Category: 53136-21-3

On December 19, 2005, Salvatore, Ralph Nicholas; Smith, Robert A.; Nischwitz, Adam K.; Gavin, Terrence published an article.Computed Properties of 53136-21-3 The title of the article was A mild and highly convenient chemoselective alkylation of thiols using Cs2CO3-TBAI. And the article contained the following:

A mild and improved method for the synthesis of thioethers has been developed. In the presence of cesium carbonate, tetrabutylammonium iodide, and DMF, various alkyl and aryl thiols underwent S-alkylation to afford structurally diverse sulfides in high yield. Unprotected mercapto alcs. and thio amines reacted chemoselectively at the sulfur moiety exclusively. An example of a one-pot, solid-phase synthesis of a thioether is also described. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Computed Properties of 53136-21-3

The Article related to cesium carbonate tetrabutylammonium iodide alkylation thiol, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Phenols, Thiophenols, and Derivatives Including Phenol and Thiophenol Ethers and Esters and other aspects.Computed Properties of 53136-21-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On May 16, 2014, Li, Yiming; Pu, Jiahua; Jiang, Xuefeng published an article.Recommanded Product: Benzyl(4-bromophenyl)sulfane The title of the article was A Highly Efficient Cu-Catalyzed S-Transfer Reaction: From Amine to Sulfide. And the article contained the following:

A highly efficient Cu-catalyzed dual C-S bonds formation reaction, proceeding in alc. and water under air, is reported, in which inodorous stable Na2S2O3 is used as a sulfurating reagent. This powerful strategy provides a practical and efficient approach to construct thioethers, using readily available aromatic amines and alkyl halides as starting materials. Sensitive and synthetic useful functional groups could be tolerated. Furthermore, pharmaceuticals, glucose, an amino acid, and a chiral ligand are successfully furnished by this late-stage sulfuration strategy. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Recommanded Product: Benzyl(4-bromophenyl)sulfane

The Article related to thioether preparation dual carbon sulfur bond formation copper catalyst, aromatic amine alkyl halide sulfuration sodium thiosulfate sulfurating reagent, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Phenols, Thiophenols, and Derivatives Including Phenol and Thiophenol Ethers and Esters and other aspects.Recommanded Product: Benzyl(4-bromophenyl)sulfane

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On December 6, 2004, Jeong, Yong-Chul; Choi, Soojin; Hwang, Yao Dong; Ahn, Kwang-Hyun published an article.Recommanded Product: Benzyl(4-bromophenyl)sulfane The title of the article was Enantioselective oxidation of sulfides with hydrogen peroxide catalyzed by vanadium complex of sterically hindered chiral Schiff bases. And the article contained the following:

Sterically hindered chiral Schiff base ligands were prepared from an aldehyde derived from BINOL. The vanadium complexes of the ligands catalyzed an efficient, enantioselective H2O2-promoted sulfoxidation of alkyl aryl sulfides to give sulfoxides, e.g., I, in high enantioselectivities. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Recommanded Product: Benzyl(4-bromophenyl)sulfane

The Article related to hydrogen peroxide aryl sulfide oxidation vanadium chiral binaphthylimino alc, aryl sulfoxide asym preparation, vanadium chiral binaphthylimino alc asym oxidation catalyst and other aspects.Recommanded Product: Benzyl(4-bromophenyl)sulfane

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Lu, Fangling; Chen, Ziyue; Li, Zhen; Wang, Xiaoyan; Peng, Xinyue; Li, Cong; Li, Ru; Pei, Hongqiao; Wang, Huamin; Gao, Meng published an article in 2018, the title of the article was Copper-catalyzed alkylation of thiophenols with benzyltrimethylammonium triflates.Product Details of 53136-21-3 And the article contains the following content:

A copper-catalyzed cross coupling of thiophenols with benzyltrimethylammonium triflates was developed. Various kinds of aryl and heteroaryl thiophenols and alkylthiols demonstrated to be efficient substrates, generating the desired alkyl thioethers RSCH2R1 [R = 4-MeC6H4, CH2C6H5, 2-naphthyl, etc.; R1 = Ph, 2-MeC6H4, 4-BrC6H4, etc.] in moderate to good yields. Meanwhile, different benzyltrimethylammonium triflates could be well tolerated. Selected thioether products were further transformed into sulfoxide R2S(O)R3 [R2 = 4-MeC6H4, 4-ClC6H4, 4-BrC6H4, etc.; R3 = Ph, 4-MeC6H4, 2-IC6H4, etc.] with good efficiency. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Product Details of 53136-21-3

The Article related to aryl benzyl sulfoxide preparation, alkyl thioether reactant aryl benzyl sulfoxide preparation, thiophenol benzyltrimethylammonium triflate copper catalyst cross coupling alkylation and other aspects.Product Details of 53136-21-3

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Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Durka, Krzysztof; Klis, Tomasz; Serwatowski, Janusz; Wozniak, Krzysztof published an article in 2011, the title of the article was Functionalization of some benzylthioarylboronic acids by benzylic lithiation of their N-butyldiethanolamine esters or lithium (triisopropoxy)borates.Quality Control of Benzyl(4-bromophenyl)sulfane And the article contains the following content:

The reaction of benzylthioarylboronic acids protected as N-butyldiethanolamine esters or as triisopropoxyborates with organolithium bases or lithium diisopropylamide (LDA) has been investigated. The benzylic lithiation occurs selectively using LDA at -68掳. The stability of the resultant borio-lithio intermediates is strongly influenced by the position of the boron atom in the Ph ring. The reaction with various electrophiles affords new arylboronic acids substituted in the benzylic position. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Quality Control of Benzyl(4-bromophenyl)sulfane

The Article related to functionalization benzylthioarylboronic acid butyldiethanolamine ester triisopropoxyborate benzylic lithiation, silyl ethylthiomethyl phenylboronic acid preparation crystal mol structure and other aspects.Quality Control of Benzyl(4-bromophenyl)sulfane

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Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Schwertz, Geoffrey; Frei, Michelle S.; Witschel, Matthias C.; Rottmann, Matthias; Leartsakulpanich, Ubolsree; Chitnumsub, Penchit; Jaruwat, Aritsara; Ittarat, Wanwipa; Schaefer, Anja; Aponte, Raphael A.; Trapp, Nils; Mark, Kerstin; Chaiyen, Pimchai; Diederich, Francois published an article in 2017, the title of the article was Conformational Aspects in the Design of Inhibitors for Serine Hydroxymethyltransferase (SHMT): Biphenyl, Aryl Sulfonamide, and Aryl Sulfone Motifs.Computed Properties of 53136-21-3 And the article contains the following content:

Malaria remains a major threat to mankind due to the perpetual emergence of resistance against marketed drugs. Twenty-one pyrazolopyran-based inhibitors bearing terminal biphenyl, aryl sulfonamide, or aryl sulfone motifs were synthesized and tested towards serine hydroxymethyltransferase (SHMT), a key enzyme of the folate cycle. The best ligands inhibited Plasmodium falciparum (Pf) and Arabidopsis thaliana (At) SHMT in target, as well as PfNF54 strains in cell-based assays in the low nanomolar range (18-56 nM). Seven cocrystal structures with P. vivax (Pv) SHMT were solved at 2.2-2.6 脜 resolution The authors observed an unprecedented influence of the torsion angle of ortho-substituted biphenyl moieties on cell-based efficacy. The peculiar lipophilic character of the sulfonyl moiety was highlighted in the complexes with aryl sulfonamide analogs, which bind in their preferred staggered orientation. The results are discussed within the context of conformational preferences in the ligands. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Computed Properties of 53136-21-3

The Article related to conformation sulfonamide serine hydroxymethyltransferase inhibitor, crystal structure, co-crystal structures, conformation analysis, drug design, plasmodium, serine hydroxymethyltransferase and other aspects.Computed Properties of 53136-21-3

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Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On October 18, 2002, Capozzi, Maria Annunziata M.; Cardellicchio, Cosimo; Naso, Francesco; Rosito, Valerio published an article.Safety of Benzyl(4-bromophenyl)sulfane The title of the article was A Straightforward Enantioselective Route to Dialkyl Sulfoxides Based upon Two Carbon-for-Carbon Substitution Reactions on the Sulfinyl Group. And the article contained the following:

(R)-Benzyl p-bromophenyl sulfoxide (I) was obtained on a multigram scale and in an enantiomerically pure form by enantioselective catalytic oxidation of benzyl p-bromophenyl sulfide with tert-Bu hydroperoxide in the presence of chiral titanium complexes. Some mechanistic and stereochem. features of the process were also studied. I was then subjected to two consecutive substitution reactions with different Grignard reagents, which caused two sequentially stereocontrolled carbon-for-carbon displacements, leading to chiral nonracemic dialkyl sulfoxides. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Safety of Benzyl(4-bromophenyl)sulfane

The Article related to sulfoxide dialkyl chiral enantioselective preparation, sulfide benzyl bromophenyl chiral titanium complex catalyzed enantioselective oxidation, benzylsulfoxide bromophenyl preparation stereoselective grignard substitution and other aspects.Safety of Benzyl(4-bromophenyl)sulfane

