Extracurricular laboratory: Synthetic route of Benzyl ether

HPLC of Formula: C14H14O. About Benzyl ether, If you have any questions, you can contact Hatamie, S; Shih, PJ; Chen, BW; Wang, IJ; Young, TH; Yao, DJ or concate me.

Hatamie, S; Shih, PJ; Chen, BW; Wang, IJ; Young, TH; Yao, DJ in [Hatamie, Shadie; Wang, I-Jong] Natl Taiwan Univ, Coll Med, Taipei 10048, Taiwan; [Hatamie, Shadie; Shih, Po-Jen; Young, Tai-Horng] Natl Taiwan Univ, Dept Biomed Engn, Taipei 10617, Taiwan; [Chen, Bo-Wei; Yao, Da-Jeng] Natl Tsing Hua Univ, Inst Nanoengn & Microsyst, Hsinchu 30013, Taiwan published Synergic Effect of Novel WS2 Carriers Holding Spherical Cobalt Ferrite @cubic Fe3O4 (WS2/s-CoFe2O4@c-Fe3O4) Nanocomposites in Magnetic Resonance Imaging and Photothermal Therapy for Ocular Treatments and Investigation of Corneal Endothelial Cell Migration in 2020, Cited 62. HPLC of Formula: C14H14O. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

The design of novel materials to use simultaneously in an ocular system for driven therapeutics and wound healing is still challenging. Here, we produced nanocomposites of tungsten disulfide carriers with spherical cobalt ferrite nanoparticles (NPs) as core inside a cubic iron oxide NPs shell (WS2/s-CoFe2O4@c-Fe3O4). Transmission electron microscopy (TEM) confirmed that 10 nm s-CoFe2O4@c-Fe3O4 NPs were attached on the WS2 sheet surfaces. The cytotoxicity of the WS2 sheets and nanocomposites were evaluated on bovine cornea endothelial cells (BCECs) using 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assay for a duration of three days. The MTT assay results showed low toxicity of the WS2 sheets on BCECs by 67% cell viability at 100 mu g/mL in 24 h, while the nanocomposites show 50% cell viability in the same conditions. The magnetic resonance imaging (MRI) of nanocomposites revealed the excellent T-2-weighted imaging with an r(2) contrast of 108 mM(-1) S-1. The in vitro photothermal therapy based on WS2 sheets and WS2/s-CoFe2O4 @c-Fe3O4 nanocomposites using 808 nm laser showed that the maximum thermal energy dispatched in medium at different applied power densities (1200 mw, 1800, 2200, 2600 mW) was for 0.1 mg/mL of the sample solution. The migration assay of BCECs showed that the wound healing was approximately 20% slower for the cell exposed by nanocomposites compared with the control (no exposed BCECs). We believe that WS2/s-CoFe2O4@c-Fe3O4 nanocomposites have a synergic effect as photothermal therapy agents for eye diseases and could be a target in an ocular system using MRI.

HPLC of Formula: C14H14O. About Benzyl ether, If you have any questions, you can contact Hatamie, S; Shih, PJ; Chen, BW; Wang, IJ; Young, TH; Yao, DJ or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

New explortion of C14H14O

SDS of cas: 103-50-4. About Benzyl ether, If you have any questions, you can contact Campisi, S; Ferri, M; Chan-Thaw, CE; Trujillo, FJS; Motta, D; Tabanelli, T; Dimitratos, N; Villa, A or concate me.

SDS of cas: 103-50-4. I found the field of Chemistry; Science & Technology – Other Topics; Materials Science; Physics very interesting. Saw the article Metal-Support Cooperative Effects in Au/VPO for the Aerobic Oxidation of Benzyl Alcohol to Benzyl Benzoate published in 2019, Reprint Addresses Villa, A (corresponding author), Univ Milan, Dipartimento Chim, Via C Golgi 19, I-20133 Milan, Italy.; Dimitratos, N (corresponding author), ALMA MATER STUDIORUM Univ Bologna, Dipartimento Chim Ind & Mat, Viale Risorgimento 4, I-40136 Bologna, Italy.. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether.

This paper studies the cooperative effect of Au nanoparticles deposited on vanadyl pyrophosphate oxide (VPO) in the liquid phase oxidation of benzyl alcohol. VPO was prepared using the classical method by thermally treating VOHPO4 center dot 0.5H(2)O precursor in reacting atmosphere at 420 degrees C for a period of 72 h. Au nanoparticles were deposited by incipient wetness method. The catalysts were characterized by means of XRD, TEM, XPS and Raman. The bulk VPO catalyst contains vanadyl pyrophosphate phase ((VO)(2)P2O7), and a small amount of VOPO4. The catalytic system exhibits a high activity in the base-free liquid phase oxidation of alcohols compared to Au on activated carbon, classic catalyst used for this type of reaction. Au/VPO showed a high peculiar selectivity to benzyl benzoate (76%), an important product used in the pharmaceutical and perfume industries. This behavior might be ascribed to the presence of strong acid sites of VPO, as determined by liquid phase titration. Stability tests performed on Au/VPO showed a deactivation of 10% after the first run, but a constant conversion along the following five cycles. This phenomenon can be attributed to the increase of mean Au particle size (from 19.1 to 23.4 nm) after recycling tests as well as the partial leaching of Au and V in the reaction media. Moreover, XRD evidenced a modification in the VPO structure with the partial formation of VOHPO4 center dot 0.5H(2)O phase.

SDS of cas: 103-50-4. About Benzyl ether, If you have any questions, you can contact Campisi, S; Ferri, M; Chan-Thaw, CE; Trujillo, FJS; Motta, D; Tabanelli, T; Dimitratos, N; Villa, A or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Extended knowledge of 103-50-4

Application In Synthesis of Benzyl ether. About Benzyl ether, If you have any questions, you can contact Woiski, C; Dobslaw, D; Engesser, KH or concate me.

An article Isolation and characterization of 2-butoxyethanol degrading bacterial strains WOS:000529855200001 published article about NONIONIC DETERGENT DEGRADATION; FATTY ALCOHOL ETHOXYLATES; GLYCOL MONOBUTYL ETHER; POLYETHYLENE-GLYCOL; PSEUDOMONAS-PUTIDA; BUTOXYACETIC ACID; BUTYL ETHER; TETRAHYDROFURAN DEGRADATION; MOLECULAR CHARACTERIZATION; MICROBIAL-DEGRADATION in [Woiski, Christine; Dobslaw, Daniel; Engesser, Karl-Heinrich] Univ Stuttgart, Inst Sanit Engn Water Qual & Solid Waste Manageme, Dept Biol Waste Air Purificat, Bandtaele 2, D-70569 Stuttgart, Germany in 2020, Cited 100. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. Application In Synthesis of Benzyl ether

A total of 11 bacterial strains capable of completely degrading 2-butoxyethanol (2-BE) were isolated from forest soil, a biotrickling filter, a bioscrubber, and activated sludge, and identified by 16S rRNA gene sequence analysis. Eight of these strains belong to the genus Pseudomonas; the remaining three strains are Hydrogenophaga pseudoflava BOE3, Gordonia terrae BOE5, and Cupriavidus oxalaticus BOE300. In addition to 2-BE, all isolated strains were able to grow on 2-ethoxyethanol and 2-propoxyethanol, ethanol, n-hexanol, ethyl acetate, 2-butoxyacetic acid (2-BAA), glyoxylic acid, and n-butanol. Apart from the only gram-positive strain isolated, BOE5, none of the strains were able to grow on the nonpolar ethers diethyl ether, di-n-butyl ether, n-butyl vinyl ether, and dibenzyl ether, as well as on 1-butoxy-2-propanol. Strains H. pseudoflava BOE3 and two of the isolated pseudomonads, Pseudomonas putida BOE100 and P. vancouverensis BOE200, were studied in more detail. The maximum growth rates of strains BOE3, BOE100, and BOE200 at 30 degrees C were 0.204 h(-1) at 4 mM, 0.645 h(-1) at 5 mM, and 0.395 h(-1) at 6 mM 2-BE, respectively. 2-BAA, n-butanol, and butanoic acid were detected as potential metabolites during the degradation of 2-BE. These findings indicate that the degradation of 2-BE by the isolated gram-negative strains proceeds via oxidation to 2-BAA with subsequent cleavage of the ether bond yielding glyoxylate and n-butanol. Since Gordonia terrae BOE5 was the only strain able to degrade nonpolar ethers like diethyl ether, the degradation pathway of 2-BE may be different for this strain.

Application In Synthesis of Benzyl ether. About Benzyl ether, If you have any questions, you can contact Woiski, C; Dobslaw, D; Engesser, KH or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

The Best Chemistry compound:C14H14O

About Benzyl ether, If you have any questions, you can contact Manohar, A; Krishnamoorthi, C; Pavithra, C; Thota, N or concate me.. Safety of Benzyl ether

An article Magnetic Hyperthermia and Photocatalytic Properties of MnFe(2)O(4)Nanoparticles Synthesized by Solvothermal Reflux Method WOS:000574332800001 published article about SUPERPARAMAGNETIC NATURE; FERROELECTRIC PROPERTIES; MNFE2O4 NANOPARTICLES; TEMPERATURE; DESIGN in [Manohar, A.; Krishnamoorthi, C.] Vellore Inst Technol, Ctr Nanotechnol Res, Vellore 632014, Tamil Nadu, India; [Manohar, A.] Korea Univ, Dept Mat Sci & Engn, 145 Anam Ro, Seoul 02841, South Korea; [Pavithra, C.] Marudhar Kesari Jain Coll, Dept Phys, Vaniyambadi 635752, Tamil Nadu, India; [Thota, Narayana] Indian Inst Sci, Solid State & Struct Chem, Bengaluru 560012, India in 2021, Cited 44. Safety of Benzyl ether. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

Development of new superparamagnetic materials with narrow size distribution is crucial for biomedical and environmental applications. Hence, we report the synthesis of narrow size distributed single grain MnFe(2)O(4)nanoparticles of average particle size 9 nm by solvothermal reflux method. Synthesized compound crystallized in face centered cubic spinel structure and is confirmed by X-ray diffraction profiles. Transmission electron micrograph shows narrow size distributed particles with an average particle size of 9 nm and is equal to crystallite diameter estimated from Scherrer equation. The spinel crystal structure is further confirmed by electron diffraction profiles, Fourier transformed infrared spectrum, and Raman spectrum at room temperature. Magnetic properties of the sample show superparamagnetic nature at room temperature with moderate saturated magnetization of 56.4 emug(-1). Magnetic heating properties of nanoparticles dispersion show the attainment of hyperthermia temperature (43 degrees C) in a short span of time of 1.6 min for 2 mg/mL and 2.6 min for 1 mg/mL concentrations. Estimated specific heat generation rate or specific power absorption rate, from temporal temperature plots, is 145.78 Wg(-1)and is useful for magnetic hyperthermia application in cancer therapy. Photocatalysis properties of sample show 96% of rhodamine B dye degradation in little less than 6 h under UV light irradiation and are useful for photocatalytic applications in wastewater treatment in industries.

About Benzyl ether, If you have any questions, you can contact Manohar, A; Krishnamoorthi, C; Pavithra, C; Thota, N or concate me.. Safety of Benzyl ether

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Final Thoughts on Chemistry for C14H14O

COA of Formula: C14H14O. About Benzyl ether, If you have any questions, you can contact Nagendra, B; Cozzolino, A; Golla, M; Daniel, C; Rizzo, P; Guerra, G or concate me.

COA of Formula: C14H14O. Nagendra, B; Cozzolino, A; Golla, M; Daniel, C; Rizzo, P; Guerra, G in [Guerra, Gaetano] Univ Salerno, Dipartimento Chim & Biol, Via Giovanni Paolo II 132, I-84084 Fisciano, Italy; Univ Salerno, INSTM Res Unit, Via Giovanni Paolo II 132, I-84084 Fisciano, Italy published Guest induced transition from beta to alpha nanoporous crystalline forms of PPO in 2020, Cited 49. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

The stability of a and beta nanoporous-crystalline (NC) forms of Poly(2,6-dimethyl-1,4-phenylene) oxide (PPO), in the presence of guest molecules leading to crystallization in a and beta-form (alpha and beta-guests), is explored. Sorption of liquid guests at 30 degrees C and 60 degrees C is studied both for NC films and NC aerogels. WAXD and FTIR characterizations show that, for all considered conditions, NC alpha-phases after guest sorption/desorption remain unaltered. NC beta-phases, on the contrary, after alpha-guest sorption can be transformed in co-crystalline (CC) alpha-phases that after guest desorption are transformed in NC alpha-phases. All conducted experiments also show that possible planar orientations of NC films (c//or c perpendicular to orientations) remain essentially unaltered, after sorption of all considered guest molecules. The presently discovered beta ->alpha transition constitutes a route to obtain unoriented alpha-form films, which till now were not available by known preparation procedures.

COA of Formula: C14H14O. About Benzyl ether, If you have any questions, you can contact Nagendra, B; Cozzolino, A; Golla, M; Daniel, C; Rizzo, P; Guerra, G or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Simple exploration of C14H14O

Formula: C14H14O. About Benzyl ether, If you have any questions, you can contact Gambe, J; Jouin, J; Remondiere, F; Thomas, P; Masson, O or concate me.

Formula: C14H14O. Recently I am researching about SOLVOTHERMAL SYNTHESIS; SIZE DEPENDENCE; ZIRCONIA; TEMPERATURE; STABILIZATION; NANOCRYSTALS, Saw an article supported by the . Published in SPRINGER in NEW YORK ,Authors: Gambe, J; Jouin, J; Remondiere, F; Thomas, P; Masson, O. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether

This work deals with the synthesis of zirconium dioxide (ZrO2) nanoparticles (NPs) in different solvents and their structural characterization for better understanding the oxygen donor solvent/zirconium precursor/NPs structure relationships. By selecting solvents over their capacity to produce different crystalline states from alkalinized zirconium alkoxide, spherical nanoparticles with a size of about 1.3-3 nm and a narrow size distribution were elaborated using a nonaqueous solvothermal sol-gel route. Conventional X-ray diffraction (XRD) was used to determine the average structure and crystallite size of the nanoparticles. Well-crystallized and single-phased nanoparticles with average monoclinic and tetragonal structure were obtained with benzaldehyde and benzyl alcohol, respectively, and a much distorted structure was observed for the synthesis in anisole. The atomic pair distribution functions (PDF) of the samples were also analyzed to access the local structure of the nanoparticles. The PDF of the benzaldehyde-prepared sample is consistent with the monoclinic structure. However, the local structure of nanoparticles synthesized with benzyl alcohol does not fully conform to the tetragonal structure observed by XRD, but exhibits monoclinic-like distortions. Lastly, the anisole-prepared nanoparticles present large structural distortions at the medium range and monoclinic local structural features. The restructuring of this last sample was studied by post-treatments in different solvents and leads to the expression of the tetragonal polymorph. Moreover, it seems that the main structural features are obtained in the early stages of the nanoparticles’ formation.

Formula: C14H14O. About Benzyl ether, If you have any questions, you can contact Gambe, J; Jouin, J; Remondiere, F; Thomas, P; Masson, O or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Let`s talk about compound :103-50-4

Computed Properties of C14H14O. About Benzyl ether, If you have any questions, you can contact Staniuk, M; Rechberger, F; Tervoort, E; Niederberger, M or concate me.

Computed Properties of C14H14O. Staniuk, M; Rechberger, F; Tervoort, E; Niederberger, M in [Staniuk, Malwina; Rechberger, Felix; Tervoort, Elena; Niederberger, Markus] Swiss Fed Inst Technol, Dept Mat, Lab Multifunct Mat, Vladimir Prelog Weg 5, CH-8093 Zurich, Switzerland published Adapting the concepts of nonaqueous sol-gel chemistry to metals: synthesis and formation mechanism of palladium and palladium-copper nanoparticles in benzyl alcohol in 2020, Cited 58. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

Benzyl alcohol is a versatile reaction medium for the synthesis of different types of nanoparticles. Its ability to act as an oxygen source gave access to metal oxide nanoparticles, while its reducing properties can be harnessed for the preparation of metals. Here we report the synthesis of Pd and PdCu nanoparticles in benzyl alcohol supplemented by a detailed mechanistic study for both systems. To elucidate the chemical formation mechanism of the Pd nanoparticles, we performed in situ attenuated total reflection ultraviolet-visible (ATR-UV-vis) and Fourier transform infrared spectroscopy (ATR-FTIR), providing information on the organic as well as on the inorganic side of the reaction. Potential gaseous products were analyzed by in situ gas chromatography (GC) and mass spectrometry (MS). We observed the formation of benzaldehyde, toluene, and dibenzyl ether as the three main organic products. The formation of the PdCu alloy nanoparticles was studied by ex situ powder X-ray diffraction (PXRD). A time-resolved study of the synthesis at 100 degrees C indicated that initially three types of particles formed, composed of an alloy with high Pd content, an alloy with high content of copper, and palladium particles, and only later in the reaction course they transformed into an alloy with a Pd-to-Cu ratio close to 1. [GRAPHICS] .

Computed Properties of C14H14O. About Benzyl ether, If you have any questions, you can contact Staniuk, M; Rechberger, F; Tervoort, E; Niederberger, M or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Our Top Choice Compound:103-50-4

COA of Formula: C14H14O. About Benzyl ether, If you have any questions, you can contact Kim, MA; Kim, YH; Chun, J; Lee, HS; Park, SJ; Cheon, JH; Il Kim, T; Kim, WH; Park, JJ or concate me.

COA of Formula: C14H14O. In 2021 J CROHNS COLITIS published article about CROHNS-DISEASE; BIRTH OUTCOMES; ULCERATIVE-COLITIS; PRETERM BIRTH; ALPHA; RISK; EXPRESSION; MANAGEMENT; FERTILITY; RECEPTORS in [Kim, Min-A] Yonsei Univ, Gangnam Severance Hosp, Inst Womens Life Med Sci, Dept Obstet & Gynecol,Coll Med, Seoul, South Korea; [Kim, Young-Han] Yonsei Univ, Severance Hosp, Inst Womens Life Med Sci, Dept Obstet & Gynecol,Coll Med, Seoul, South Korea; [Chun, Jaeyoung] Yonsei Univ, Gangnam Severance Hosp, Dept Internal Med, Coll Med, Seoul, South Korea; [Lee, Hye Sun] Yonsei Univ, Biostat Collaborat Unit, Coll Med, Seoul, South Korea; [Park, Soo Jung; Cheon, Jae Hee; Il Kim, Tae; Kim, Won Ho; Park, Jae Jun] Yonsei Univ, Severance Hosp, Dept Internal Med, Coll Med, Seoul, South Korea in 2021, Cited 65. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

Background and Aims: Robust evidence regarding the impact of disease activity on pregnancy outcomes in women with inflammatory bowel disease [IBD] is crucial for both clinicians and patients in preparing a birth plan. We sought to perform a systematic review and meta-analysis to assess the pooled influences of disease activity on pregnancy outcomes in women with IBD. Methods: We searched MEDLINE, EMBASE and the COCHRANE library to identify articles comparing pregnancy outcomes between active and inactive IBD at the time of conception or during pregnancy. A meta-analysis was performed using a random-effects model to pool estimates and report odds ratios [ORs]. Results: A total of 28 studies were identified as eligible for the meta-analysis. In women with active IBD, the pooled ORs for low birth weight [LBW], preterm birth, small for gestational age [SGA], spontaneous abortion and stillbirths were respectively 3.81 (95% confidence interval [CI] 1.81-8.02), 2.42 [95% CI 1.74-3.35], 1.48 [95% CI 1.19-1.85], 1.87 [95% CI 1.17-3.0] and 2.27 [95% CI 1.03-5.04] compared to women with inactive IBD. In the subgroup analysis based on disease type, women with active ulcerative colitis had an increased risk of LBW, preterm birth and spontaneous abortion. Women with active Crohn’s disease had a higher risk of preterm birth, SGA and spontaneous abortion. Conclusions: Active IBD during the periconception period and pregnancy is associated with an increased risk of adverse pregnancy outcomes. Our data suggest that pregnancy should be planned when the disease is quiescent, and continuous disease control is important even during pregnancy.

COA of Formula: C14H14O. About Benzyl ether, If you have any questions, you can contact Kim, MA; Kim, YH; Chun, J; Lee, HS; Park, SJ; Cheon, JH; Il Kim, T; Kim, WH; Park, JJ or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Extracurricular laboratory: Synthetic route of C14H14O

About Benzyl ether, If you have any questions, you can contact Yu, J; Nap, RJ; Szleifer, I; Wong, JY or concate me.. Computed Properties of C14H14O

In 2019 LANGMUIR published article about SULFONATED COPOLYMERS; SIZE; TEMPERATURES; STABILITY; BRINE in [Yu, Jin; Wong, Joyce Y.] Boston Univ, Div Mat Sci & Engn, Boston, MA 02215 USA; [Nap, Rikkert J.; Szleifer, Igal] Northwestern Univ, Dept Biomed Engn, Evanston, IL 60208 USA; [Nap, Rikkert J.; Szleifer, Igal] Northwestern Univ, Chem Life Proc Inst, Evanston, IL 60208 USA; [Wong, Joyce Y.] Boston Univ, Dept Biomed Engn, Boston, MA 02215 USA in 2019, Cited 23. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. Computed Properties of C14H14O

Superparamagnetic nanoparticles (SPIONs) can be used as nuclear magnetic resonance (NMR) signal enhancement agents for petroleum exploration. This enhancement effect is uniform if SPIONs are monodisperse in size and in composition; yet it is challenging to synthesize mono disperse particles that do not aggregate in high salinity petroleum brine. Here, we report a method to synthesize individual SPIONs coated with tunable surface coating densities of poly(2-acrylamido-2-methyl-1-propanesulfonic acid (pAMPS) with a catechol end-group (pAMPS*). To establish parameters under which pAMPS*-coated SPIONS do not aggregate, we compared computational predictions with experimental results for variations in pAMPS* chain length and surface coverage. Using this combined theoretical and experimental approach, we show that singly dispersed SPIONs remained stabilized in petroleum brine for up to 75 h with high surface density pAMPS*.

About Benzyl ether, If you have any questions, you can contact Yu, J; Nap, RJ; Szleifer, I; Wong, JY or concate me.. Computed Properties of C14H14O

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Chemical Research in Benzyl ether

Recommanded Product: 103-50-4. About Benzyl ether, If you have any questions, you can contact Xu, LJ; Yuan, YY; Han, Q; Dong, L; Chen, L; Zhang, XM; Xu, L or concate me.

Recently I am researching about MEDIUM-RANGE STRUCTURE; HYDROTHERMAL CONVERSION; NANOSIZED ZEOLITES; CATALYTIC-ACTIVITY; EXTERNAL SURFACE; BETA; NANOZEOLITES; MECHANISM; EFFICIENT; INSIGHT, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21902154]. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Xu, LJ; Yuan, YY; Han, Q; Dong, L; Chen, L; Zhang, XM; Xu, L. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether. Recommanded Product: 103-50-4

A novel interzeolite transformation strategy using internally confined organic structure directing agents (OSDAs), called the OSDA-confined strategy, is proposed for highly crystalline nanosized high-silica ZSM-5 zeolite synthesis, by which high yield and fast synthesis of ZSM-5 is achieved using BEA zeolite as a raw material. The transformation process was investigated by XRD, SEM, ICP, FTIR and UV Raman spectroscopy, which revealed that the decomposition of a parent zeolite and the crystallization process of products were well modulated by the confined OSDA. The transformation process could be divided into three stages consisting of raw material deconstruction, small size product formation and product growth. The strong etching power of NaOH contributes to the fast decomposition of BEA zeolites. In addition, tetrapropylammonium hydroxide (TPAOH) as an OSDA was confined in the parent zeolite instead of being added into the mother liquid, achieving a high local concentration of TPAOH, which could reduce the decomposition rate of the parent BEA zeolite and promote the efficient organization of the building units generated by the decomposition of the BEA zeolite. Thereof, a high yield was achieved by the synergistic effect of NaOH and occluded TPAOH. During the interzeolite transformation process, the six-membered rings (6Rs), five-membered rings (5Rs) and four-membered rings (4Rs) in the BEA zeolite framework were disassembled and combined with the help of 5Rs to produce the ZSM-5 zeolite structure. Moreover, due to the nanoscale and large surface area, the obtained ZSM-5 zeolite catalyst showed extremely high catalytic activity in the self-etherification reaction of benzyl alcohol (BA) to dibenzyl ether (DE). This study provides insights into the interzeolite transformation process, which would be helpful for achieving size control and high-efficiency synthesis.

Recommanded Product: 103-50-4. About Benzyl ether, If you have any questions, you can contact Xu, LJ; Yuan, YY; Han, Q; Dong, L; Chen, L; Zhang, XM; Xu, L or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem