Category: 150-19-6

In 2022,Xie, Huilin; Lin, Chuankai; Wang, Ruixiang; Liu, Jin-Biao published an article in Tetrahedron Letters. The title of the article was 《Synthesis of salicylates from anionically activated aromatic trifluoromethyl group》.Application of 150-19-6 The author mentioned the following in the article:

An efficient approach to salicylates via a novel transformation of anionically activated aromatic trifluoromethyl group is described. 2-(Trifluoromethyl)phenol reacts with phenols/alcs. under alk. conditions to afford the corresponding aryl/alkyl salicylates in high yields. Mechanism studies indicated that the carbonyl oxygen atom of ester is from the H2O in the solvent. The experimental process involved the reaction of m-Methoxyphenol(cas: 150-19-6Application of 150-19-6)

m-Methoxyphenol(cas: 150-19-6) may be used as an analytical standard for the determination of the analyte in wine, coffee beans, wood samples, and mainstream smoke by gas chromatography (GC) based techniques.Application of 150-19-6

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

The author of 《Visible light induced oxidative hydroxylation of boronic acids》 were Ding, Aishun; Zhang, Yanbin; Chen, Yang; Rios, Ramon; Hu, Jianhua; Guo, Hao. And the article was published in Tetrahedron Letters in 2019. HPLC of Formula: 150-19-6 The author mentioned the following in the article:

A visible light-induced aerobic oxidative hydroxylation of boronic acids was reported. The reaction employed 7H-benzo[c]thioxanthen-7-one as metal-free catalyst and di-Me carbonate as green solvent. Scale-up experiment was achieved using 0.1 mol% catalyst in a good yield with column-free purification This reaction showed great green chem. features and potential in synthetic applications. The results came from multiple reactions, including the reaction of m-Methoxyphenol(cas: 150-19-6HPLC of Formula: 150-19-6)

m-Methoxyphenol(cas: 150-19-6) may be used as an analytical standard for the determination of the analyte in wine, coffee beans, wood samples, and mainstream smoke by gas chromatography (GC) based techniques.HPLC of Formula: 150-19-6

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

In 2022,Jia, Le; Li, Chao-Jun; Zeng, Huiying published an article in Chinese Chemical Letters. The title of the article was 《Cleavage/cross-coupling strategy for converting β-O-4 linkage lignin model compounds into high valued benzyl amines via dual C-O bond cleavage》.Quality Control of m-Methoxyphenol The author mentioned the following in the article:

Lignin is the most recalcitrant of the three components of lignocellulosic biomass. The strength and stability of the linkages have long been a great challenge for the degradation and valorization of lignin biomass to obtain bio-fuels and com. chems. Up to now, the selective cleavage of C-O linkages of lignin to afford chems. contains only C, H and O atoms. Authors’ group has developed a cleavage/cross-coupling strategy for converting 4-O-5 linkage lignin model compounds into high value-added compounds Herein, a palladium-catalyzed cleavage/cross-coupling of the β-O-4 lignin model compounds with amines via dual C-O bond cleavage for the preparation of benzyl amine compounds and phenols is presented. In the experiment, the researchers used m-Methoxyphenol(cas: 150-19-6Quality Control of m-Methoxyphenol)

m-Methoxyphenol(cas: 150-19-6) may be used in synthesis of:C(4) symmetric calix[4]resorcinarene, 2-nitroso-5-methoxyphenol, 6-methoxy-2(3H)-benzoxazoloneQuality Control of m-Methoxyphenol

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

In 2022,Hebade, Madhav J.; Shimpi, Ravindra P.; Chavan, Omprakash S. published an article in Pharma Chemica. The title of the article was 《Microwave assisted, fly ash catalyzed synthesis of coumarin derivatives: green approach》.Synthetic Route of C7H8O2 The author mentioned the following in the article:

Solvent free synthesis of substituted coumarin by Von Pechmann condensation of phenols with β-ketoesters catalyzed by fly ash as a byproduct from thermal power station by microwave irradiation method is reported. Authors present protocol is economical and clean comprise of green reagent, solvent and catalyst. The experimental process involved the reaction of m-Methoxyphenol(cas: 150-19-6Synthetic Route of C7H8O2)

m-Methoxyphenol(cas: 150-19-6) may be used in synthesis of:C(4) symmetric calix[4]resorcinarene, 2-nitroso-5-methoxyphenol, 6-methoxy-2(3H)-benzoxazoloneSynthetic Route of C7H8O2

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

In 2022,Nguyen, Nguyen H.; Oh, Soo Min; Park, Cheol-Min; Shin, Seunghoon published an article in Chemical Science. The title of the article was 《Ortho-selective C-H arylation of phenols with N-carboxyindoles under Bronsted acid- or Cu(I)-catalysis》.Related Products of 150-19-6 The author mentioned the following in the article:

Control over chemo- and regioselectivity is a critical issue in the heterobiaryl synthesis via C-H oxidative coupling. To address this challenge, a strategy to invert the normal polarity of indoles in the heterobiaryl coupling was developed. With N-carboxyindoles as umpoled indoles, an exclusively ortho-selective coupling with phenols was realized for the synthesis of aryl indoles I [R1 = H, 4-Me, 7-F, etc.; R2 = t-Bu, Ph, 1-naphthyl, etc.; Ar’ = 2-OH-4-MeC6H3, 2-OH-5-MeC6H3, 2-OH-4-MeOC6H3, etc.], employing a Bronsted acid- or Cu(I)-catalyst (as low as 0.01 mol%). A range of phenols and N-carboxyindoles coupled with exceptional efficiency and selectivity at ambient temperature and the substrates bearing redox-active aryl halides (-Br and -I) smoothly coupled in an orthogonal manner. Notably, preliminary examples of atropselective heterobiaryl coupling were demonstrated, based on a chiral disulfonimide or a Cu(I)/chiral bisphosphine catalytic system. The reaction was proposed to occur through SN2′ substitution or a Cu(I)-Cu(III) cycle, with Bronsted acid or Cu(I) catalysts, resp.m-Methoxyphenol(cas: 150-19-6Related Products of 150-19-6) was used in this study.

m-Methoxyphenol(cas: 150-19-6) may be used in synthesis of:C(4) symmetric calix[4]resorcinarene, 2-nitroso-5-methoxyphenol, 6-methoxy-2(3H)-benzoxazoloneRelated Products of 150-19-6

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Wang, Jingyang; Wang, Yu; Ding, Guangni; Wu, Xiaoyu; Yang, Liqun; Fan, Sijie; Zhang, Zhaoguo; Xie, Xiaomin published an article in 2021. The article was titled 《Nickel-catalyzed deallylation of aryl allyl ethers with hydrosilanes》, and you may find the article in Tetrahedron Letters.Application In Synthesis of m-Methoxyphenol The information in the text is summarized as follows:

An efficient and mild catalytic deallylation method of aryl allyl ethers was developed, with com. available Ni(COD)2 as catalyst precursor, simple substituted bipyridine as ligand and air-stable hydrosilanes. The process was compatible with a variety of functional groups and the desired phenol products can be obtained with excellent yields and selectivity. Besides, by detection or isolation of key intermediates, mechanism studies confirm that the deallylation undergoes η3-allylnickel intermediate pathway. In the experiment, the researchers used m-Methoxyphenol(cas: 150-19-6Application In Synthesis of m-Methoxyphenol)

m-Methoxyphenol(cas: 150-19-6) may be used as an analytical standard for the determination of the analyte in wine, coffee beans, wood samples, and mainstream smoke by gas chromatography (GC) based techniques.Application In Synthesis of m-Methoxyphenol

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

In 2022,Sharapov, Ainur D.; Fatykhov, Ramil F.; Khalymbadzha, Igor A.; Sharutin, Vladimir V.; Santra, Sougata; Zyryanov, Grigory V.; Chupakhin, Oleg N.; Ranu, Brindaban C. published an article in Green Chemistry. The title of the article was 《Mechanochemical synthesis of coumarins via Pechmann condensation under solvent-free conditions: an easy access to coumarins and annulated pyrano[2,3-f] and [3,2-f]indoles》.Safety of m-Methoxyphenol The author mentioned the following in the article:

A green protocol has been developed for the synthesis of simple coumarins, e.g., I linear pyrano[2,3-f] and [3,2-f]indoles by the reaction of phenol derivatives ROH (R = 3,5-(OH)2C6H3, 4-Br-3-OHC6H3, 3-OMeC6H4) with β-ketoesters, e.g., cyclohexanecarboxylic acid, 2-oxo-, Et ester under ball milling at ambient temperature in the presence of methanesulfonic acid as a mild acid catalyst. The significant advantages of this procedure are high yields, scalability, no use of hazardous acids or solvents, shorter reaction time, ambient temperature, low cost, and straightforward purification without column chromatog. This procedure is associated with high EcoScale metrics and a low E-factor. In contrast to traditional Pechmann condensation procedures, the mechanochem. protocol leads to the synthesis of pyranoindoles with excellent regioselectivity and high yields.m-Methoxyphenol(cas: 150-19-6Safety of m-Methoxyphenol) was used in this study.

m-Methoxyphenol(cas: 150-19-6) may be used in synthesis of:C(4) symmetric calix[4]resorcinarene, 2-nitroso-5-methoxyphenol, 6-methoxy-2(3H)-benzoxazoloneSafety of m-Methoxyphenol

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

《Carbamates: A Directing Group for Selective C-H Amidation and Alkylation under Cp*Co(III) Catalysis》 was published in Organic Letters in 2020. These research results belong to Bera, Sourav Sekhar; Maji, Modhu Sudan. Quality Control of m-Methoxyphenol The article mentions the following:

The selective reactivity of carbamate and thiocarbamate toward alkylation and amidation corresponding alkyl-carbamates e.g., I and amidyl-thiocarbamates e.g., II to get was reported under stable, high-valent, cost-effective cobalt(III) catalysis. This method revealed the wide possibility of designing a different branch of synthetically challenging yet highly promising asym. catalysts based on BINOL and SPINOL scaffolds. Late-stage C-H functionalization of L-tyrosine and estrone was also achieved through this approach. The mechanistic study shows that a base-assisted internal electrophilic substitution mechanism is operative here. After reading the article, we found that the author used m-Methoxyphenol(cas: 150-19-6Quality Control of m-Methoxyphenol)

m-Methoxyphenol(cas: 150-19-6) may be used in synthesis of:C(4) symmetric calix[4]resorcinarene, 2-nitroso-5-methoxyphenol, 6-methoxy-2(3H)-benzoxazoloneQuality Control of m-Methoxyphenol

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

《Visible-light photoredox-catalyzed C-O bond cleavage of diaryl ethers by acridinium photocatalysts at room temperature》 was published in Nature Communications in 2020. These research results belong to Tan, Fang-Fang; He, Xiao-Ya; Tian, Wan-Fa; Li, Yang. Recommanded Product: 150-19-6 The article mentions the following:

Visible-light photoredox-catalyzed C-O bond cleavage of diaryl ethers by an acidolysis with an aryl carboxylic acid and a following one-pot hydrolysis was reported. Two mols. of phenols were obtained from one mol. of diaryl ether at room temperature The aryl carboxylic acid used for the acidolysis was recovered. The key to success of the acidolysis was merging visible-light photoredox catalysis using an acridinium photocatalyst and Lewis acid catalysis using Cu(TMHD)2. Preliminary mechanistic studies indicated that the catalytic cycle occurred via a rare selective electrophilic attack of the generated aryl carboxylic radical on the electron-rich aryl ring of the di-Ph ether. This transformation was applied to a gram-scale reaction and the model of 4-O-5 lignin linkages.m-Methoxyphenol(cas: 150-19-6Recommanded Product: 150-19-6) was used in this study.

m-Methoxyphenol(cas: 150-19-6) may be used in synthesis of:C(4) symmetric calix[4]resorcinarene, 2-nitroso-5-methoxyphenol, 6-methoxy-2(3H)-benzoxazoloneRecommanded Product: 150-19-6

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Tavakolian, Mina; Keshavarz, Kimia; Hosseini-Sarvari, Mona published their research in Molecular Catalysis in 2021. The article was titled 《Cu2O/TiO2 as sustainable and recyclable photocatalyst for gram-scale synthesis of phenols in water》.Product Details of 150-19-6 The article contains the following contents:

A green and straightforward protocol was developed for the synthesis of phenols from aryl boronic acid using an inexpensive and available Cu2O/TiO2 photocatalyst under visible light and sunlight. This approach proceeded in mild reaction conditions in water and the presence of air as a green oxidant, resulting in the corresponding phenols in good to excellent yields. Sunlight was also a sustainable source for this photochem. reaction. Heterogeneous nano photocatalyst was successfully recovered in 8 consecutive runs. It is noteworthy that, the photocatalyst exhibited high activity for the large-scale synthesis of phenols. The experimental process involved the reaction of m-Methoxyphenol(cas: 150-19-6Product Details of 150-19-6)

m-Methoxyphenol(cas: 150-19-6) may be used in synthesis of:C(4) symmetric calix[4]resorcinarene, 2-nitroso-5-methoxyphenol, 6-methoxy-2(3H)-benzoxazoloneProduct Details of 150-19-6

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem