Category: 529-28-2

The author of 《Bioinspired Palladium Nanoparticles Supported on Soil-Derived Humic Acid Coated Iron-Oxide Nanoparticles as Catalyst for C-C Cross-Coupling and Reduction Reactions》 were Chinchole, Anurag N.; Dubey, Abhishek V.; Kumar, A. Vijay. And the article was published in Catalysis Letters in 2019. HPLC of Formula: 529-28-2 The author mentioned the following in the article:

Palladium supported on humic acid-coated magnetite nanoparticles was prepared as a recyclable catalyst for Suzuki coupling reactions of aryl iodides, bromides, and diazonium tetrafluoroborates with arylboronic acids, for stereoselective Heck reactions of styrene with aryl bromides and iodides, and for hydrogenation reactions of diaryl alkenes using aqueous ethanol or methanol as solvents. In the experimental materials used by the author, we found 1-Iodo-2-methoxybenzene(cas: 529-28-2HPLC of Formula: 529-28-2)

1-Iodo-2-methoxybenzene(cas: 529-28-2) participates in palladium catalyzed enantioselective Heck arylation of 2,3-dihydrofuran in the presence of chiral ionic liquids containing L-prolinate and L-lactate anions and non-chiral quaternary ammonium cations.HPLC of Formula: 529-28-2

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

《A practical ortho-acylation of aryl iodides enabled by moisture-insensitive activated esters via palladium/norbornene catalysis》 was published in Organic Chemistry Frontiers in 2020. These research results belong to Feng, Yunxia; Wang, Yangyang; Zhao, Shen; Zhang, Dao-Peng; Li, Xinjin; Liu, Hui; Dong, Yunhui; Sun, Feng-Gang. Computed Properties of C7H7IO The article mentions the following:

Polysubstituted aryl ketones I [R1 = 6-Me, 6-Cl, 4,6-di-Me, etc.] and II [R1 = C(O)Et, C(O)OEt, C(O)OtBu; R2 = cyclohexyl, thiophene-2-yl, 3-MeOC6H4, etc.] were synthesized via palladium/norbornene cooperative system catalyzed ortho-arene C-H acylation of aryl iodides using triazine esters. This ortho-acylation even proceeded smoothly in water. Preliminary mechanistic experiments indicated that the strong electron-withdrawing ability and coordination chem. of triazine play crucial roles in this transformation. In the part of experimental materials, we found many familiar compounds, such as 1-Iodo-2-methoxybenzene(cas: 529-28-2Computed Properties of C7H7IO)

1-Iodo-2-methoxybenzene(cas: 529-28-2) is a useful synthetic intermediate. It can be used in the synthesis of piperidinyl diaminopyrimidines as cyclin-dependent kinase inhibitors with antitumor activity and polysubstituted benzofuran derivatives as novel inhibitors of parasitic growth.Computed Properties of C7H7IO

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

《Ligand Free Palladium-Catalyzed Synthesis of α-Trifluoromethylacrylic Acids and Related Acrylates by Three-Component Reaction》 was published in Advanced Synthesis & Catalysis in 2020. These research results belong to Xiao, Pan; Pannecoucke, Xavier; Bouillon, Jean-Philippe; Couve-Bonnaire, Samuel. Application of 529-28-2 The article mentions the following:

Aryl iodides and 2-(trifluoromethyl)acrylic acid reacted together in ligand-free Mizoroki-Heck reaction furnishing a quick and efficient access to highly valuable α-trifluoromethylacrylic acids I [R1 = H; Ar = Ph, 4-ClC6H4, 2-naphthyl, etc.; stereo = E and Z]. The useful transformation was independent with regard to the electronic nature of the aryl group substituent. A three-component one-pot version was also developed to give diverse substituted acrylates I [R1 = Et, n-heptyl, CH2CH(Et)CH2CH2CH2CH3, Bn, CH2CH2CH2Ph]. The versatility of α-trifluoromethylacrylic acids I was demonstrated by quick access to 3-CF3-coumarins as well as fluorinated analogs of therapeutic or cosmetic agents. Finally, a catalytic cycle based on the silver carboxylate salt, identified as a key intermediate in the reaction was proposed. The experimental process involved the reaction of 1-Iodo-2-methoxybenzene(cas: 529-28-2Application of 529-28-2)

1-Iodo-2-methoxybenzene(cas: 529-28-2) is a useful synthetic intermediate. It can be used in the synthesis of piperidinyl diaminopyrimidines as cyclin-dependent kinase inhibitors with antitumor activity and polysubstituted benzofuran derivatives as novel inhibitors of parasitic growth.Application of 529-28-2

