Category: 53136-21-3

On May 14, 2014, Jiang, Xuefeng; Li, Yiming published a patent.Application of 53136-21-3 The title of the patent was Aryl alkyl thioether compound and its preparation. And the patent contained the following:

The invention relates to aryl alkyl thioether compound of Ar-S-CH2-R and its preparation The method includes: in a reaction solvent (methanol, ethanol, etc.), using arylamine derivative and haloalkane as starting materials, and Na2S2O3 as vulcanization reagent, under the action of copper catalyst (copper sulfate, copper nitrate, etc.), reacting to obtain aryl alkyl thioether compound The inventive synthesis method has easily-accessible and cheap starting materials, simple reaction operation, mild reaction conditions, high yield, and excellent functional group tolerance. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Application of 53136-21-3

The Article related to aryl alkyl thioether preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Application of 53136-21-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Miyazaki, Takahiro; Kasai, Shinsei; Ogiwara, Yohei; Sakai, Norio published an article in 2016, the title of the article was Indium-Catalyzed Reductive Sulfidation of Esters by Using Thiols: An Approach to the Diverse Synthesis of Sulfides.Category: ethers-buliding-blocks And the article contains the following content:

A new reductive preparation of unsym. sulfides (i.e., thioethers) from esters and thiols in the presence of InI3 and either 1,1,3,3-tetramethyldisiloxane (TMDS) or PhSiH3 as the reductant was developed. This protocol was applied to not only benzoic acid esters that have a methoxy, Me, chloro, bromo, iodo, or trifluoromethyl group on the aromatic ring but also aliphatic acid esters with either aromatic or aliphatic thiols. A reaction mechanism is proposed by using Hammett plot results and several control experiments The synthesis of the target compounds was achieved using indium iodide (InI3) or indium bromide (InBr3) as catalysts. Starting materials included benzoic acid Me ester derivatives, benzenepropanoic acid 4-chlorophenyl ester, benzenepropanoic acid Ph ester, 1-naphthalenepropanoic acid Ph ester, benzeneacetic acid Me ester derivatives Thiol reactants included benzenethiol derivatives, benzenemethanethiol, 1-octanethiol. The title compounds thus formed included thioethers (sulfides), such as 1-methyl-4-[(phenylmethyl)thio]benzene, [2-(octylthio)ethyl]benzene, 1-methyl-4-[(3-phenylpropyl)thio]benzene. 2-[3-(Octylthio)propyl]phenol was formed from octanethiol and 3,4-dihydro-2H-1-benzopyran-2-one (i.e., hydrocoumarin). The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Category: ethers-buliding-blocks

The Article related to sulfide thioether preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Category: ethers-buliding-blocks

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Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On July 31, 2006, Zhan, Zhuang-Ping; Lang, Kai published an article.Recommanded Product: Benzyl(4-bromophenyl)sulfane The title of the article was A novel one pot synthesis of benzyl sulfides: samarium-induced, benzyl bromide mediated reduction of alkyl thiocyanates and diaryl disulfides in methanol. And the article contained the following:

A convenient synthesis of benzyl sulfides by the treatment of alkyl thiocyanates or diaryl disulfides with metallic Sm and benzyl bromide in MeOH was developed. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Recommanded Product: Benzyl(4-bromophenyl)sulfane

The Article related to reduction alkyl thiocyanate aryl disulfide samarium reducing agent, benzyl bromide mediated reduction thiocyanate disulfide preparation sulfide, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Recommanded Product: Benzyl(4-bromophenyl)sulfane

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Xu, Bo; Liu, Wei; Kuang, Chunxiang published an article in 2014, the title of the article was Palladium-Catalyzed C-H Acylation of Arenes Using Thioethers as Directing Groups.SDS of cas: 53136-21-3 And the article contains the following content:

A highly efficient protocol for regioselective synthesis of diaryl ketones by palladium-catalyzed direct acylation of arenes using thioethers as directing groups is reported. The possible pathway of direct acylation between thioethers and α-oxocarboxylic acids is discussed. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).SDS of cas: 53136-21-3

The Article related to diaryl ketone preparation regioselective acylation arene thioether directing group, palladium catalyzed carbon hydrogen acylation thioether alpha oxocarboxylic acid, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ketones and Derivatives, Including Quinones and Sulfur Analogs and other aspects.SDS of cas: 53136-21-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On February 16, 2017, Gao, Chunji; Zhang, Chengcheng; Li, Guoqiang; Hu, Xiaoming; Cui, Dunzhu published a patent.Name: Benzyl(4-bromophenyl)sulfane The title of the patent was Preparation of aromatic amine compound and their application as light-emitting devices. And the patent contained the following:

The invention is related to the preparation of aromatic amine compound I and their application as light-emitting devices. The invention provides an aromatic amine compound I, wherein R1-R4 are independent H, halo, cyano, C1-C30 alkyl, C6-C50 aryl, C7-C50 arylalkyl, C7-50 aryl alkoxy, C7-50 arylalkyl-thiol, or C5-50 heteroaryl; and Ar1 and Ar2 are independently selected from C6-50 arylidene; are claimed. Compound I was prepared by multi-step procedure (procedure given). The inventive aromatic amine compound(current efficiency reaching 6.7 cd/A under elec. c.d. of 20mA/cm2, and service life reaching 6800h) can be used for preparing organic light-emitting devices. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Name: Benzyl(4-bromophenyl)sulfane

The Article related to preparation aromatic amine compound application light emitting devices, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Amines, Amine Oxides, Imines, and Quaternary Ammonium Compounds and other aspects.Name: Benzyl(4-bromophenyl)sulfane

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On December 9, 2015, Gao, Chunji; Zhang, Chengcheng; Li, Guoqiang; Hu, Xiaoming; Cui, Dunzhu published a patent.Formula: C13H11BrS The title of the patent was Preparation of aromatic amine compound and their application as light-emitting devices. And the patent contained the following:

The invention is related to the preparation of aromatic amine compound I and their application as light-emitting devices. The invention provides an aromatic amine compound I, wherein R1-R4 are independent H, halo, cyano, C1-C30 alkyl, C6-C50 aryl, C7-C50 arylalkyl, C7-50 aryl alkoxy, C7-50 arylalkyl-thiol, or C5-50 heteroaryl; and Ar1 and Ar2 are independently selected from C6-50 arylidene; are claimed. Compound I was prepared by multi-step procedure (procedure given). The inventive aromatic amine compound(current efficiency reaching 6.7 cd/A under elec. c.d. of 20mA/cm2, and service life reaching 6800h) can be used for preparing organic light-emitting devices. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Formula: C13H11BrS

The Article related to preparation aromatic amine compound application light emitting devices, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Amines, Amine Oxides, Imines, and Quaternary Ammonium Compounds and other aspects.Formula: C13H11BrS

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On November 25, 2015, Gao, Chunji; Sun, Xiangnan; Chen, Ming; Cui, Ming; Cui, Dunzhu published a patent.Quality Control of Benzyl(4-bromophenyl)sulfane The title of the patent was Aromatic amine compound, its preparation and application in organic electroluminescence device. And the patent contained the following:

The invention relates to aromatic amine compound of formula I, its preparation and application in organic electroluminescence device. Compounds I, wherein R1, R2, R3, and R4 are independently H, halo, cyano, C1-C30 alkyl, etc.; Ar1 and Ar2 are independently C6-C50 arylidene; or Ar1, nitrogen atom directly connected with Ar1, and Ph ring of substituent group R1 together form the carbazole structure, or Ar2, nitrogen atom directly connected with Ar2 and Ph ring of substituent group R2 together form the carbazole structure, are claimed. Compound II was prepared by multi-step procedure (procedure given). The inventive aromatic amine compound can be used for preparing organic electroluminescence device. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Quality Control of Benzyl(4-bromophenyl)sulfane

The Article related to aromatic amine preparation application organic electroluminescence device, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Amines, Amine Oxides, Imines, and Quaternary Ammonium Compounds and other aspects.Quality Control of Benzyl(4-bromophenyl)sulfane

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Jin, Ming; Xu, Haoran; Hong, Hong; Malval, Jean-Pierre; Zhang, Yuan; Ren, Aimin; Wan, Decheng; Pu, Hongting published an article in 2013, the title of the article was Design of D-π-A type photoacid generators for high efficiency excitation at 405 nm and 800 nm.Product Details of 53136-21-3 And the article contains the following content:

New sulfonium salts with diphenylamino asym. substituted stilbene as a D-π-A conjugated system have been synthesized. The resulting photoacid generators exhibit a highly efficient acid photogeneration process by either one-photon 405 nm or two-photon 800 nm excitation. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Product Details of 53136-21-3

The Article related to sulfonium phenylamino substituted stilbene photoacid generator photoresist, Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes: Photoresists and Radiation-Sensitive Resists and other aspects.Product Details of 53136-21-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On January 7, 2015, Jin, Ming; Xie, Jianchao; Pu, Hongting; Wan, Decheng published a patent.SDS of cas: 53136-21-3 The title of the patent was Fluorene-containing sulfonium-series photoacid generator, and preparing method and its application. And the patent contained the following:

The invention relates to a fluorene-containing sulfonium-series photoacid generator, and preparing method and its application. The photoacid generator has chem. structure (I) or (II), wherein, R1 is H, Me, Et, Pr, Bu, hexyl, octyl, nonyl, or dodecyl; R2 is Me, Et, Pr, Bu, hexyl, octyl, nonyl, or dodecyl; R3 is Me, benzyl, 4-cyano benzyl; R4 is Me, benzyl, pentafluorobenzyl, 4-cyanobenzyl, 4-nitrobenzyl, 4-trifluoromethyl benzyl, or 3,5-di-(trifluoromethyl) benzyl; R5 is trifluoromethanesulfonate, hexafluorophosphate, hexafluoroantimonate, or tetrafluoroborate. The inventive photoacid generator is suitable for photoresist active ingredient from UV region to visible region, such as 313nm, 365nm, 385nm, 405nm, and 425nm. The photoacid generator has the advantages of simple synthesis process, easy purification, and high yield, can be used for preparing high-performance photoresist used in 300-425nm, exhibits 0.3-0.6 of photoproduction acid quantum yield, and has high light excitation efficiency, and high catalytic activity. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).SDS of cas: 53136-21-3

The Article related to fluorene sulfonium photoacid generator, Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes: Photoresists and Radiation-Sensitive Resists and other aspects.SDS of cas: 53136-21-3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Capozzi, Maria Annunziata M.; Centrone, Caterina; Fracchiolla, Giuseppe; Naso, Francesco; Cardellicchio, Cosimo published an article in 2011, the title of the article was A Study of Factors Affecting Enantioselectivity in the Oxidation of Aryl Benzyl Sulfides in the Presence of Chiral Titanium Catalysts.Name: Benzyl(4-bromophenyl)sulfane And the article contains the following content:

A series of experiments was performed to test a theor. model that we have recently proposed to explain the highly enantioselective oxidation of aryl benzyl sulfides with tert-Bu hydroperoxide in the presence of a complex between titanium and (S,S)- or (R,R)-hydrobenzoin. The studied variations involved the sulfides, the ligands, and the order of addition of reactants. The reaction path predicted by our model was confirmed in every experiment In particular, aryl benzyl sulfides behaved as the ideal substrate for this type of asym. oxidation, which yields synthetically useful, enantiopure aryl benzyl sulfoxides in a straightforward manner. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Name: Benzyl(4-bromophenyl)sulfane

The Article related to enantioselective oxidation aryl benzyl sulfide chiral titanium catalyst, Physical Organic Chemistry: Stereochemistry and Stereochemical Relationships, Including Conformational Inversions and Rotational Isomerization and other aspects.Name: Benzyl(4-bromophenyl)sulfane

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem