Category: 10365-98-7

In 2022,Ruan, Zhuwei; Wang, Min; Yang, Chen; Zhu, Lili; Su, Zhishan; Hong, Ran published an article in JACS Au. The title of the article was 《Total Synthesis of (+)-Hinckdentine A: Harnessing Noncovalent Interactions for Organocatalytic Bromination》.Product Details of 10365-98-7 The author mentioned the following in the article:

Synthesis of hinckdentine A, a marine-sponge-derived tribrominated indole alkaloid bearing a unique indolo[1,2-c]quinazoline skeleton, was completed in 12 steps featuring the construction of the α-quaternary carbon center by asym. azo-ene cyclization. A novel organocatalyst, e.g., 1-(3,5-bis-trifluoromethyl-phenyl)-3-[2-(diphenyl-phosphinothioyl)-phenyl]-thiourea was developed to promote high-yielding tribromination, which represents a challenging process encountered in previous syntheses. D. functional theory calculations scrutinized viable substrates and deciphered the origin of the enhancement of C8 electrophilic bromination with a bifunctional organocatalyst. Moreover, the application of organocatalyst-enabled bromination on various substrates such as 1H-indazole, 1-isothiocyanato-2,4-dimethoxybenzene, (2H-1,3-benzodioxol-5-yl)methanol, etc. was demonstrated to highlight future late functionalizations of biol. intriguing targets. In the part of experimental materials, we found many familiar compounds, such as 3-Methoxyphenylboronic acid(cas: 10365-98-7Product Details of 10365-98-7)

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Product Details of 10365-98-7

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

In 2019,RSC Advances included an article by Wang, Tao; Guo, Jiarui; Wang, Xiaojuan; Guo, Han; Jia, Dingli; Wang, Hengjin; Liu, Lantao. Quality Control of 3-Methoxyphenylboronic acid. The article was titled 《Cross coupling of benzylammonium salts with boronic acids using a well-defined N-heterocyclic carbene-palladium(II) precatalyst》. The information in the text is summarized as follows:

N-heterocyclic carbene-palladium(II)-catalyzed cross-coupling of benzylammonium salts with arylboronic acids for the synthesis of diarylmethane derivatives via C-N bond activation were developed. Notably, in the presence of the easily prepared and bench-stable Pd-PEPPSI precatalyst, the Csp3-N bond activation of the benzylammonium salt even proceeded smoothly in isopropanol at room temperature The experimental part of the paper was very detailed, including the reaction process of 3-Methoxyphenylboronic acid(cas: 10365-98-7Quality Control of 3-Methoxyphenylboronic acid)

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Quality Control of 3-Methoxyphenylboronic acid

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

In 2019,RSC Advances included an article by Xue, Feng; Liu, Qibin; Zhu, Yong; Qing, Yunfei; Wan, Boshun. Recommanded Product: 10365-98-7. The article was titled 《Chiral benzene backbone-based sulfoxide-olefin ligands for highly enantioselective Rh-catalyzed addition of arylboronic acids to N-tosylarylimines》. The information in the text is summarized as follows:

An efficient Rh-catalyzed addition of arylboronic acids RB(OH)2 (R = Ph, 1-naphthyl, 4-BrC6H4, etc.) to N-tosylarylimines R1CH=NTs (R1 = Ph, 1-naphthyl, 4-BrC6H4, etc.) has been developed with chiral benzene backbone-based sulfoxide-olefin ligands, where 2-methoxy-1-naphthyl sulfinyl functionalized olefin ligands have shown to be more effective. The versatile method tolerates a wide range of functional groups and shows broad scope without regard to electronic or steric substitution pattern, allowing access to a broad range of chiral diarylmethylamines R1CH(R)NTs in high yields (up to 99%) with excellent enantioselectivities (up to 99% ee). After reading the article, we found that the author used 3-Methoxyphenylboronic acid(cas: 10365-98-7Recommanded Product: 10365-98-7)

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Recommanded Product: 10365-98-7

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

The author of 《Coupling of Trifluoroacetaldehyde N-Triftosylhydrazone with Organoboronic Acids for the Synthesis of gem-Difluoroalkenes》 were Ma, Yu; Reddy, Bhoomireddy Rajendra Prasad; Bi, Xihe. And the article was published in Organic Letters in 2019. COA of Formula: C7H9BO3 The author mentioned the following in the article:

The synthesis of alkyl gem-difluoroalkenes remains a difficult task in organic synthesis. Here, a general and efficient approach for tackling this problem by gem-difluoroolefination of trifluoroacetaldehyde N-triftosylhydrazone with organoboronic acids is reported. This protocol is operationally simple, free of transition metals, and suitable for a broad range of organoboronic acids. Moreover, the utility of the products was demonstrated by further conversion of the gem-difluorovinyl group. In the experiment, the researchers used 3-Methoxyphenylboronic acid(cas: 10365-98-7COA of Formula: C7H9BO3)

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.COA of Formula: C7H9BO3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Tang, Huiling; Liu, Mengna; Zhu, Meiqi; Cui, Benqiang; Shi, Yanhui; Cao, Changsheng published an article in 2021. The article was titled 《C(sp2)-C(sp2) Suzuki cross-coupling of arylammonium salts catalyzed by a stable Pd-NHC complex》, and you may find the article in Tetrahedron.Formula: C7H9BO3 The information in the text is summarized as follows:

The authors developed the Suzuki-Miyaura cross-coupling of aryl ammonium salts via C-N bond activation catalyzed by an easily prepared and bench-stable palladium-N-heterocyclic carbene complex. The reaction proceeded well under mild conditions with phenylboronic acid and pinacol ester or anhydride and provided biaryls Ar1-Ar2 [Ar1 = 1-naphthyl, Ph, 2-pyridyl, etc., Ar2 = Ph, 4-MeC6H4, 4-PhC6H4, etc.] in up to 97% yield with good functional group compatibility. The direct arylation of arylamine could be performed by a two-step, one-pot process and a protocol could be performed on the gram scale. After reading the article, we found that the author used 3-Methoxyphenylboronic acid(cas: 10365-98-7Formula: C7H9BO3)

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Formula: C7H9BO3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Related Products of 10365-98-7In 2021 ,《Magnetic Circularly Polarized Luminescence in the Photoexcited States of Racemic [n]Helicenes (n=3-5,7) in Tetrahydrofuran and Dimethyl Sulfoxide Solutions》 appeared in ChemPhysChem. The author of the article were Toda, Hayato; Otake, Shuhei; Ito, Akari; Miyasaka, Makoto; Fujiki, Michiya; Imai, Yoshitane. The article conveys some information:

This paper reports the first magnetic circularly polarized luminescence (MCPL) characteristics of racemic helicenes, including four unsubstituted [n]helicenes (n=3,4,5,7) and two [4]helicene derivatives bearing methoxy substituents, in THF (THF) and DMSO (DMSO) solutions The value of |gMCPL| was calculated to be of the order of 10-3 T-1 within 350-430 nm under the north-up (N-up) and south-up (S-up) Faraday geometries in an external magnetic field of 1.6 T. The [n]-dependent MCPL signs were altered by the N-up and S-up geometries. In the experiment, the researchers used 3-Methoxyphenylboronic acid(cas: 10365-98-7Related Products of 10365-98-7)

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Related Products of 10365-98-7

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

《Leveraging the Hydroarylation of α-(Trifluoromethyl)styrenes to Access Trifluoromethylated All-Carbon Quaternary Centers》 was written by Vayer, Marie; Mayer, Robert J.; Moran, Joseph; Lebœuf, David. Recommanded Product: 10365-98-7This research focused ontrifluorodiarylalkane regioselective preparation mechanism; styrene trifluoromethyl arene hydroarylation triflic acid hexafluoroisopropanol. The article conveys some information:

α-(Trifuoromethyl)styrenes are attractive olefin building blocks that have eluded hydroarylation processes. Here, the authors demonstrate that the use of a promoter system featuring triflic acid and hexafluoroisopropanol enables hydroarylation to directly build trifluoromethylated all-carbon quaternary centers. The observed reactivity significantly enriches the scope of hydroarylation of inactivated styrenes, e.g., 1-(trifluoromethyl)styrene, and provides straightforward access to trifluoromethylated diarylalkanes of interest, e.g., 1-methoxy-4-(1,1,1-trifluoro-2-phenylpropan-2-yl)benzene. Gram-scale reactions and further functionalizations illustrate the synthetic potential of this approach. In the experiment, the researchers used 3-Methoxyphenylboronic acid(cas: 10365-98-7Recommanded Product: 10365-98-7)

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Recommanded Product: 10365-98-7

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

《Suzuki-Miyaura Cross-Coupling of Sulfoxides》 was published in ACS Catalysis in 2020. These research results belong to Chen, Qianwei; Wu, Shufeng; Yan, Shuqin; Li, Chengxi; Abduhulam, Hayrul; Shi, Yanhui; Dang, Yanfeng; Cao, Changsheng. Application of 10365-98-7 The article mentions the following:

The utilization of di-Ph sulfoxides as versatile electrophilic coupling partners for the Suzuki-Miyaura reaction via C-S bond cleavage was successfully developed under palladium-N-heterocyclic carbene catalysis. The reactions showed good functional group compatibility, proceeded well under mild conditions, and provided biaryls in yields of up to 96%. A wide range of useful functional groups, such as fluoro, chloro, ether, hydroxyl, amide, cyano, keto, TMS and ester were tolerated under the reaction conditions, however the use of phenylboronic anhydride and arylboronic acid pinacol esters generally would lead low yields. Good regioselectivity for the electron-poor Ph group was achieved when unsym. di-Ph sulfoxides were used. The protocol is applicable at the gram scale even with half the amount of catalyst. D. functional theory calculations were performed to investigate the reaction mechanism, indicating that the reaction occurred through oxidative addition, transmetalation, and reductive elimination to provide the final coupling product. The results came from multiple reactions, including the reaction of 3-Methoxyphenylboronic acid(cas: 10365-98-7Application of 10365-98-7)

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Application of 10365-98-7

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Music, Arif; Nuber, Constantin M.; Lemke, Yannick; Spiess, Philipp; Didier, Dorian published their research in Organic Letters in 2021. The article was titled 《Electro-alkynylation: Intramolecular Rearrangement of Trialkynylorganoborates for Chemoselective C(sp2)-C(sp) Bond Formation》.Quality Control of 3-Methoxyphenylboronic acid The article contains the following contents:

An alternative and complementary transformation for the synthesis of aryl- and heteroaryl-substituted alkynes RCCR1 (R = 4-methylphenyl, 2-(4-fluorophenyl)ethenyl, 1-benzyl-1H-pyrazol-4-yl, etc.; R1 = t-Bu, 2-phenylethyl, 4-methoxyphenyl, etc.) is presented that relies on a chemoselective electrocoupling process. Tetraorganoborate substrates were logically designed and simply accessed by transmetalations using readily or com. available organotrifluoroborate salts RBF3K. In addition to this study using 3-Methoxyphenylboronic acid, there are many other studies that have used 3-Methoxyphenylboronic acid(cas: 10365-98-7Quality Control of 3-Methoxyphenylboronic acid) was used in this study.

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Quality Control of 3-Methoxyphenylboronic acid

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem

Kim, Daeun; Choi, Geunho; Kim, Weonjeong; Kim, Dongwook; Kang, Youn K.; Hong, Soon Hyeok published their research in Chemical Science in 2021. The article was titled 《The site-selectivity and mechanism of Pd-catalyzed C(sp2)-H arylation of simple arenes with aryl bromides.》.COA of Formula: C7H9BO3 The article contains the following contents:

Herein, comprehensively investigated the scope, site-selectivity and mechanism of the Pd-catalyzed direct C-H arylation reaction of simple arenes with aryl bromides. Counterintuitively, electron-rich arenes preferably proceeded through meta-arylation without an need for a specifically designed directing group, where as electron-deficient arenes bearing fluoro or cyano groups exhibited high ortho-selectivity and electron-deficient arenes bearing bulky electron-withdrawing groups favored the meta-product. Comprehensive mechanistic investigations through a combination of kinetic measurements and stoichiometric experiments using arylpalladium complexes were revealed that the Pd-based catalytic system works via a cooperative bimetallic mechanism, not the originally proposed monometallic CMD mechanism, regardless of the presence of a strongly coordinating L-type ligand. Notably, the transmetalation step, which was influenced by a potassium cation were suggested as the selectivity-determining step. In the experiment, the researchers used 3-Methoxyphenylboronic acid(cas: 10365-98-7COA of Formula: C7H9BO3)

3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.COA of Formula: C7H9BO3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem