Category: 578-58-5

On June 22, 2022, Zhang, Qingyu; Xu, Yongyuan; Liang, Xiaochen; Ke, Zhihai published an article.Recommanded Product: 2-Methylanisole The title of the article was Amphiphilic indoles as efficient phase-transfer green catalysts for bromination in water. And the article contained the following:

Brominated compounds are important, but they are usually prepared in organic solvents. Here, efficient amphiphilic indole-based phase-transfer organocatalysts were developed for environmentally benign bromination reactions in water. As test reactions, hydroxybromination of olefins and aromatic bromination could be conducted in a greener and more sustainable manner compared with methods using organic solvents, producing the corresponding bromides in good yields. Some pure products could be obtained without column chromatog. The experimental process involved the reaction of 2-Methylanisole(cas: 578-58-5).Recommanded Product: 2-Methylanisole

The Article related to amphiphilic indole green phase transfer catalyst bromination, bromination, green chemistry, halogenation, indoles, phase-transfer catalysis, Placeholder for records without volume info and other aspects.Recommanded Product: 2-Methylanisole

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Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

D′Auria, Maurizio; Racioppi, Rocco published an article in 2022, the title of the article was Characterization of the volatile fraction of mastic oil and mastic gum.Formula: C8H10O And the article contains the following content:

GC-MS of Et acetate solutions and HS-SPME-GC-MS of mastic oil and mastic gum showed the presence of α-pinene and β-myrcene as main components of the mixture In the GC-MS anal. of mastic oil 19 compounds were detected, while mastic gum allowed to detect only twelve compounds Mastic gum showed the presence of compounds with a higher mol. weight In HS-SPME anal. the amount of β-myrcene increased in comparison to the results obtained in the analyses performed in solution The relative ratio between α-pinene and β-myrcene showed that SPME anal. induces a preferential detection for β-myrcene (α-pinene/β-myrcene in the mastic oil 16.18 in GC-MS anal., and 5.06 in SPME anal.; α-pinene/β-myrcene in mastic gum 10.64 in GC-MS anal., and 2.25 in SPME anal.). These results can be explained considering a different absorption selectivity of these compounds on the SPME fiber. The experimental process involved the reaction of 2-Methylanisole(cas: 578-58-5).Formula: C8H10O

The Article related to mastic oil gum, mastic oil, gas chromatography – mass spectrometry, mastic gum, solid phase microextraction, Placeholder for records without volume info and other aspects.Formula: C8H10O

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Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On October 1, 2021, Ahemed, Jakeer; Pasha, Jakeer; Rao D, Venkateshwar; Kore, Ranjith; Gade, Ramesh; Bhongiri, Yadagiri; Chetti, Prabhakar; Pola, Someshwar published an article.Reference of 2-Methylanisole The title of the article was Synthesis of new Zn (II) complexes for photo decomposition of organic dye pollutants, industrial wastewater and photo-oxidation of methyl arenes under visible-light. And the article contained the following:

Synthesis of new Schiff′s base Zn-complexes for photo-oxidation of Me arenes and xylenes are reported under visible light irradiation conditions. All the synthesized new ligands and Zn-complexes are thoroughly characterized with various spectral analyses and confirmed as 1:1 ratio of Zn and ligand with distorted octahedral structure. The bandgap energies of the ligands are higher than its Zn-complexes. These synthesized new Zn(II) complexes are used for the photo-fragmentation of organic dye pollutants, photodegradation of food industrial wastewater and oxidation of Me arenes which are converted into its resp. aldehydes with moderate yields under visible light irradiation The photooxidation reaction dependency on the intensity of the visible light was also studied. With the increase in the dosage of photocatalyst, the Me groups are oxidized to get aldehydes and mono acid products, which are also identified from LC-MS data. Finally, [Zn(PPMHT)Cl] is with better efficiency than [Zn(PTHMT)Cl] and [Zn(MIMHPT)Cl] for oxidation of Me arenes is reported under visible-light-driven conditions. The experimental process involved the reaction of 2-Methylanisole(cas: 578-58-5).Reference of 2-Methylanisole

The Article related to zinc methyl arene odp industrial wastewater photooxidation photodecomposition, Placeholder for records without volume info and other aspects.Reference of 2-Methylanisole

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Ether – Wikipedia,
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On September 26, 2022, Yang, Tao; Li, Xiaoqian; Deng, Shuang; Qi, Xiaotian; Cong, Hengjiang; Cheng, Hong-Gang; Shi, Liangwei; Zhou, Qianghui; Zhuang, Lin published an article.Electric Literature of 578-58-5 The title of the article was From N-H Nitration to Controllable Aromatic Mononitration and Dinitration-The Discovery of a Versatile and Powerful N-Nitropyrazole Nitrating Reagent. And the article contained the following:

Herein,the identification of a powerful nitrating reagent, 5-methyl-1,3-dinitro-1H-pyrazole, from the N-nitro-type reagent library constructed using a practical N-H nitration method was reported. This nitrating reagent behaved as a controllable source of the nitronium ion, enabling mild and scalable nitration of a broad range of (hetero)arenes with good functional group tolerance. Of note, this nitration method was controlled by manipulating the reaction conditions to furnish mononitrated or dinitrated product selectively. The value of this method in medicinal chem. was well established by its efficient late-stage C-H nitration of complex biorelevant mols. D. functional theory (DFT) calculations and preliminary mechanistic studies reveal that the powerfulness and versatility of this nitrating reagent were due to the synergistic “nitro effect” and “methyl effect”. The experimental process involved the reaction of 2-Methylanisole(cas: 578-58-5).Electric Literature of 578-58-5

The Article related to arene nitropyrazole nitration, nitroarene preparation, General Organic Chemistry: Synthetic Methods and other aspects.Electric Literature of 578-58-5

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Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On February 29, 2020, Song, Song; Li, Xinyao; Wei, Jialiang; Wang, Weijin; Zhang, Yiqun; Ai, Lingsheng; Zhu, Yuchao; Shi, Xiaomeng; Zhang, Xiaohui; Jiao, Ning published an article.Application of 578-58-5 The title of the article was DMSO-catalysed late-stage chlorination of (hetero)arenes. And the article contained the following:

A highly efficient aromatic chlorination of arenes such as 1-methyl-indazole, imidazo[1,2-a]pyrazine, phenylthiophene, anthracene, etc. that is catalyzed by DMSO with N-chlorosuccinimide as the chloro source is reported. The mild conditions, easy-availability and stability of the catalyst and reagents, as well as good functional-group tolerance, showed the approach to be a versatile protocol for the late-stage aromatic chlorination of complex natural products, e.g., papaverine, drugs, e.g., diclofenac and peptides, e.g., I. The multi-gram experiment and low-cost of N-chlorosuccinimide and DMSO show great potential for drug discovery and development in industrial applications. The experimental process involved the reaction of 2-Methylanisole(cas: 578-58-5).Application of 578-58-5

The Article related to arene heteroarene chlorination dimethyl sulfoxide catalyst, General Organic Chemistry: Synthetic Methods and other aspects.Application of 578-58-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Burrows, James; Kamo, Shogo; Koide, Kazunori published an article in 2021, the title of the article was Scalable Birch reduction with lithium and ethylenediamine in tetrahydrofuran.SDS of cas: 578-58-5 And the article contains the following content:

A Birch reduction promoted by lithium and ethylenediamine (or analogs) in THF at ambient temperature were reported. This method is easy to set up, inexpensive, scalable, rapid, accessible to any chem. laboratory and capable of reducing both electron-rich and electron-deficient substrates. This protocol is also compatible with organocuprate chem. for further functionalization. The experimental process involved the reaction of 2-Methylanisole(cas: 578-58-5).SDS of cas: 578-58-5

The Article related to arene lithium ethylenediamine birch reduction, fused cyclohexadiene preparation, General Organic Chemistry: Synthetic Methods and other aspects.SDS of cas: 578-58-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On October 1, 2021, Griffiths, Oliver M.; Esteves, Henrique A.; Chen, Yiding; Sowa, Karin; May, Oliver S.; Morse, Peter; Blakemore, David C.; Ley, Steven V. published an article.HPLC of Formula: 578-58-5 The title of the article was Photoredox-Catalyzed Dehydrogenative Csp3-Csp2 Cross-Coupling of Alkylarenes to Aldehydes in Flow. And the article contained the following:

Herein, the transfer of photoredox-catalyzed benzylic coupling of alkylarenes such as 4-methylanisole, tert-Bu 3-methyl-1H-indole-1-carboxylate, 2-methylfuran, etc. to aldehydes RCHO (R = pentyl, dec-9-en-1-yl, cyclopentyl, 1-[(tert-butoxy)carbonyl]piperidin-4-yl, etc.) to a flow chem. setting leading to improvements in terms of higher concentration, shorter residence times, better yields, ease of catalyst preparation, and enhanced substrate scope have been reported. Its applicability has been demonstrated by a multi-gram-scale reaction using high-power light-emitting diodes (LEDs), late-stage functionalization of selected active pharmaceutical ingredients (APIs), e.g., I, and also a photocatalyst recycling method. The experimental process involved the reaction of 2-Methylanisole(cas: 578-58-5).HPLC of Formula: 578-58-5

The Article related to aralkyl ketone preparation, alkylarene aldehyde dehydrogenative cross coupling photoredox iridium complex catalyst, General Organic Chemistry: Synthetic Methods and other aspects.HPLC of Formula: 578-58-5

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Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Washington, Jack B.; Assante, Michele; Yan, Chunhui; McKinney, David; Juba, Vanessa; Leach, Andrew G.; Baillie, Sharon E.; Reid, Marc published an article in 2021, the title of the article was Trialkylammonium salt degradation: implications for methylation and cross-coupling.Recommanded Product: 2-Methylanisole And the article contains the following content:

This study presented a mechanistic degradation anal. of N,N,N-trimethylanilinium salts and highlighted implications for synthetic applications of this important class of salts. Kinetic degradation studies, in both solid and solution phases, had delivered insights into phys. and chem. parameters affecting anilinium salt stability. 1H NMR kinetic anal. of salt degradation had evidenced thermal degradation to Me iodide and parent aniline, consistent with a closed-shell SN2-centered degradative pathway, and Me iodide being key reactive species in applied methylation procedures. Furthermore, effect of halide and non-nucleophilic counterions on salt degradation had been investigated, along with deuterium isotope and solvent effects. New mechanistic insights had enabled investigation of use of trimethylanilinium salts in O-methylation and in improved cross-coupling strategies. Finally, detailed computational studies had helped highlight limitations in current state-of-the-art of solvation modeling of reaction in which bulk medium undergoes exptl. observable changes over reaction timecourse. The experimental process involved the reaction of 2-Methylanisole(cas: 578-58-5).Recommanded Product: 2-Methylanisole

The Article related to trialkylammonium salt preparation degradation reaction mechanism dft, methoxy hydrocarbon preparation, alc acid phenol trimethylanilinium salt methylation, General Organic Chemistry: Synthetic Methods and other aspects.Recommanded Product: 2-Methylanisole

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On September 3, 2021, Palav, Amey; Misal, Balu; Chaturbhuj, Ganesh published an article.Recommanded Product: 2-Methylanisole The title of the article was NCBSI/KI: A Reagent System for Iodination of Aromatics through In Situ Generation of I-Cl. And the article contained the following:

In-situ iodine monochloride (I-Cl) generation followed by iodination of aromatics using NCBSI/KI system was developed. The NCBSI reagent required no activation due to longer bond length, lower bond dissociation energy, and higher absolute charge d. on nitrogen. The system was adequate for mono- and diiodination of a wide range of moderate to highly activated arenes with good yield and purity. Moreover, the precursor N-(benzenesulfonyl)benzenesulfonamide was recovered and transformed to NCBSI and made the protocol eco-friendly and cost-effective. The experimental process involved the reaction of 2-Methylanisole(cas: 578-58-5).Recommanded Product: 2-Methylanisole

The Article related to arene chlorophenylsulfonyl benzenesulfonamide potassium iodide iodination green chem, iodoarene preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Halides and Halonium Compounds and other aspects.Recommanded Product: 2-Methylanisole

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Xia, Wen-Jin; Xin, Yangchun; Zhao, Zhi-Wei; Chen, Xin; Wang, Xiang-Xiang; Li, Yi; Wang, Guanlin; Li, Ya-Min published an article in 2020, the title of the article was Oxidative cascade cyclization of 2-cyano-3-arylaniline derived acrylamides with toluenes, ethers, aliphatic alcohols or simple alkanes.Application In Synthesis of 2-Methylanisole And the article contains the following content:

An oxidative radical cascade cyclization of 2-cyano-3-arylaniline-derived acrylamides I (R1 = H, 3-Me, 4-CN, 3,5-Cl2, etc.; R2 = Me, PhCH2; R3 = Me, Ph, PhCH2) with hydrocarbons, e.g., toluene, THF, cyclohexane, etc., is described. The present reaction exhibited a wide substrate scope, and toluenes, ethers, aliphatic alcs. and simple alkanes were employed as coupling partners, providing access to alkyl-substituted pyrido[4,3,2-gh]phenanthridines, e.g., II from toluene. The experimental process involved the reaction of 2-Methylanisole(cas: 578-58-5).Application In Synthesis of 2-Methylanisole

The Article related to arylcyanophenyl acrylamide cascade radical oxidative cyclization hydrocarbon, alkyl pyridophenanthridine preparation, Heterocyclic Compounds (More Than One Hetero Atom): Other 6-Membered Rings, Two Hetero Atoms and other aspects.Application In Synthesis of 2-Methylanisole

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem