Category: 150-19-6

《Triethylammonium Hydrogen Sulfate [Et3NH][HSO4] as an Efficient Ionic Liquid Catalyst for the Synthesis of Coumarin Derivatives》 was published in Polycyclic Aromatic Compounds in 2020. These research results belong to Karimi-Jaberi, Zahed; Masoudi, Behzad; Rahmani, Atefeh; Alborzi, Kiana. Computed Properties of C7H8O2 The article mentions the following:

Triethylammonium hydrogen sulfate [Et3NH][HSO4] has been studied to be an efficient ionic liquid catalyst for the synthesis of biol. potent coumarin derivatives Thus, 4-substituted coumarins have been synthesized through the Pechmann condensation of phenols with β-ketoesters in the presence of [Et3NH][HSO4]. Also, 4-hydroxycoumarin was reacted with various aldehydes using this catalyst to obtain the α,α’-benzylidene bis(4-hydroxycoumarin) derivatives In addition, this efficient and privileged ionic liquid catalyst has been described in the synthesis of pyrano[3,2-c]coumarin derivatives by condensation of 4-hydroxycoumarin with chalcones. The optimization conditions carried out in the present study revealed that 20 mol% of ionic liquid catalyst under solvent-free condition at 110° are the best conditions for the synthesis of coumarin-derivatives in good to excellent yields. The present methodol. is a facile and green approach offering several advantages, such as excellent yield of products, minimizing production of chem. wastes, shorter reaction profile, mild reaction conditions, simple operational procedure, and easy preparation/separation of catalyst as a non-corrosive and stable ionic liquid After reading the article, we found that the author used m-Methoxyphenol(cas: 150-19-6Computed Properties of C7H8O2)

m-Methoxyphenol(cas: 150-19-6) may be used in synthesis of:C(4) symmetric calix[4]resorcinarene, 2-nitroso-5-methoxyphenol, 6-methoxy-2(3H)-benzoxazoloneComputed Properties of C7H8O2

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

The author of 《Miscible-Immiscible Transition of Deep Eutectic Solvents in Water Switched by CO2》 were Wan, Wenrui; Xiong, Dazhen; Zhang, Qian; Wang, Jianji. And the article was published in ACS Sustainable Chemistry & Engineering in 2019. Application of 150-19-6 The author mentioned the following in the article:

It is very important to develop “”smart”” solvents that can integrate the advantages of homogeneous and heterogeneous reactions into one chem. process for enhanced reaction rate and minimal environmental impact. In designing these solvents, the applicability of the systems to real processes strongly depends on the phase behavior of the systems. In this work, a novel class of CO2 driven miscible-immiscible transition of deep eutectic solvents (DESs) have been explored. These DESs are composed of alkanolamine compounds as hydrogen bond acceptor (HBA) and phenolic compounds as hydrogen bond donor (HBD). They exhibit unique phase behavior with H2O: miscible with water in the absence of CO2, but immiscible with water in the presence of CO2 at room temperature and ambient pressure. Reversible liquid-liquid phase transition of such DESs-H2O mixtures can be realized by alternatively bubbling of CO2 and N2 under ambient conditions. Spectroscopic investigations show that the mechanism behind miscible-immiscible transition of DESs involves breaking of the hydrogen bonds between HBD and HBA by H2CO3 generated by bubbling CO2 through aqueous solution, because the acidity of H2CO3 is stronger than that of HBAs. And then HBAs react with H2CO3 to form ammonium salts. The salting-out effect of ammonium salts leads to the formation of an ammonium-salts-rich top phase and an HBD-rich bottom phase. When CO2 is removed by bubbling of N2, reversible process is achieved. The experimental process involved the reaction of m-Methoxyphenol(cas: 150-19-6Application of 150-19-6)

m-Methoxyphenol(cas: 150-19-6) may be used as an analytical standard for the determination of the analyte in wine, coffee beans, wood samples, and mainstream smoke by gas chromatography (GC) based techniques.Application of 150-19-6

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

《An efficient base and H2O2 free protocol for the synthesis of phenols in water and oxygen using spinel CuFe2O4 magnetic nanoparticles》 was published in Journal of Coordination Chemistry in 2020. These research results belong to Chutia, Rituparna; Chetia, Bolin. Recommanded Product: m-Methoxyphenol The article mentions the following:

An efficient base and H2O2 free protocol was used for the synthesis of phenols from boronic acids using biogenic CuFe2O4 magnetic nanoparticles as catalyst at room temperature in water and oxygen. The catalyst was prepared using the flowers of Lantana camara. The size of the nanoparticles was 4.27 nm. Base free and ligand free protocol, less time, excellent yields, room temperature, biogenic synthesis of the catalyst, use of O2 as an environmentally friendly oxidant are the advantages of the present protocol. The recyclability of the catalyst was for 5 cycles without loss of magnetic property or catalytic activity. The experimental process involved the reaction of m-Methoxyphenol(cas: 150-19-6Recommanded Product: m-Methoxyphenol)

m-Methoxyphenol(cas: 150-19-6) may be used in synthesis of:C(4) symmetric calix[4]resorcinarene, 2-nitroso-5-methoxyphenol, 6-methoxy-2(3H)-benzoxazoloneRecommanded Product: m-Methoxyphenol

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Cordero, Jose Andres; He, Kai; Janya, Kanjira; Echigo, Shinya; Itoh, Sadahiko published an article in 2021. The article was titled 《Predicting formation of haloacetic acids by chlorination of organic compounds using machine-learning-assisted quantitative structure-activity relationships》, and you may find the article in Journal of Hazardous Materials.Category: ethers-buliding-blocks The information in the text is summarized as follows:

The presence of disinfection byproducts (DBPs) in drinking water is a major public health concern, and an effective strategy to limit the formation of these DBPs is to prevent their precursors. In silico prediction from chem. structure would allow rapid identification of precursors and could be used as a prescreening tool to prioritize testing. We present models using machine learning algorithms (i.e., support vector regressor, random forest regressor, and multilayer perceptron regressor) and chem. descriptors as features to predict the formation of haloacetic acids (HAAs). A robust model with good predictivity (i.e., leave-one-out cross-validated Q2 > 0.5) to predict the formation of trichloroacetic acid (TCAA) was developed using a random forest regressor. The number of aromatic bonds, hydrophilicity, and electrotopol. descriptors related to electrostatic interactions and the at. distribution of electronegativity were identified as important predictors of TCAA formation potentials (FPs). However, the prediction of dichloroacetic acid was less accurate, which is congruent with the presence of different types of precursors exhibiting distinct mechanisms. This study demonstrates that nonlinear combinations of general chem. descriptors can adequately estimate HAAFPs, and we hope that our study can be used to predict precursors of other disinfection byproducts based on chem. structures using a similar workflow. In the experiment, the researchers used many compounds, for example, m-Methoxyphenol(cas: 150-19-6Category: ethers-buliding-blocks)

m-Methoxyphenol(cas: 150-19-6) may be used in synthesis of:C(4) symmetric calix[4]resorcinarene, 2-nitroso-5-methoxyphenol, 6-methoxy-2(3H)-benzoxazoloneCategory: ethers-buliding-blocks

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

In 2022,He, Shun-Dong; Guo, Xiao-Qiang; Li, Jun; Zhang, Yu-Cheng; Chen, Lian-Mei; Kang, Tai-Ran published an article in European Journal of Organic Chemistry. The title of the article was 《Base-Promoted Reaction of Phenols with Spirocylic λ3-Iodanes: Access to Both 2-Iodovinyl Aryl Ethers and Diaryl Ethers》.HPLC of Formula: 150-19-6 The author mentioned the following in the article:

Herein, an efficient method for vinyl or aryl C(sp2)-O bond forming to construct both the (Z)-2-iodovinyl aryl ethers and diaryl ethers under metal-, photocatalyst- and light-free condition in one-step, has been developed. To generate the two desired products, authors proposed a SNAr2 reaction of phenol with vinyl aryl iodonium salts intermediates that subsequently lead to the phenyl-I bond cleavage and phenyl-O bond formation. Authors firstly found that the vinyl aryl iodonium salts was formed in situ from the spiro-cis-β-phenol-VBXs, which was generated between electrophilic spiro-EBXs and nucleophilic arylols. Trisubstituted alkenes and functionalized diaryl ethers can be afforded from the two desired products. In the part of experimental materials, we found many familiar compounds, such as m-Methoxyphenol(cas: 150-19-6HPLC of Formula: 150-19-6)

m-Methoxyphenol(cas: 150-19-6) may be used in synthesis of:C(4) symmetric calix[4]resorcinarene, 2-nitroso-5-methoxyphenol, 6-methoxy-2(3H)-benzoxazoloneHPLC of Formula: 150-19-6

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Yu, Jianjin; Li, Chao-Jun; Zeng, Huiying published an article in 2021. The article was titled 《Dearomatization-Rearomatization Strategy for ortho-Selective Alkylation of Phenols with Primary Alcohols》, and you may find the article in Angewandte Chemie, International Edition.Category: ethers-buliding-blocks The information in the text is summarized as follows:

Phenols are common precursors and core structures of a variety of industrial chems. ranging from pharmaceuticals to polymers. However, the synthesis of site-specifically substituted phenols is challenging, and thus the development of new methods for this purpose would be highly desirable. Reported here is a protocol for palladium-catalyzed ortho-selective alkylation reactions of phenols with primary alcs. by a dearomatization-rearomatization strategy, with water as the sole byproduct. Various substituted phenols and primary alcs. were compatible with the standard reaction conditions. The detailed mechanism of this transformation was also investigated. After reading the article, we found that the author used m-Methoxyphenol(cas: 150-19-6Category: ethers-buliding-blocks)

m-Methoxyphenol(cas: 150-19-6) may be used as an analytical standard for the determination of the analyte in wine, coffee beans, wood samples, and mainstream smoke by gas chromatography (GC) based techniques.Category: ethers-buliding-blocks

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

In 2022,Zhu, Longfei; Ye, Sen; Zhu, Jiazheng; Duan, Chengjie; Li, Kun; He, Guangke; Liu, Xiang published an article in ACS Sustainable Chemistry & Engineering. The title of the article was 《Tartaric Acid-Assisted Synthesis of Well-Dispersed Ni Nanoparticles Supported on Hydroxyapatite for Efficient Phenol Hydrogenation》.Computed Properties of C7H8O2 The author mentioned the following in the article:

Developing highly active nonnoble-metal-based heterogeneous catalysts for selective hydrogenation is a long-sought goal due to the scarcity and high price of noble metals. Herein, well-dispersed and small-sized Ni nanoparticles (NPs) supported on hydroxyapatite (Ni-TA/HAP) were prepared using a simple tartaric acid (TA)-assisted impregnation method, which is based on the coupling interaction of strong electrostatic adsorption between the HAP and TA and reactive metal-ligand chelation between Ni and TA. Under mild conditions (e.g., 1 mol % Ni, 3 bar H2 at 80°C), the as-synthesized Ni-TA/HAP exhibited excellent activity and selectivity (>99%) for the efficient hydrogenation of phenolic compounds to the corresponding cyclohexanols, as well as the controlled partial hydrogenation of N-heteroarenes. Characterization results revealed that TA addition could promote a better dispersion of Ni species and inhibit the aggregation of Ni NPs during the fabrication of the Ni-TA/HAP catalyst. An optimal TA dosage (nTA/nNi = 0.5) as well as a low Ni loading (1.0 weight %) coconstructed the favorable microstructure of the well-dispersed Ni nanoparticles as the catalytic center. The hydrogenation was boosted by small-sized Ni nanoparticles with a high ability for H2 activation and HAP with both base and acid sites for appreciating phenol absorption. The experimental part of the paper was very detailed, including the reaction process of m-Methoxyphenol(cas: 150-19-6Computed Properties of C7H8O2)

m-Methoxyphenol(cas: 150-19-6) may be used as an analytical standard for the determination of the analyte in wine, coffee beans, wood samples, and mainstream smoke by gas chromatography (GC) based techniques.Computed Properties of C7H8O2

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

In 2019,Journal of the American Chemical Society included an article by Xu, Jiancong; Chen, Jingjing; Gao, Feng; Xie, Shuguang; Xu, Xiaohua; Jin, Zhong; Yu, Jin-Quan. Related Products of 150-19-6. The article was titled 《Sequential Functionalization of meta-C-H and ipso-C-O Bonds of Phenols》. The information in the text is summarized as follows:

The use of a template as a linchpin motif in directed remote C-H functionalization is a versatile yet relatively underexplored strategy. We have developed a template-directed approach to realizing one-pot sequential palladium-catalyzed meta-selective C-H olefination of phenols, and nickel-catalyzed ipso-C-O activation and arylation. Thus, this bifunctional template converts phenols to synthetically useful 1,3-disubstituted arenes. In the experiment, the researchers used m-Methoxyphenol(cas: 150-19-6Related Products of 150-19-6)

m-Methoxyphenol(cas: 150-19-6) may be used in synthesis of:C(4) symmetric calix[4]resorcinarene, 2-nitroso-5-methoxyphenol, 6-methoxy-2(3H)-benzoxazoloneRelated Products of 150-19-6

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

In 2019,Chinese Journal of Chemical Engineering included an article by Han, Hongjing; Li, Jinxin; Wang, Haiying; Xue, Feng; Chen, Yanguang; Zhang, Yanan; Wang, Yizhen; Zhang, Mei. Recommanded Product: m-Methoxyphenol. The article was titled 《Catalytic depolymerization of calcium lignosulfonate by NiMgFeOx derived from sub-micron sized NiMgFe hydrotalcite prepared by introducing hydroxyl compounds》. The information in the text is summarized as follows:

A new method for regulating the synthesis of NiMgFe hydrotalcites (NMF LDHs) with the addition of hydroxyl compounds was proposed. A series of NMF LDHs were prepared by the above method, and then were calcined to obtain the NiMgFeOx(NMFOx) samples. The NMFOxsamples were characterized by XRD, SEM, TG-DTG, XPS and CO2-TPD, resp. The catalytic performance of NMFOx for depolymerizing calcium lignosulfonate (CLS) was evaluated by hydrothermal reaction. The results showed that the addition of hydroxyl compounds favored reducing the particle sizes of NMF LDHs. For the depolymerization of CSL, the yield of liquid product increased from 45% to 75.8% with the addition of NMFOx-ethanol (NMFOxET). The liquid products were mainly phenolics, aromatics, ketones and esters. The total selectivity of oxy-containing compounds was over 90.6%, among them, the phenolics were approx. 35.2%. The valence of Ni and Fe, crystalline phase and basicity almost remained unchanged. The NMFOx-ET samples were recycled for the depolymerization of CLS, moreover, the NMFOx-ET samples had high activity and stability after 4 cycles. The results came from multiple reactions, including the reaction of m-Methoxyphenol(cas: 150-19-6Recommanded Product: m-Methoxyphenol)

m-Methoxyphenol(cas: 150-19-6) may be used in synthesis of:C(4) symmetric calix[4]resorcinarene, 2-nitroso-5-methoxyphenol, 6-methoxy-2(3H)-benzoxazoloneRecommanded Product: m-Methoxyphenol

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Related Products of 150-19-6In 2020 ,《Access to Vinyl Ethers and Ketones with Hypervalent Iodine Reagents as Oxy-Allyl Cation Synthetic Equivalents》 was published in Angewandte Chemie, International Edition. The article was written by Declas, Nina; Waser, Jerome. The article contains the following contents:

We report an Umpolung strategy of enol ethers to generate oxy-allyl cation equivalent based on the use of hypervalent iodine reagents. Under mild basic conditions, the addition of nucleophiles to aryloxy-substituted vinylbenziodoxolone (VBX) reagents, easily available in two steps from silyl alkynes, resulted in the stereoselective formation of substituted aryl enol ethers. The reaction was most efficient with phenols as nucleophiles, but preliminary results were also achieved for C- and N- nucleophiles. In absence of external nucleophiles, the 2-iodobenzoate group of the reagent was transferred. The obtained aryl enol ethers could then be transformed into α-difunctionalized ketones by oxidation The described “”allyl cation””-like reactivity contrast with the well-established “”vinyl-cation”” behavior of alkenyl iodonium salts. Thus, e.g., reaction of I with p-cresol afforded allyl ether II (80%) in DME with KOtBu as base; in absence of external nucleophile, allylic ester III was obtained (65%). In the experiment, the researchers used m-Methoxyphenol(cas: 150-19-6Related Products of 150-19-6)

m-Methoxyphenol(cas: 150-19-6) may be used as an analytical standard for the determination of the analyte in wine, coffee beans, wood samples, and mainstream smoke by gas chromatography (GC) based techniques.Related Products of 150-19-6

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem