Category: 53136-21-3

On February 28, 2005, Mohammadpoor-Baltork, Iraj; Memarian, Hamid R.; Bahrami, Kiumars published an article.Application In Synthesis of Benzyl(4-bromophenyl)sulfane The title of the article was 3-Carboxypyridinium chlorochromate-aluminum chloride – An efficient and inexpensive reagent system for the selective oxidation of sulfides to sulfoxides and sulfones in solution and under microwave irradiation. And the article contained the following:

3-Carboxypyridinium chlorochromate (CPCC) in the presence of aluminum chloride is a very efficient reagent for the selective oxidation of sulfides to sulfoxide and sulfones in solution and under microwave irradiation It is noteworthy that different functional groups including carbon-carbon double bonds, ketones, oximes, aldehydes, ethers, and acetals were tolerated under these reaction conditions. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Application In Synthesis of Benzyl(4-bromophenyl)sulfane

The Article related to sulfoxide sulfone preparation oxidation sulfide carboxypyridinium chlorochromate aluminum chloride, microwave irradiation sulfoxide sulfone preparation oxidation sulfide, General Organic Chemistry: Synthetic Methods and other aspects.Application In Synthesis of Benzyl(4-bromophenyl)sulfane

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On April 2, 2021, Luo, Shuping; Wang, Tianqi; Liu, Xiaoqing; Ren, Chenchao; Zhang, Yu published a patent.Recommanded Product: Benzyl(4-bromophenyl)sulfane The title of the patent was Photocatalytic preparation of aryl sulfide and its derivatives. And the patent contained the following:

The present invention relates to the photocatalytic preparation of aryl sulfide and its derivatives In particular, the aryl sulfide compound I or II (wherein, Ar = substituent-substituted Ph group, substituent-substituted benzyl group or substituent-substituted naphthyl group, and the substituent = H, C1-C4 alkyl, C1-C4 alkoxy, halogen group or nitro group; R = H, Me or halogen group; X = C, S, N or O) was prepared by dissolving an N-(sulfanyl) amide compound in a Me aromatic compound under inert gas protection condition, under the action of light, a catalyst, a ligand and a base. The inventive method has good functional group compatibility, the C-S bond compound can be selectively and efficiently constructed in one step, has simple catalytic system, mild reaction conditions, simple and accessible substrate economy and simple reaction operation. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Recommanded Product: Benzyl(4-bromophenyl)sulfane

The Article related to aryl sulfide compound preparation photocatalysis, Heterocyclic Compounds (One Hetero Atom): Pyridines and other aspects.Recommanded Product: Benzyl(4-bromophenyl)sulfane

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On July 31, 1990, Sugimoto, Hachiro; Tsuchiya, Yutaka; Sugumi, Hiroyuki; Higurashi, Kunizo; Karibe, Norio; Iimura, Yoichi; Sasaki, Atsushi; Kawakami, Yoshiyuki; Nakamura, Takaharu published an article.Recommanded Product: Benzyl(4-bromophenyl)sulfane The title of the article was Novel piperidine derivatives. Synthesis and anti-acetylcholinesterase activity of 1-benzyl-4-[2-(N-benzoylamino)ethyl]piperidine derivatives. And the article contained the following:

The title compound I (R = H, 2-Me, 4-NO2, 4-MeO, 4-CHO, 4-Cl, 4-PhCH2SO2; R1 = Bz, CH2Ph, CH2CH:CHPh, CH2CH2Ph, CH2C6H4Me-4, CH2C6H4NO2-2; R2 = H, Me, Et, Ph) were prepared and evaluated for antiacetylcholinesterase activity. Substituting the benzamide group with a bulky moiety in the para position led to a substantial increase in activity. Introduction of an alkyl or Ph group at the benzamide nitrogen atom dramatically enhanced the activity. The basicity of the piperidine nitrogen atom appears to play an important role in the increased activity, since the N-benzoylpiperidine derivative was almost inactive. I (R = 4-PhCH2SO2, R1 = CH2Ph, R2 = Me, R)(II) were the most potent inhibitors of acetylcholinesterase and produced significant increases in acetylcholine content in the cerebral cortex and hippocampus of rats. II was chosen for development as an antidementia agent. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Recommanded Product: Benzyl(4-bromophenyl)sulfane

The Article related to acetylcholinesterase inhibiting msbar benzylethylpiperidine, antidementia agent benzylethylpiperidine, dementia treatment agent benzylethylpiperidine, Heterocyclic Compounds (One Hetero Atom): Pyridines and other aspects.Recommanded Product: Benzyl(4-bromophenyl)sulfane

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Unno, Masafumi; Tanaka, Ryoji; Obinata, Daisuke; Endo, Mayuko; Sakurai, Tomoyuki; Ojima, Satoshi; Katayama, Takako; Fugami, Keigo published an article in 2011, the title of the article was Solvent-free synthesis of siloxanes and their usage as potential cross-coupling reagents.Category: ethers-buliding-blocks And the article contains the following content:

Hexaarylcyclotrisiloxanes were selectively prepared by solvent-free synthesis from diarylsilanediol. These well-known stable compounds were found to undergo palladium-catalyzed cross-coupling reaction with aryl halides in good yields. All of attached aryl groups on silicon atom could be utilized. Furthermore, base-sensitive functionality such as acetyl and nitro groups survived the reaction. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Category: ethers-buliding-blocks

The Article related to hexaarylcyclotrisiloxane solvent free preparation cross coupling reaction aryl halide, biaryl preparation, Organometallic and Organometalloidal Compounds: Metal Heterocyclic Compounds and Cluster Compounds and other aspects.Category: ethers-buliding-blocks

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On October 9, 2008, Tomoo, Toshiyuki; Nakatsuka, Takashi; Hayashi, Yasuhiro; Katayama, Toyoko published a patent.Safety of Benzyl(4-bromophenyl)sulfane The title of the patent was Preparation of indole derivatives as cytosolic phospholipase A2 (cPLA2) inhibitors. And the patent contained the following:

The title compounds I [R1 = (un)substituted aromatic hydrocarbon group, (un)substituted aromatic heterocyclic group containing 1 – 4 heteroatoms (N, S, O), etc.; R2 = H, alkyl, cycloalkyl, etc.; R3 = (un)substituted aromatic hydrocarbon group, (un)substituted aromatic heterocyclic group containing 1 – 4 heteroatoms (N, S, O); R4 = cyano, tetrazole, isothiazole, etc.; X1 = carbonyl, methylene; X2 = alkylene, bond; X3 = alkylene, alkenylene, alkynylene] are prepared (2E)-3-(3-Benzoyl-1-phenyl-1H-indol-5-yl)-2-propenoic acid was prepared in a multistep process starting from 5-bromoindole and iodobenzene. Compounds of this invention showed IC50 values of 0.002 渭M to 21.3 渭M against cPLA2. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Safety of Benzyl(4-bromophenyl)sulfane

The Article related to indole derivative preparation cytosolic phospholipase a2 inhibitor, Heterocyclic Compounds (One Hetero Atom): Indoles, Indolizines, Carbazoles, and Other Arenopyrroles and other aspects.Safety of Benzyl(4-bromophenyl)sulfane

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Rostamnia, Sadegh; Alamgholiloo, Hassan; Jafari, Maryam; Rookhosh, Rezan; Abbasi, Amir Reza published an article in 2016, the title of the article was Synthesis and catalytic study of open metal site metal-organic frameworks of Cu3(BTC)2 microbelts in selective organic sulfide oxidation.Related Products of 53136-21-3 And the article contains the following content:

The synthesis of open metal site metal-organic frameworks of Cu3(BTC)2 with microbelt morphol. and a study of the catalytic oxidation of organic sulfides are reported. This CuBTC is an efficient, selective and waste-free green heterogeneous co-catalyst for the green H2O2 catalytic oxidation of sulfides. The catalyst can be isolated from the reaction mixture and reused at least five times. Copyright © 2016 John Wiley and Sons, Ltd. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Related Products of 53136-21-3

The Article related to copper benzenetricarboxylate metal organic framework preparation sulfide oxidation catalyst, sulfoxide preparation copper benzenetricarboxylate mof catalyst, Inorganic Chemicals and Reactions: Coordination Compounds and other aspects.Related Products of 53136-21-3

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On December 19, 2009, Barry, Nicola; Brondel, Nicolas; Lawrence, Simon E.; Maguire, Anita R. published an article.Name: Benzyl(4-bromophenyl)sulfane The title of the article was Synthesis of aryl benzyl NH-sulfoximines. And the article contained the following:

Efficient synthesis and characterization of a series of aryl benzyl NH-sulfoximines are described. While N-protected versions of aryl benzyl sulfoximines have been previously described, reports of their deprotection are very limited, presumably due to lability under the typically harsh deprotection conditions which can be employed with the less reactive aryl alkyl derivatives Use of N-cyanosulfoximines as key intermediates overcomes these difficulties leading to an effective synthetic route to these compounds The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Name: Benzyl(4-bromophenyl)sulfane

The Article related to aryl benzyl sulfoximine preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Others and other aspects.Name: Benzyl(4-bromophenyl)sulfane

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Xie, Yongtao; Zhou, Biying; Zhou, Sha; Zhou, Shaa; Wei, Wei; Liu, Jingbo; Zhan, Yizhou; Cheng, Dandan; Chen, Minggui; Li, Yuxin; Wang, Baolei; Xue, Xiao-song; Li, Zhengming published an article in 2017, the title of the article was Sulfimine-promoted fast O transfer: one-step synthesis of sulfoximine from sulfide.Application of 53136-21-3 And the article contains the following content:

Transfer of electrophilic NH to sulfides and a subsequent sulfimine-promoted fast O transfer was achieved in a one-pot process unprecedentedly for the preparation of sulfoximines, e.g., I at ambient temperature under air. The transformations, which are metal-, ligand-, base-, additive-free, and operationally simple, proceeded in just 5 min and furnished NH-sulfoximines in good-to-excellent yields (up to 99 %) by treatment of sulfides with a combination of PhI(OAc)2 and ammonia source. A variety of com. available and inexpensive electrophilic nitrogen sources were successfully used in the oxidative sulfide-to-sulfoximine conversions. This method featured a high efficiency, excellent functional-group tolerance, and broad substrate scope, which may facilitate its applications in medicinal chem. area. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Application of 53136-21-3

The Article related to sulfoximine preparation, sulfide iodobenzene diacetate ammonium carbonate imination, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Others and other aspects.Application of 53136-21-3

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On June 30, 2011, Hatano, Akihiko; Okada, Munehiro; Shimazaki, Kei; Uehara, Sanae; Ishikawa, Yuta; Matsumoto, Arata; Fujita, Yudai; Nishimura, Makoto published an article.COA of Formula: C13H11BrS The title of the article was Inhibitory effects on microbial growth using the derivatives of benzyl phenyl sulfide. And the article contained the following:

We investigated the antimicrobial activities of twelve derivatives of benzyl Ph sulfide by using Min. Inhibitory Concentration (MIC) and Min. Bactericidal Concentration (MBC) values against 10 microbial strains. These derivatives of benzyl Ph sulfides were synthesized by means of the nucleophilic coupling reaction at our laboratory MIC testing revealed that all synthetic derivatives of benzyl and 4-methoxybenzyl Ph sulfides had no effect against the tested microbial strains. However, the compounds of 4-nitrobenzyl Ph sulfide showed antimicrobial activity against many of the tested strains. Above all, 4-nitrobenzyl 4-chlorophenyl sulfide 11 exhibited the strongest and widest ranging inhibitory effects among the twelve synthetic compounds We researched the antimicrobial activities of the coupling materials of sulfide. As a result, it was considered important for the expression of antimicrobial activities that the sulfide had a 4-nitrobenzyl group and 4-chlorophenyl group in the same mol. as in the case of benzyl Ph sulfide. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).COA of Formula: C13H11BrS

The Article related to benzyl phenyl sulfide growth inhibition, Microbial, Algal, and Fungal Biochemistry: Antimicrobial Sensitivity and other aspects.COA of Formula: C13H11BrS

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On March 5, 2021, Liu, Long; Tang, Yuanyuan; Wang, Kunyu; Huang, Tianzeng; Chen, Tieqiao published an article.HPLC of Formula: 53136-21-3 The title of the article was Transition-Metal-Free and Base-Promoted Carbon-Heteroatom Bond Formation via C-N Cleavage of Benzyl Ammonium Salts. And the article contained the following:

A facile and general method for constructing carbon-heteroatom (C-P, C-O, C-S, and C-N) bonds via C-N cleavage of benzyl ammonium salts under transition-metal-free conditions was reported. The combination of t-BuOK and 18-crown-6 enabled a wide range of substituted benzyl ammonium salts to couple readily with different kinds of heteroatom nucleophiles, i.e. hydrogen phosphoryl compounds, alcs., thiols, and amines. Good functional group tolerance was demonstrated. The scale-up reaction and one-pot synthesis were also successfully performed. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).HPLC of Formula: 53136-21-3

The Article related to benzyl ammonium salt nucleophile bond formation potassium tert butoxide, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: General and other aspects.HPLC of Formula: 53136-21-3

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