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Sharghi, Hashem; Ghaderi, Iman; Doroodmand, Mohammad Mahdi published an article in 2017, the title of the article was Eco-compatible three component strategies for C-S bond formation in thioether and S-aryl-carbamodithioate compounds catalyzed by copper(II) nanoparticles supported on modified AlPO4.Safety of Benzyl(4-bromophenyl)sulfane And the article contains the following content:

One-pot and three components C-S bond formation reactions in thioethers ArCH(X)SAr1 (Ar = C6H5, 4-BrC6H4, 4-H2C=CHC6H4; X = H, CH3; Ar1 = C6H5, 4-CH3C6H4, 4-ClC6H4, etc.) and S-aryl-carbamodithioates YC(S)SAr1 (Y = morpholinyl, piperidinyl, (diethylamino), etc.) have been catalyzed by a copper heterogeneous nano-catalyst supported on modified AlPO4 under different reaction conditions. The above-mentioned nano-catalyst has been characterized by various techniques such as SEM, TEM, AFM, XRD, FT-IR, UV-Vis, CV, BET, TGA, ICP and XPS spectrometry and its particle size was estimated to be between 60-110 nm. Finally, the reusability of the catalyst up to ten cycles without any significant leaching is one of the outstanding properties of the catalyst. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Safety of Benzyl(4-bromophenyl)sulfane

The Article related to thioether preparation green chem, thiourea arylhalide benzyl halide three component copper nanocatalyst, dithiocarbamate aryl preparation green chem, secondary amine carbon disulfide aryliodide three component copper nanocatalyst and other aspects.Safety of Benzyl(4-bromophenyl)sulfane

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On October 18, 2002, Capozzi, Maria Annunziata M.; Cardellicchio, Cosimo; Naso, Francesco; Rosito, Valerio published an article.Safety of Benzyl(4-bromophenyl)sulfane The title of the article was A Straightforward Enantioselective Route to Dialkyl Sulfoxides Based upon Two Carbon-for-Carbon Substitution Reactions on the Sulfinyl Group. And the article contained the following:

(R)-Benzyl p-bromophenyl sulfoxide (I) was obtained on a multigram scale and in an enantiomerically pure form by enantioselective catalytic oxidation of benzyl p-bromophenyl sulfide with tert-Bu hydroperoxide in the presence of chiral titanium complexes. Some mechanistic and stereochem. features of the process were also studied. I was then subjected to two consecutive substitution reactions with different Grignard reagents, which caused two sequentially stereocontrolled carbon-for-carbon displacements, leading to chiral nonracemic dialkyl sulfoxides. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Safety of Benzyl(4-bromophenyl)sulfane

The Article related to sulfoxide dialkyl chiral enantioselective preparation, sulfide benzyl bromophenyl chiral titanium complex catalyzed enantioselective oxidation, benzylsulfoxide bromophenyl preparation stereoselective grignard substitution and other aspects.Safety of Benzyl(4-bromophenyl)sulfane

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Sharghi, Hashem; Ghaderi, Iman; Doroodmand, Mohammad Mahdi published an article in 2017, the title of the article was Eco-compatible three component strategies for C-S bond formation in thioether and S-aryl-carbamodithioate compounds catalyzed by copper(II) nanoparticles supported on modified AlPO4.Safety of Benzyl(4-bromophenyl)sulfane And the article contains the following content:

One-pot and three components C-S bond formation reactions in thioethers ArCH(X)SAr1 (Ar = C6H5, 4-BrC6H4, 4-H2C=CHC6H4; X = H, CH3; Ar1 = C6H5, 4-CH3C6H4, 4-ClC6H4, etc.) and S-aryl-carbamodithioates YC(S)SAr1 (Y = morpholinyl, piperidinyl, (diethylamino), etc.) have been catalyzed by a copper heterogeneous nano-catalyst supported on modified AlPO4 under different reaction conditions. The above-mentioned nano-catalyst has been characterized by various techniques such as SEM, TEM, AFM, XRD, FT-IR, UV-Vis, CV, BET, TGA, ICP and XPS spectrometry and its particle size was estimated to be between 60-110 nm. Finally, the reusability of the catalyst up to ten cycles without any significant leaching is one of the outstanding properties of the catalyst. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Safety of Benzyl(4-bromophenyl)sulfane

The Article related to thioether preparation green chem, thiourea arylhalide benzyl halide three component copper nanocatalyst, dithiocarbamate aryl preparation green chem, secondary amine carbon disulfide aryliodide three component copper nanocatalyst and other aspects.Safety of Benzyl(4-bromophenyl)sulfane

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem