Category: 146370-51-6

On October 27, 2015, Menk, Florian; Mondeshki, Mihail; Dudenko, Dmytro; Shin, Suyong; Schollmeyer, Dieter; Ceyhun, Oliver; Choi, Tae-Lim; Zentel, Rudolf published an article.Quality Control of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene The title of the article was Reactivity Studies of Alkoxy-Substituted [2.2]Paracyclophane-1,9-dienes and Specific Coordination of the Monomer Repeating Unit during ROMP. And the article contained the following:

The polymerization of alkoxy-substituted [2.2]paracyclophane-1,9-dienes via ring-opening metathesis polymerization (ROMP) to obtain soluble poly(p-phenylenevinylene)s is a versatile method due to its living nature which enables the possibility of block copolymerization and end group modification. However, detailed studies on the reactivity behavior and the polymerization process of alkoxy-substituted [2.2]paracyclophane-1,9-dienes have not been reported so far. Herein we present a detailed study on the varying tendencies of the four isomers of dimethoxy-(2-ethylhexyloxy)-[2.2]paracyclophane-1,9-diene to undergo ROMP. Therefore, we carried out polymerization combining all individual isomers with five different metathesis catalysts and collected initiation and propagation kinetics for various combinations. Furthermore, we revealed a specific coordination of the monomer repeating unit to the catalyst during the polymerization process and succeeded to polymerize not only the pseudogeminal isomers but also one of the pseudo-ortho isomers. The experimental process involved the reaction of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene(cas: 146370-51-6).Quality Control of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene

The Article related to alkoxy paracyclophane diene isomer reactivity romp kinetics, Chemistry of Synthetic High Polymers: Polymerization Kinetics, Mechanisms, Thermodynamics, Catalysis, Catalysts and other aspects.Quality Control of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene

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Ether | (C2H5)2O – PubChem

On March 31, 2005, Kalgutkar, Rajdeep S.; Palazzotto, Michael C. published a patent.Recommanded Product: 146370-51-6 The title of the patent was Arylsulfinate salts in initiator systems for polymeric reactions. And the patent contained the following:

Compositions are provided that can be used as an initiator system for free radical polymerization reactions. More specifically, the initiator systems include an electron acceptor and an electron donor. The electron donors are arylsulfinate salts having a cation that contains at least one carbon atom and either a pos. charged nitrogen atom or a pos. charged phosphorus atom. Methods of polymerization are also provided that can be used to prepare polymeric material with the initiator systems. The initiator systems can be thermal initiator systems, photoinitiator systems, or combinations thereof. The experimental process involved the reaction of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene(cas: 146370-51-6).Recommanded Product: 146370-51-6

The Article related to arylsulfinate initiator photoinitiator, Chemistry of Synthetic High Polymers: Polymerization Kinetics, Mechanisms, Thermodynamics, Catalysis, Catalysts and other aspects.Recommanded Product: 146370-51-6

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Buhrmester, Claudia; Chen, Jun; Moshurchak, Lee; Jiang, Junwei; Wang, Richard Liangchen; Dahn, J. R. published an article in 2005, the title of the article was Studies of Aromatic Redox Shuttle Additives for LiFePO4-Based Li-Ion Cells.Safety of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene And the article contains the following content:

Fifty eight aromatic organic mols. were screened as chem. shuttles to provide overcharge protection for LiFePO4/graphite and LiFePO4/Li4/3Ti5/3O4 Li-ion cells. The majority of the mols. were based on methoxybenzene and on dimethoxybenzene with a variety of ligands added to explore their effect. The added ligands affect the redox potential of the mols. through their electron-withdrawing effect and affect the stability of the radical cation. Of all the mols. tested, only 2,5-di-tert-butyl-1,4-dimethoxybenzene shows an appropriate redox potential of 3.9 V vs. Li/Li+ and long-term stability during extended abusive overcharge totaling over 300 cycles of 100% overcharge per cycle. The reasons for the success of this mol. are explored. The experimental process involved the reaction of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene(cas: 146370-51-6).Safety of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene

The Article related to aromatic shuttle battery electrolyte additive secondary lithium methoxybenzene derivative, Electrochemical, Radiational, and Thermal Energy Technology: Energy-Conversion Devices and Their Components and other aspects.Safety of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene

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Ether – Wikipedia,
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On August 31, 2006, Lin, King-Fu; Fan, Yang-Liang; Chow, Hsuan-Liang published an article.Category: ethers-buliding-blocks The title of the article was Origin of the methylene bonds in poly[2-methoxy-5-(2′-ethyl-hexyloxy)-1,4-phenylenevinylene] prepared according to Gilch’s method: novel applications. And the article contained the following:

Impurities containing methylene bridges between 2-((2′-ethylhexyl)oxy)-5-methoxy-benzene mols. are inevitably formed during the synthesis of 1,4-bis(chloromethyl)-2-((2′-ethylhexyl)oxy)-5-methoxy-benzene, the monomer used in the preparation of poly[2-methoxy-5-(2′-ethyl-hexyloxy)-1,4-phenylenevinylene] (MEH-PPV), but they can be removed by double recrystallization of the monomer prior to polymerization When impurities containing methylene bridges participate in a Gilch polymerization, the methylene bonds formed in the main chains are prone to break at 200 °C, i.e., at least 150 °C below the major degradation temperature of defect-free MEH-PPV. Interestingly, the thermal treatment used to break the methylene bonds bonds present reduces the chain aggregation of MEH-PPV during film formation and induces its blends with poly(2,3-diphenyl-5-octyl-p-phenylene-vinylene) (DPO-PPV) to form a morphol. similar to that of block copolymers. Both significantly enhance the luminescence properties. The experimental process involved the reaction of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene(cas: 146370-51-6).Category: ethers-buliding-blocks

The Article related to polyphenylenevinylene synthesis monomer impurity methylene bridging exciplex, Physical Properties of Synthetic High Polymers: Analysis, Molecular Weight Determination, and Fractionation and other aspects.Category: ethers-buliding-blocks

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On August 15, 2006, Ma, Ming-you published an article.Application In Synthesis of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene The title of the article was Synthesis of 1-[(2-ethylhexyl)oxy]-4-methoxybenzene under ultrasound conditions. And the article contained the following:

1-[(2-Ethylhexyl)oxy]-4-methoxybenzene (MOEHOB) was synthesized by the reaction of 4-methoxyphenol (MOPh) with 2-ethylhexyl bromide in argon atm. under supersonic irradiation in the solution of sodium ethoxide. Reaction yields reached 86-88%. The optimum reaction conditions: molar ratio of MOPh/ethylhexyl bromide was 1:1.5, the concentration of sodium ethoxide was 2.5 mol/L, the frequency of the ultrasound was 40 kHz, the reaction time was 5-6 h. The experimental process involved the reaction of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene(cas: 146370-51-6).Application In Synthesis of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene

The Article related to ethylhexyloxy methoxy benzene preparation, methoxyphenol ethylhexylbromide williamson ether synthesis ultrasound, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Application In Synthesis of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene

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On April 8, 2004, Leatherdale, Catherine A.; Schardt, Craig R.; Thompson, D. Scott; Thompson, Wendy L. published a patent.COA of Formula: C15H24O2 The title of the patent was Photolithographic and photochemical fabrication of planar inorganic device. And the patent contained the following:

A method for making an inorganic structure includes: (a) applying a photoreactive composition to a substrate, wherein the composition includes: a reactive species, a photoinitiator system, and a plurality of substantially inorganic colloidal particles, wherein the particles have an average particle size of less than about 300 nm; (b) photopatterning the composition to define a structure; and (c) subjecting the structure to elevated temperature for a time sufficient to pyrolyze the reactive species and to at least partially fuse the particles. The invention allows fabrication of inorganic structures, such as planar waveguides and splitters, using inexpensive solution processing and conventional photopatterning. The invention provides the ability to use photoimageable resins including uniformly dispersed, non-aggregated particles to form high resolution features (micron) with little resolution loss due to scattering. Addition of inorganic particles to the reactive composition allows tailoring of the optical, thermal, mech., and dielec. properties of the composite, while maintaining the speed, easy processing, and flexible chem. provided by the organic components of the composition Following imaging, the completed structure can be left as is, heated to pyrolyze the organic components and leave a substantially inorganic porous structure, or sintered further to leave a substantially inorganic densified structure. The experimental process involved the reaction of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene(cas: 146370-51-6).COA of Formula: C15H24O2

The Article related to planar inorganic structure device fabrication photolithog wavegiude, Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes: Photoresists and Radiation-Sensitive Resists and other aspects.COA of Formula: C15H24O2

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On May 5, 2008, Naidu, Ajay B.; Sekar, G. published an article.Application In Synthesis of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene The title of the article was An efficient intermolecular BINAM-copper(I) catalyzed Ullmann-type coupling of aryl iodides/bromides with aliphatic alcohols. And the article contained the following:

A wide range of alkyl aryl ethers are synthesized from the corresponding aryl iodides and aliphatic alcs. through Ullmann-type intermol. coupling reactions in the presence of a catalytic amount of easily available BINAM-CuI complex. Less reactive aryl bromides also reacted with aliphatic alcs. under identical conditions to give good yields of the alkyl aryl ethers without increasing the reaction temperature and time. The experimental process involved the reaction of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene(cas: 146370-51-6).Application In Synthesis of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene

The Article related to aryl halide aliphatic alc ullmann coupling binam copper catalyst, alkyl aryl ether, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Phenols, Thiophenols, and Derivatives Including Phenol and Thiophenol Ethers and Esters and other aspects.Application In Synthesis of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene

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Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On November 13, 2001, Oba, Tsuyoshi; Mizushima, Hirozumi; Sone, Hajime; Yamamuro, Akira; Hotta, Mitsuyuki published a patent.Name: 1-((2-Ethylhexyl)oxy)-4-methoxybenzene The title of the patent was Preparation of methoxyphenyl alkyl ethers and blood circulation stimulators as external medicines. And the patent contained the following:

The compounds MeOC6H3R1OR2 (R1 = H, MeO; R2 = C1-18 alkyl, C7-24 aralkyl) are prepared 4-Methoxyphenol was reacted with Bu bromide in the presence of NaOH under reflux for 3 h to give 74.9% Bu 4-methoxyphenyl ether showing good stimulating blood circulation in guinea pig skin. The experimental process involved the reaction of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene(cas: 146370-51-6).Name: 1-((2-Ethylhexyl)oxy)-4-methoxybenzene

The Article related to methoxyphenyl alkyl ether preparation blood circulation stimulator, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Phenols, Thiophenols, and Derivatives Including Phenol and Thiophenol Ethers and Esters and other aspects.Name: 1-((2-Ethylhexyl)oxy)-4-methoxybenzene

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Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

On January 31, 2014, Li, Ruyu; Mo, Yanjiao; Shi, Rong; Li, Peng; Li, Chengyu; Wang, Zhenjiang; Wang, Xun; Li, Shengbiao published an article.Related Products of 146370-51-6 The title of the article was Synthesis and properties of poly(p-phenylene vinylene) derivatives with hyperbranched structure and containing a nitro substituent. And the article contained the following:

In order to improve efficiency, processability, and stability, two groups of novel poly(p-phenylene vinylene) (PPV) derivatives (P1-P3 and P4-P6) with hyperbranched structure and containing a nitro substituent were synthesized via a Gilch reaction in different monomer ratios. The properties of the polymers were investigated by using UV-Vis absorption, fluorescence spectroscopy, cyclic voltammetry, and thermogravimetric anal. The result shows that the band gaps of the PPV derivatives with a nitro substituent were decreased and the polymers had higher mol. weights (106), excellent solubility in common organic solvents, good film-forming ability, and better thermal stability. The polymers can be used as an efficient acceptor material in polymeric solar cells. The experimental process involved the reaction of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene(cas: 146370-51-6).Related Products of 146370-51-6

The Article related to polyphenylenevinylene nitro containing hyperbranched preparation property, hyperbranched, nitro substituent, poly(p-phenylene vinylene) derivatives, properties, synthesis and other aspects.Related Products of 146370-51-6

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Ether | (C2H5)2O – PubChem

Elacqua, Elizabeth; Gregor, Maria published an article in 2019, the title of the article was Poly(arylenevinylene)s through Ring-Opening Metathesis Polymerization of an Unsymmetrical Donor-Acceptor Cyclophane.Recommanded Product: 146370-51-6 And the article contains the following content:

Reported are well-defined donor-acceptor alternating copolymers prepared using ring-opening metathesis polymerization (ROMP). Unsym. cyclophanedienes comprising electron-donating (4-methoxy-1-(2-ethylhexyl)oxy)benzene (MEH) and electron-accepting benzothiadiazole (BT) rings were synthesized from the corresponding [3.3]dithiaparacyclophanes. ROMP of the strained unsym. and “electronically-ambiguous” cyclophanedienes proceeded in a controlled manner in the presence of either Hoveyda-Grubbs II or Grubbs II initiator in wake of both steric and electronic encumbrance. The resulting polymers, comprising alternating BT and MEH-PPV units, are achieved in mol. weights exceeding 20k with D values ranging from 1.1-1.4. The living nature of the polymerization is verified through the formation of rod-coil and rod-rod block copolymers. Our strategy to develop previously unrealized polymers from functional building blocks featuring a locked-in D-A unit is significant in a field striving to achieve well-defined and sequence-specific materials. The experimental process involved the reaction of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene(cas: 146370-51-6).Recommanded Product: 146370-51-6

The Article related to paracyclophane ring opening metathesis polymerization polyarylenevinylene block copolymer, metathesis, paracyclophanes, polymers, ring-opening polymerization, stereoelectronics and other aspects.Recommanded Product: 146370-51-6

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