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

In 2019,Organic & Biomolecular Chemistry included an article by Shaifali; Ram, Shankar; Thakur, Vandna; Das, Pralay. Formula: C7H7IO. The article was titled 《Synthesis of α,β-alkynyl ketones via the nickel catalyzed carbonylative Sonogashira reaction using oxalic acid as a sustainable C1 source》. The information in the text is summarized as follows:

An efficient and economic nickel-dppb catalyzed-carbonylative Sonogashira cross-coupling reaction was demonstrated to provide rapid access to various α,β-alkynyl ketones RC(O)C≡CR1 [R = Ph, 4-MeC6H4, 4-BrC6H4, etc.; R1 = Ph, 2-ClC6H4, 4-MeOC6H4, etc.] from aryl iodides and terminal alkynes using oxalic acid as the ex-situ C1 source in a double vial (DV) system. Notably, the role of the ligand in combination with the Ni catalyst for the selective formation of carbonylative Sonogashira products was investigated and supported with control experiments In this process, for the first time, oxalic acid was used as an ex-situ solid, bench stable, easy to handle and efficient CO surrogate in a DV-system for the carbonylative Sonogashira coupling reaction with vast substrate scope. The results came from multiple reactions, including the reaction of 1-Iodo-2-methoxybenzene(cas: 529-28-2Formula: C7H7IO)

1-Iodo-2-methoxybenzene(cas: 529-28-2) is a useful synthetic intermediate. It can be used in the synthesis of piperidinyl diaminopyrimidines as cyclin-dependent kinase inhibitors with antitumor activity and polysubstituted benzofuran derivatives as novel inhibitors of parasitic growth.Formula: C7H7IO

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

In 2019,Journal of Organic Chemistry included an article by Sikari, Rina; Sinha, Suman; Das, Siuli; Saha, Anannya; Chakraborty, Gargi; Mondal, Rakesh; Paul, Nanda D.. COA of Formula: C7H7IO. The article was titled 《Achieving Nickel Catalyzed C-S Cross-Coupling under Mild Conditions Using Metal-Ligand Cooperativity》. The information in the text is summarized as follows:

A simple and efficient approach of C-S cross-coupling of a wide variety of (hetero)aryl thiols and (hetero)aryl halides under mild conditions, mostly at room temperature, catalyzed by well-defined singlet diradical Ni(II) catalysts bearing redox noninnocent ligands is reported. Taking advantage of ligand centered redox events, the high-energetic Ni(0)/Ni(II) or Ni(I)/Ni(III) redox steps were avoided in the catalytic cycle. The cooperative participation of both nickel and the coordinated ligands during oxidative addition/reductive elimination steps allowed us to perform the catalytic reactions under mild conditions. The results came from multiple reactions, including the reaction of 1-Iodo-2-methoxybenzene(cas: 529-28-2COA of Formula: C7H7IO)

1-Iodo-2-methoxybenzene(cas: 529-28-2) is a useful synthetic intermediate. It can be used in the synthesis of piperidinyl diaminopyrimidines as cyclin-dependent kinase inhibitors with antitumor activity and polysubstituted benzofuran derivatives as novel inhibitors of parasitic growth.COA of Formula: C7H7IO

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

In 2019,Letters in Organic Chemistry included an article by Zhou, De-Jun; Zhai, Yang-Yang; Meng, Ling-Pu; Song, Wei-Wei; Liu, Xiao; Yin, Shu-Qiang. HPLC of Formula: 529-28-2. The article was titled 《Efficient Synthesis of Diacetoxyiodoarenes via Intramolecular Rearrangement》. The information in the text is summarized as follows:

This study introduces a concise and efficient method for preparing diacetoxyiodoarenes from the corresponding iodoarenes. In the presence of acetic anhydride, iodoarenes were oxidized to diacetoxyiodoarenes by sodium perborate in acetic acid under argon protection at 55°C in ideal yields. Through this method, 10 diacetoxyiodoarenes were obtained smoothly. The experimental part of the paper was very detailed, including the reaction process of 1-Iodo-2-methoxybenzene(cas: 529-28-2HPLC of Formula: 529-28-2)

1-Iodo-2-methoxybenzene(cas: 529-28-2) participates in palladium catalyzed enantioselective Heck arylation of 2,3-dihydrofuran in the presence of chiral ionic liquids containing L-prolinate and L-lactate anions and non-chiral quaternary ammonium cations.HPLC of Formula: 529-28-2

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

《Organocatalyst in Direct C(sp2)-H Arylation of Unactivated Arenes: [1-(2-Hydroxyethyl)-piperazine]-Catalyzed Inter-/Intra-molecular C-H Bond Activation》 was published in Journal of Organic Chemistry in 2020. These research results belong to Yadav, Lalit; Tiwari, Mohit K.; Shyamlal, Bharti Rajesh Kumar; Chaudhary, Sandeep. Application of 529-28-2 The article mentions the following:

In the presence of 10 mol% 1-piperazineethanol, aryl iodides and bromides underwent arylation with benzene mediated by KOt-Bu to yield biaryls. N-Aryl 2-bromobenzamides underwent cyclization mediated by KOt-Bu in the presence of 40 mol% 1-piperazineethanol and 40 mol% 4-dimethylaminopyridine in mesitylene to yield phenanthridinones. Study of the reaction mechanism using kinetics and kinetic isotope effects and inhibition studies are consistent with the formation of aryl radical anions and a single electron transfer mechanism. After reading the article, we found that the author used 1-Iodo-2-methoxybenzene(cas: 529-28-2Application of 529-28-2)

1-Iodo-2-methoxybenzene(cas: 529-28-2) is a useful synthetic intermediate. It can be used in the synthesis of piperidinyl diaminopyrimidines as cyclin-dependent kinase inhibitors with antitumor activity and polysubstituted benzofuran derivatives as novel inhibitors of parasitic growth.Application of 529-28-2

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

《Palladium-Catalyzed ortho-C-H Glycosylation/ipso-Alkenylation of Aryl Iodides》 was published in Journal of Organic Chemistry in 2020. These research results belong to Ding, Ya-Nan; Shi, Wei-Yu; Liu, Ce; Zheng, Nian; Li, Ming; An, Yang; Zhang, Zhe; Wang, Cui-Tian; Zhang, Bo-Sheng; Liang, Yong-Min. Product Details of 529-28-2 The article mentions the following:

This report describes first example of palladium-catalyzed ortho-C-H glycosylation/ipso-alkenylation of aryl iodides, and the easily accessible glycosyl chlorides are used as a glycosylation reagent. The reaction compatible with the functional groups of the substrates, and a series of C-aryl glycosides have been synthesized in good to excellent yield and with excellent diastereoselectivity. It is found that a cheap 5-norbornene-2-carbonitrile as a transient mediator can effectively promote this reaction. In addition, ipso-arylation and cyanation were also realized by the strategy. In the experiment, the researchers used 1-Iodo-2-methoxybenzene(cas: 529-28-2Product Details of 529-28-2)

1-Iodo-2-methoxybenzene(cas: 529-28-2) is a useful synthetic intermediate. It can be used in the synthesis of piperidinyl diaminopyrimidines as cyclin-dependent kinase inhibitors with antitumor activity and polysubstituted benzofuran derivatives as novel inhibitors of parasitic growth.Product Details of 529-28-2

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Xu, Hang; Yamaguchi, Sho; Mitsudome, Takato; Mizugaki, Tomoo published their research in Organic & Biomolecular Chemistry in 2021. The article was titled 《A copper nitride catalyst for the efficient hydroxylation of aryl halides under ligand-free conditions》.Name: 1-Iodo-2-methoxybenzene The article contains the following contents:

Copper nitride(Cu3N) was used as a heterogeneous catalyst for the hydroxylation of aryl halides RX (R = 4-methoxyphenyl, Ph, 1-naphthyl, pyridin-3-yl, etc.; X = I, Br, Cl) under ligand-free conditions. The cubic Cu3N nanoparticles showed high catalytic activity, comparable to those of conventional Cu catalysts with nitrogen ligands, demonstrating that the nitrogen atoms in Cu3N act as functional ligands that promote hydroxylation. In the part of experimental materials, we found many familiar compounds, such as 1-Iodo-2-methoxybenzene(cas: 529-28-2Name: 1-Iodo-2-methoxybenzene)

1-Iodo-2-methoxybenzene(cas: 529-28-2) is a useful synthetic intermediate. It can be used in the synthesis of piperidinyl diaminopyrimidines as cyclin-dependent kinase inhibitors with antitumor activity and polysubstituted benzofuran derivatives as novel inhibitors of parasitic growth.Name: 1-Iodo-2-methoxybenzene

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

In 2019,Organic & Biomolecular Chemistry included an article by Takagi, Mio; Watanabe, Ayako; Murata, Shigeo; Takita, Ryo. Formula: C7H7IO. The article was titled 《Copper-catalyzed arene amination in pure aqueous ammonia》. The information in the text is summarized as follows:

A simple protocol for copper-catalyzed arene amination using aqueous ammonia without any addnl. ligands and organic coordinating solvents has been developed. The reaction pathway via a Cu(I)/Cu(III) mechanism is proposed based on the results of control experiments as well as DFT calculations After reading the article, we found that the author used 1-Iodo-2-methoxybenzene(cas: 529-28-2Formula: C7H7IO)

1-Iodo-2-methoxybenzene(cas: 529-28-2) is a useful synthetic intermediate. It can be used in the synthesis of piperidinyl diaminopyrimidines as cyclin-dependent kinase inhibitors with antitumor activity and polysubstituted benzofuran derivatives as novel inhibitors of parasitic growth.Formula: C7H7IO

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem