Category: 10365-98-7

In 2019,Nature (London, United Kingdom) included an article by Berger, Florian; Plutschack, Matthew B.; Riegger, Julian; Yu, Wanwan; Speicher, Samira; Ho, Matthew; Frank, Nils; Ritter, Tobias. Application of 10365-98-7. The article was titled 《Site-selective and versatile aromatic C-H functionalization by thianthrenation》. The information in the text is summarized as follows:

Direct C-H functionalization can quickly increase useful structural and functional mol. complexity. Site selectivity can sometimes be achieved through appropriate directing groups or substitution patterns-in the absence of such functionality, most aromatic C-H functionalization reactions provide more than one product isomer for most substrates. Development of a C-H functionalization reaction that proceeds with high positional selectivity and installs a functional group that can serve as a synthetic linchpin for further functionalization would provide access to a large variety of well-defined arene derivatives Here we report a highly selective aromatic C-H functionalization reaction that does not require a particular directing group or substitution pattern to achieve selectivity, and provides functionalized arenes that can participate in various transformations. We introduce a persistent sulfur-based radical to functionalize complex arenes with high selectivity and obtain thianthrenium salts, e.g., I that are ready to engage in different transformations, via both transition-metal and photoredox catalysis. This transformation differs fundamentally from all previous aromatic C-H functionalization reactions in that it provides direct access to a large number of derivatives of complex small mols., quickly generating functional diversity with selectivity that is not achievable by other methods. In the experiment, the researchers used 3-Methoxyphenylboronic acid(cas: 10365-98-7Application of 10365-98-7)

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Application of 10365-98-7

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Li, Bo; Yang, Chenxin; Wang, Xinhao; Li, Guangwu; Peng, Wangwang; Xiao, Huiping; Luo, Shenglian; Xie, Sheng; Wu, Jishan; Zeng, Zebing published their research in Angewandte Chemie, International Edition in 2021. The article was titled 《Synthesis and Structural Elucidation of Bisdibenzocorannulene in Multiple Redox States》.Reference of 3-Methoxyphenylboronic acid The article contains the following contents:

An anti-folded bowl-shaped bisdibenzocorannulene (BDBC) featuring a new chair-cyclohexane-like hexagon as a bridge of two dibenzocorannulene moieties was reported. The neutral compound showed multiple redox-active properties and could be converted to the corresponding redox states through chem. reduction or oxidation Chem. reduction of BDBC by stoichiometric addition of metallic potassium in the presence of [18]crown-6 ether, provided a radical anion BDBC.- and a dianion BDBC2-, resp.; while chem. oxidation by silver hexafluoroantimonate(V), converted the neutral compound to an open-shell singlet diradical dication (BDBC••)2+. The structural consequences of both electron-reduction and oxidation were closely related to the release of ring-strain of the bowl-shaped π-scaffold and imposed steric hindrance of the hexagonal bridge. In addition, the unusual open-shell nature of the dication could mainly be attributed to the changing of localized antiaromaticity in the closed-shell structure to delocalized character in the biradical, and thus the emergence of weakly bonded π-electrons.3-Methoxyphenylboronic acid(cas: 10365-98-7Reference of 3-Methoxyphenylboronic acid) was used in this study.

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Reference of 3-Methoxyphenylboronic acid

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Hoshikawa, Shoki; Yanai, Hikaru; Martin-Mejias, Irene; Lazaro-Milla, Carlos; Aragoncillo, Cristina; Almendros, Pedro; Matsumoto, Takashi published an article in 2021. The article was titled 《Synthesis of Polycyclic Aromatic Hydrocarbons Decorated by Fluorinated Carbon Acids/Carbanions》, and you may find the article in Chemistry – A European Journal.Related Products of 10365-98-7 The information in the text is summarized as follows:

The carboarylation reaction of biphenyl-alkynes was successfully triggered by electrophilic attack of 1,1-bis(triflyl)ethylene on the alkyne moiety to give polycyclic aromatic hydrocarbons (PAHs), e.g., I, decorated by superacidic carbon acid functionality. Neutralization of thus obtained acids with NaHCO3 yielded the corresponding sodium salts, e.g., II•Na+, which showed improved solubility in both aqueous and organic solvents. The experimental process involved the reaction of 3-Methoxyphenylboronic acid(cas: 10365-98-7Related Products of 10365-98-7)

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Related Products of 10365-98-7

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Recommanded Product: 3-Methoxyphenylboronic acidIn 2019 ,《Heterogeneous Chiral Diene-Rh Complexes for Asymmetric Arylation of α,β-Unsaturated Carbonyl Compounds, Nitroalkenes, and Imines》 appeared in Advanced Synthesis & Catalysis. The author of the article were Kuremoto, Tatsuya; Yasukawa, Tomohiro; Kobayashi, Shu. The article conveys some information:

A chiral diene ligand with tertiary alkyl amine-derived secondary amide moiety was immobilized on cross-linked polystyrene (PS) by radical polymerization, which was combined with Rh to form heterogeneous chiral Rh complexes (PS-diene Rh-Cl). PS-diene Rh-Cl catalyzed asym. arylation reactions of α,β-unsaturated carbonyl compounds (ketones, esters, and amides), nitroalkenes, and imines afforded the desired products in high yields with excellent enantioselectivities. PS-diene Rh-Cl is stable in air, can be stored for several months, and can be reused more than 10 times without any reduction of either yield or enantioselectivity. We also developed a method of activation of PS-diene Rh-Cl to generate more active species. In the experimental materials used by the author, we found 3-Methoxyphenylboronic acid(cas: 10365-98-7Recommanded Product: 3-Methoxyphenylboronic acid)

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Recommanded Product: 3-Methoxyphenylboronic acid

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Ether – Wikipedia,
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《Reductive Hydroxymethylation of 4-Heteroarylpyridines》 was written by Hepburn, Hamish B.; Donohoe, Timothy J.. Recommanded Product: 10365-98-7 And the article was included in Chemistry – A European Journal in 2020. The article conveys some information:

The activation of pyridinium salts with electron-withdrawing heterocycles enabled an iridium-catalyzed reductive hydroxymethylation reaction to proceed smoothly, facilitating the preparation of useful 3D heteroaryl-substituted functionalized piperidines. The methodol. was used to prepare 3-hydroxymethylated analogs of pharmaceutical agents. Mechanistically, formaldehyde acts as both a hydride donor and the electrophile, leading to the formation of two new carbon-hydrogen bonds and one new carbon-carbon bond under relatively mild conditions. In the experimental materials used by the author, we found 3-Methoxyphenylboronic acid(cas: 10365-98-7Recommanded Product: 10365-98-7)

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Recommanded Product: 10365-98-7

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

《Synthesis and optical properties of triphenylene-based donor-donor and donor-acceptor conjugated polymers: a comparative study》 was written by Li, Yong; Nguyen, Dung D.; Shetye, Kuldeep; Peng, Zhonghua. Recommanded Product: 3-Methoxyphenylboronic acidThis research focused ontriphenylene based donor acceptor conjugated polymer synthesis optical property. The article conveys some information:

Two new conjugated polymers (P1 and P2), containing a bithiophene donor unit coupled with either a triphenylene donor unit or an imide-functionalized triphenylene acceptor unit in the backbone, have been synthesized, structurally characterized, and comparatively studied by using 1H NMR, FTIR, gel permeation chromatog., differential scanning calorimetry, cyclic voltammetry, UV-visible absorption, and fluorescence spectroscopy. Both polymers are amorphous in nature and thermally stable up to 450°. The inclusion of the imide functionalization in the triphenylene unit significantly lowered the LUMO energy level and the bandgap of the donor-acceptor polymer P2 over the donor-donor polymer P1. P1 and P2 show very different optical properties in hexane and other solvents. P1 shows a broad emission in hexane but vibronically structured emissions in other solvents; in contrast, P2 exhibits a vibronically resolved emission in hexane, while exhibiting red shifted, broad, and featureless emissions in other solvents. P1 takes a random coil conformation in good solvents like p-xylene, benzene, toluene, anisole, chloroform, THF, and o-dichlorobenzene, whereas in hexane, it may adopt a helical folding conformation. P2, on the other hand, adopts a random coil conformation in hexane but possibly the helical folding conformation in other good solvents. The opposite conformations of the two polymers may be responsible for their opposite solvent-dependent fluorescence properties. In the experiment, the researchers used 3-Methoxyphenylboronic acid(cas: 10365-98-7Recommanded Product: 3-Methoxyphenylboronic acid)

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Recommanded Product: 3-Methoxyphenylboronic acid

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

《Manganese-Catalyzed Hydroarylation of Unactivated Alkenes》 was published in Angewandte Chemie, International Edition in 2020. These research results belong to Liu, Ting; Yang, Yunhui; Wang, Congyang. Name: 3-Methoxyphenylboronic acid The article mentions the following:

Transition-metal-catalyzed hydroarylation of unactivated alkenes with strategic use of remote coordinating functional groups has received significant attention recently to address the issues of both low reactivity and poor selectivity. The bidentate 8-aminoquinoline amide group is the most successfully adopted in unactivated alkenes for Pd and Ni catalysis. The authors describe the first manganese-catalyzed hydroarylation of unactivated alkenes bearing diverse simple functionalities with arylboronic acids. A series of δ- and γ-arylated amides, ketones, pyridines, and amines was accessed with excellent regioselectivity and in high yields. Hydroalkenylation of unactivated alkenes also is applicable under this manganese-catalysis regime. The method features earth-abundant manganese catalysis, easily available substrates, broad functional-group tolerance, and excellent regioselective control. The results came from multiple reactions, including the reaction of 3-Methoxyphenylboronic acid(cas: 10365-98-7Name: 3-Methoxyphenylboronic acid)

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Name: 3-Methoxyphenylboronic acid

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

In 2022,Lakshmidevi, Jangam; Naidu, Bandameeda Ramesh; Reddy, S. Siva Sankara; Venkateswarlu, Katta published an article in Waste and Biomass Valorization. The title of the article was 《Oxidative Iododeborylation Reaction of (Hetero)arylboronic Acids in Water Extract of Pomegranate Ash: A Novel and Sustainable Synthesis of Iodo(hetero)arenes》.Category: ethers-buliding-blocks The author mentioned the following in the article:

A mild and effective process for the (H)AIs synthesis RI (R = 4-nitrophenyl, 2-methoxyphenyl, pyridin-3-yl, etc.) via ipso-functionalization of (H)ABAs RB(OH)2using water extract of pomegranate peel ash (WEPA) and environmentally benign iodinating agent such as mol. iodine (I2) under external oxidant/(transition)metal/base/additive/organic solvent-free conditions have been disclosed. The (H)AIs are formed with high regioselctivity using this protocol that operational simplicity and displays exceptional functional group compatibility. Present (H)AIs synthesis avoid addnl. substances (including metals) as oxidizing reagents, additives/surfactants and catalysts, thus making this procedure as a highly sustainable asset using biorenewable waste based aqueous extract as catalytic media. In the part of experimental materials, we found many familiar compounds, such as 3-Methoxyphenylboronic acid(cas: 10365-98-7Category: ethers-buliding-blocks)

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Category: ethers-buliding-blocks

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Ether – Wikipedia,
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The author of 《Enantioselective Palladium-Catalyzed Cross-Coupling of α-Bromo Carboxamides and Aryl Boronic Acids》 were Li, Bowen; Li, Tiejun; Aliyu, Muinat A.; Li, Zhen Hua; Tang, Wenjun. And the article was published in Angewandte Chemie, International Edition in 2019. HPLC of Formula: 10365-98-7 The author mentioned the following in the article:

We herein report an enantioselective palladium-catalyzed cross-coupling between α-bromo carboxamides and aryl boronic acids, generating a series of chiral α-aryl carboxamides in good yields and excellent enantioselectivities. The development of a chiral P,P=O ligand was critical in overcoming the second transmetalation issue and allows the first asym. palladium-catalyzed coupling of α-bromo carbonyl compounds In the experiment, the researchers used many compounds, for example, 3-Methoxyphenylboronic acid(cas: 10365-98-7HPLC of Formula: 10365-98-7)

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.HPLC of Formula: 10365-98-7

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Magre, Marc; Cornella, Josep published an article in 2021. The article was titled 《Redox-Neutral Organometallic Elementary Steps at Bismuth: Catalytic Synthesis of Aryl Sulfonyl Fluorides》, and you may find the article in Journal of the American Chemical Society.Reference of 3-Methoxyphenylboronic acid The information in the text is summarized as follows:

A Bi-catalyzed synthesis of sulfonyl fluorides from the corresponding (hetero)aryl boronic acids is presented. Authors demonstrate that the organobismuth(III) catalysts bearing a bis-aryl sulfone ligand backbone revolve through different canonical organometallic steps within the catalytic cycle without modifying the oxidation state. All steps have been validated, including the catalytic insertion of SO2 into Bi-C bonds, leading to a structurally unique O-bound bismuth sulfinate complex. The catalytic protocol affords excellent yields for a wide range of aryl and heteroaryl boronic acids, displaying a wide functional group tolerance. The results came from multiple reactions, including the reaction of 3-Methoxyphenylboronic acid(cas: 10365-98-7Reference of 3-Methoxyphenylboronic acid)

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Reference of 3-Methoxyphenylboronic acid

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem