibriums, Chemical Equilibriums, and Solutions: Other Chemical Equilibriums (Without Mechanistic Or Kinetic Interest) and other aspects.Recommanded Product: 578-58-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Zhu, Runqing; Sun, Qianqian; Li, Jing; Li, Luohao; Gao, Qinghe; Wang, Yakun; Fang, Lizhen published an article in 2021, the title of the article was para-selective hydroxylation of alkyl aryl ethers.Electric Literature of 578-58-5 And the article contains the following content:

Para-Selective hydroxylation of alkyl aryl ethers is established, which proceeds with a ruthenium(II) catalyst, hypervalent iodine(III) and trifluoroacetic anhydride via a radical mechanism. This protocol tolerates a wide scope of substrates and provides a facile and efficient method for preparing clin. drugs monobenzone and pramocaine on a gram scale. The experimental process involved the reaction of 2-Methylanisole(cas: 578-58-5).Electric Literature of 578-58-5

The Article related to alkyl aryl ether para hydroxylation regioselective, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Phenols, Thiophenols, and Derivatives Including Phenol and Thiophenol Ethers and Esters and other aspects.Electric Literature of 578-58-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On October 31, 2022, Kirihara, Masayuki; Sakamoto, Yugo; Yamahara, Sho; Kitajima, Atsuhito; Kugisaki, Naoki; Kimura, Yoshikazu published an article.Recommanded Product: 2-Methylanisole The title of the article was Aerobic Photooxidation of Toluene Derivatives into Carboxylic Acids with Bromine-Water under Catalyst-Free Conditions. And the article contained the following:

The photoirradiation of toluene derivatives with two equivalent of bromine in benzotrifluoride-water provided a satisfactory yield of the corresponding benzoic acid derivatives Either a fluorescent lamp, blue LED (454 nm), or UV LED (385 nm) was used for the photoreaction. The reaction pathway might proceed through the dibromination of benzylic carbon, generation of the benzylic radical via oxidative C-H abstraction, formation of benzoyl bromide, and hydrolysis of carboxylic acid. The experimental process involved the reaction of 2-Methylanisole(cas: 578-58-5).Recommanded Product: 2-Methylanisole

The Article related to benzoic acid preparation, toluene aerobic photooxidation bromine water catalyst free, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Carboxylic Acids and Peroxycarboxylic Acids and Their Sulfur-Containing Analogs and Salts and other aspects.Recommanded Product: 2-Methylanisole

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On June 22, 2021, Misal, Balu; Palav, Amey; Ganwir, Prerna; Chaturbhuj, Ganesh published an article.HPLC of Formula: 578-58-5 The title of the article was Sulfated polyborate-H2O assisted tunable activation of N-iodosuccinimide for expeditious mono and diiodination of arenes. And the article contained the following:

Owing to both Lewis and Bronsted acid active sites on sulfated polyborate under homogeneous conditions, iodination protocol of arenes was developed, which can meet the requirement of regioselectivity and higher yield. The sulfated polyborate activated N-iodosuccinimide for mono iodination of highly activated substrates viz. phenols, anilines under anhydrous condition. Water tuned sulfated polyborate to generate more Bronsted acid sites resulting in rapid activation of NIS for diiodination. The protocol was equally applicable to diiodination of 4-hydroxyphenylacetic acid to synthesize 4-hydroxy-3,5-diiodophenylacetic acid, an intermediate of tiratricol, a thyroid treatment drug. This protocol was further integrated via one-pot sequential iodination and Sonogashira coupling to synthesize aryl acetylenes, building blocks for the synthesis of a variety of specialty chems., API and natural products. The experimental process involved the reaction of 2-Methylanisole(cas: 578-58-5).HPLC of Formula: 578-58-5

The Article related to arene iodosuccinimide sulfated polyborate catalyst regioselective iodination, iodoarene preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Phenols, Thiophenols, and Derivatives Including Phenol and Thiophenol Ethers and Esters and other aspects.HPLC of Formula: 578-58-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On May 15, 2020, Wang, Jing-Hao; Lei, Tao; Wu, Hao-Lin; Nan, Xiao-Lei; Li, Xu-Bing; Chen, Bin; Tung, Chen-Ho; Wu, Li-Zhu published an article.Category: ethers-buliding-blocks The title of the article was Thiol Activation toward Selective Thiolation of Aromatic C-H Bond. And the article contained the following:

An effective model for regioselective thiolation of the aromatic C-H bond by thiol activation instead of arene activation was disclosed. This method was applied into anisole derivatives that are not available in the arene activation approach to forge a single thioether isomer with high reactivity. The experimental process involved the reaction of 2-Methylanisole(cas: 578-58-5).Category: ethers-buliding-blocks

The Article related to thiophenol aryl ether regioselective electrochem thiolation, diaryl thioether preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Phenols, Thiophenols, and Derivatives Including Phenol and Thiophenol Ethers and Esters and other aspects.Category: ethers-buliding-blocks

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On September 30, 2021, Wang, Chang-Cheng; Zhang, Guo-Xiang; Zuo, Zhi-Wei; Zeng, Rong; Zhai, Dan-Dan; Liu, Feng; Shi, Zhang-Jie published an article.Safety of 2-Methylanisole The title of the article was Photo-induced deep aerobic oxidation of alkyl aromatics. And the article contained the following:

In this report, e.g., photo-induced deep aerobic oxidation of (poly)alkyl benzene toluene to benzene (poly)carboxylic acids e.g., benzoic acid was developed. CeCl3 was proved to be an efficient HAT (hydrogen atom transfer) catalyst in the presence of alc. as both hydrogen and electron shuttle. Dioxygen (O2) was found as a sole terminal oxidant. In most cases, pure products were easily isolated by simple filtration, implying large-scale implementation advantages. The reaction provides an ideal protocol to produce valuable fine chems. from naturally abundant petroleum feedstocks. The experimental process involved the reaction of 2-Methylanisole(cas: 578-58-5).Safety of 2-Methylanisole

The Article related to benzene polycarboxylic acid preparation green chem, polyalkyl benzene photo aerobic oxidation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Carboxylic Acids and Peroxycarboxylic Acids and Their Sulfur-Containing Analogs and Salts and other aspects.Safety of 2-Methylanisole

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem