Category: 53136-21-3

On April 30, 2009, Movassagh, Barahman; Soleiman-Beigi, Mohammad published an article.Reference of Benzyl(4-bromophenyl)sulfane The title of the article was Synthesis of sulfides under solvent- and catalyst-free conditions. And the article contained the following:

A simple, highly efficient, and green protocol was developed for preparation of sulfides from alkyl or aryl thiols and benzyl-, allyl-, t-Bu, and adamantyl halides under solvent- and catalyst-free conditions. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Reference of Benzyl(4-bromophenyl)sulfane

The Article related to thiol thioetherification alkyl halide solvent catalyst free, sulfide preparation green chem, General Organic Chemistry: Synthetic Methods and other aspects.Reference of Benzyl(4-bromophenyl)sulfane

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On April 30, 2010, Khodaei, Mohammad Mehdi; Bahrami, Kiumars; Arabi, Mehdi Sheikh published an article.HPLC of Formula: 53136-21-3 The title of the article was Oxidation of sulfides to sulfoxides with H2O2/HNO3 reagent system. And the article contained the following:

Selective oxidation of sulfides to sulfoxides is achieved by H2O2 using HNO3 as the promotor. Aromatic and aliphatic sulfides are oxidized to sulfoxides in excellent yields and short reaction times. Different functional groups including C-C double bond, ester, ketone, acetal, alc., and oxime groups are tolerated under this reaction condition. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).HPLC of Formula: 53136-21-3

The Article related to sulfide oxidation hydrogen peroxide nitric acid oxidizing agent, sulfoxide preparation, General Organic Chemistry: Synthetic Methods and other aspects.HPLC of Formula: 53136-21-3

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On October 31, 2014, Ghorbani-Vaghei, Ramin; Shiri, Lotfi; Ghorbani-Choghamarani, Arash published an article.Synthetic Route of 53136-21-3 The title of the article was A novel method for the reduction of sulfoxides with the N,N,N’,N’-tetrabromobenzene-1,3-disulfonamide (TBBDA)/PPh3 system. And the article contained the following:

A new method is described for the reduction of sulfoxides to sulfides using N,N,N’,N’-tetrabromobenzene-1,3-disulfonamide [TBBDA] in combination with triphenylphosphine. Good to excellent yields, short reaction times, high efficiency and facile isolation of the desired products are the advantages of this method. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Synthetic Route of 53136-21-3

The Article related to tetrabromobenzene disulfonamide triphenylphosphine sulfoxide reduction, sulfide preparation, General Organic Chemistry: Synthetic Methods and other aspects.Synthetic Route of 53136-21-3

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Hosseini, Seyed Hassan; Tavakolizadeh, Maryam; Zohreh, Nasrin; Soleyman, Rouhollah published an article in 2018, the title of the article was Green route for selective gram-scale oxidation of sulfides using tungstate/triazine-based ionic liquid immobilized on magnetic nanoparticles as a phase-transfer heterogeneous catalyst.Formula: C13H11BrS And the article contains the following content:

Tungstate ions were successfully loaded onto triazine-based ionic liquid-functionalized magnetic nanoparticles through an anion exchange process. The use of triazine core for creating ionic liquid led to the immobilization of high amounts of WO42-. The resulting catalyst showed high activity and selectivity in the oxidation of sulfides to sulfoxides with H2O2 as a green oxidant at room temperature In addition, due to the presence of ammonium groups in the catalyst structure, water dispersibility of the catalyst was increased. More important, the catalyst was magnetically recovered and reused for up to six runs without any marked decrease of activity and selectivity. Finally, easy gram-scale oxidation of methylphenyl sulfide as well as fast separation of catalyst and product makes the protocol economical and industrially applicable. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Formula: C13H11BrS

The Article related to green sulfide oxidation tungstate triazine immobilized magnetic nanoparticle catalyst, General Organic Chemistry: Synthetic Methods and other aspects.Formula: C13H11BrS

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On May 27, 2022, Scattolin, Thomas; Gharbaoui, Tawfik; Chen, Cheng-yi published an article.Synthetic Route of 53136-21-3 The title of the article was A Nucleophilic Deprotection of Carbamate Mediated by 2-Mercaptoethanol. And the article contained the following:

Carbamates, typically used for the protection of amines, including Cbz, Alloc, and Me carbamate, was readily deprotected by treatment with 2-mercaptoethanol in the presence of potassium phosphate tribasic in N,N-dimethylacetamide at 75°C. This nucleophilic deprotection protocol was superior to the standard hydrogenolysis or Lewis acid-mediated deprotection conditions for substrates bearing a functionality sensitive to these more traditional methods. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Synthetic Route of 53136-21-3

The Article related to carbamate mercaptoethanol nucleophilic deprotection, secondary amine preparation, General Organic Chemistry: Synthetic Methods and other aspects.Synthetic Route of 53136-21-3

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Sorribes, Ivan; Corma, Avelino published an article in 2019, the title of the article was Nanolayered cobalt-molybdenum sulphides (Co-Mo-S) catalyse borrowing hydrogen C-S bond formation reactions of thiols or H2S with alcohols.Formula: C13H11BrS And the article contains the following content:

Nanolayered cobalt-molybdenum sulfide (Co-Mo-S) materials have been established as excellent catalysts for C-S bond construction. These catalysts allow for the preparation of a broad range of thioethers in good to excellent yields from structurally diverse thiols and readily available primary as well as secondary alcs. Chemoselectivity in the presence of sensitive groups such as double bonds, nitriles, carboxylic esters and halogens has been demonstrated. It is also shown that the reaction takes place through a hydrogen-autotransfer (borrowing hydrogen) mechanism that involves Co-Mo-S-mediated dehydrogenation and hydrogenation reactions. A novel catalytic protocol based on the thioetherification of alcs. with hydrogen sulfide (H2S) to furnish sym. thioethers has also been developed using these earth-abundant metal-based sulfide catalysts. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Formula: C13H11BrS

The Article related to thioether preparation chemoselective, alc thiol hydrogen sulfide bond formation cobalt molybdenum sulfide, General Organic Chemistry: Synthetic Methods and other aspects.Formula: C13H11BrS

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On August 18, 2008, Bahrami, Kiumars; Khodaei, Mohammad Mehdi; Karimi, Ahmad published an article.Recommanded Product: Benzyl(4-bromophenyl)sulfane The title of the article was Mild and efficient deoxygenation of sulfoxides to sulfides with triflic anhydride/potassium iodide reagent system. And the article contained the following:

The combination of triflic anhydride/KI was an effective promoter for the deoxygenation of sulfoxides and gave the corresponding sulfides in excellent yield in MeCN at room temperature This reagent system is chemoselective and tolerates various functional groups, such as alkene, ketone, ester, aldehyde, acid, and oxime. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Recommanded Product: Benzyl(4-bromophenyl)sulfane

The Article related to sulfoxide chemoselective deoxygenation triflic anhydride potassium iodide, sulfide preparation, thioether preparation, General Organic Chemistry: Synthetic Methods and other aspects.Recommanded Product: Benzyl(4-bromophenyl)sulfane

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On February 3, 2017, Barragan, Enrique; Bugarin, Alejandro published an article.Quality Control of Benzyl(4-bromophenyl)sulfane The title of the article was π-Conjugated Triazenes: Intermediates That Undergo Oxidation and Substitution Reactions. And the article contained the following:

Novel reactivity for π-conjugated triazenes is herein reported. This observed and unprecedented triazene reactivity gave access to oxidation and substitution reactions. These transformations include successful synthesis of aldehydes, ketones, ethers, and sulfides from readily available organic azides via π-conjugated triazene intermediates. Notably, the afforded adducts were obtained in good yields, at room temperature, and in the absence of added metal catalysts. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Quality Control of Benzyl(4-bromophenyl)sulfane

The Article related to aldehyde ketone ether sulfide preparation, azide reaction nitrogen heterocyclic carbene, triazene preparation reaction, General Organic Chemistry: Synthetic Methods and other aspects.Quality Control of Benzyl(4-bromophenyl)sulfane

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Tota, Arianna; Zenzola, Marina; Chawner, Stephen J.; John-Campbell, Sahra St; Carlucci, Claudia; Romanazzi, Giuseppe; Degennaro, Leonardo; Bull, James A.; Luisi, Renzo published an article in 2017, the title of the article was Synthesis of NH-sulfoximines from sulfides by chemoselective one-pot N- and O-transfers.Electric Literature of 53136-21-3 And the article contains the following content:

Direct synthesis of NH-sulfoximines from sulfides were achieved through O and NH transfer in the same reaction, occurring with complete selectivity. The reaction was mediated by bisacetoxyiodobenzene under simple conditions and employs inexpensive N-sources. Preliminary studies indicated that NH-transfer was likely to be first, followed by oxidation, but the reaction proceedes successfully in either order. A wide range of functional groups and biol. relevant compounds were tolerated. The use of AcO15NH4 affords 15N-labeled compounds The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Electric Literature of 53136-21-3

The Article related to sulfide preparation ammonium carbamate bisacetoxyiodobenzene oxidation imination, sulfoximine chemoselective preparation, General Organic Chemistry: Synthetic Methods and other aspects.Electric Literature of 53136-21-3

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Ong, Derek Yiren; Tejo, Ciputra; Xu, Kai; Hirao, Hajime; Chiba, Shunsuke published an article in 2017, the title of the article was Hydrodehalogenation of Haloarenes by a Sodium Hydride-Iodide Composite.Application of 53136-21-3 And the article contains the following content:

A simple protocol for hydrodebromination and -deiodination of halo(hetero)arenes was enabled by sodium hydride (NaH) in the presence of lithium iodide (LiI). Mechanistic studies showed that an unusual concerted nucleophilic aromatic substitution operates in the present process. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Application of 53136-21-3

The Article related to haloarene hydrodehalogenation sodium hydride iodide, dft calculations, haloarenes, hydrodehalogenation, reduction, sodium hydride, General Organic Chemistry: Synthetic Methods and other aspects.Application of 53136-21-3

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Ether – Wikipedia,
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