Category: 103-50-4

Category: ethers-buliding-blocks. Si, XG; Zhao, YP; Song, QL; Cao, JP; Wang, RY; Wei, XY in [Si, Xing-Gang; Zhao, Yun-Peng; Song, Qing-Lu; Cao, Jing-Pei; Wei, Xian-Yong] China Univ Min & Technol, Minist Educ, Key Lab Coal Proc & Efficient Utilizat, Xuzhou 221114, Jiangsu, Peoples R China; [Zhao, Yun-Peng] Taiyuan Univ Technol, State Key Lab Breeding Base Coal Sci & Technol Co, Taiyuan 030024, Peoples R China; [Zhao, Yun-Peng] Taiyuan Univ Technol, Minist Sci & Technol, Taiyuan 030024, Peoples R China; [Wang, Rui-Yu] China Univ Min & Technol, Low Carbon Energy Inst, Xuzhou 221008, Jiangsu, Peoples R China published Hydrogenolysis of lignin-derived aryl ethers to monomers over a MOF-derived Ni/N-C catalyst in 2020, Cited 43. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

A highly efficient Ni/N-C catalyst was synthesized by facile pyrolysis of a Ni-containing metal-organic framework (Ni-MOF), and its catalytic hydrogenolysis performance towards C-O bonds in lignin was evaluated in detail using diphenyl ether (DPE) as a model compound. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) analyses show that the flower-like nanosheets of the Ni-MOF shrink, forming a loose and ordered spherical structure during pyrolysis. Under the optimal conditions, DPE was completely converted and the selectivity to monomers (benzene, cyclohexanol and cyclohexane) reached 99.1%. During the catalytic hydrogenolysis conversion (CHC) of DPE, the direct cleavage of the C-aromatic-O bond affording benzene and phenol is the major reaction pathway, and a low H2 pressure is crucial to increase the monomer selectivity. Furthermore, Ni/N-C-450 shows high hydrogenolysis activity for other lignin-derived aryl ethers, such as benzyl phenyl ether, dibenzyl ether, dinaphthalene ether, benzyl 2-naphthyl ether and 3-methoxyphenol.

Category: ethers-buliding-blocks. About Benzyl ether, If you have any questions, you can contact Si, XG; Zhao, YP; Song, QL; Cao, JP; Wang, RY; Wei, XY or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

I found the field of Science & Technology – Other Topics; Materials Science very interesting. Saw the article Inorganic Porous Bulk Discs as a Matrix for Thin-Layer Chromatography and Translucent Hard Composite Materials published in 2020. Formula: C14H14O, Reprint Addresses Sturm, EV; Colfen, H (corresponding author), Univ Konstanz, Dept Chem, Phys Chem, Univ Str 10, D-78457 Constance, Germany.. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether

Magnesium-stabilized amorphous calcium carbonate (Mg-ACC), amorphous magnesium calcium silicate hydrate (MCSH), and hydroxyapatite (HAp) are prepared by a precipitation method. By cold-pressing these particles, it is possible to produce porous bulk discs with a narrow pore size distribution. These porous inorganic discs (Mg-ACC, MCSH, and HAp) are investigated as stationary phases to study the chromatographic behavior and adsorption ability of rhodamine B, methylene blue, and ribonuclease. The adsorption affinities of different biomolecules can be easily observed and evaluated through this method. Furthermore, by infiltrating fabricated opaque porous discs with benzyl ether, which has a similar refractive index as the used inorganic particles (Mg-ACC, MCSH, and HAp), their optical properties significantly change and the discs become translucent. Moreover, by infiltrating the MCSH discs with a light-curing polymer, translucent composites with good surface hardness are fabricated. By doping particles with ions such as Ni2+, Co2+ , Fe3+, and Eu3+, the color and UV-visible spectrum of the bulk discs can be adjusted. Typically, by using iron-doped MCSH particles as the inorganic matrix, nanocomposites, which show a steep UV-absorption edge at 400 nm, are fabricated. Our work provides a simple and economical method to evaluate the affinity of biomolecules to inorganic materials and a novel way to fabricate translucent hard composite materials. The fabricated nanocomposite discs show a great UV shielding effect and superior surface hardness compared to polymethyl methacrylate and commercial sunglasses, suggesting their potential as new sunglass materials.

Formula: C14H14O. About Benzyl ether, If you have any questions, you can contact Chen, S; Knaus, J; Luo, J; Spinnrock, A; Sturm, EV; Colfen, H or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

In 2019 ACS SUSTAIN CHEM ENG published article about LIGNOCELLULOSE FRACTIONATION; REDUCTIVE FRACTIONATION; PHENOLIC MONOMERS; WOODY BIOMASS; DEPOLYMERIZATION; EFFICIENT; CHEMICALS; CONVERSION; NICKEL; HYDROGENATION in [Zhao, Weijie; Li, Xuan; Li, Haowei; Zheng, Xinlai; Ma, Hongwei; Long, Jinxing; Li, Xuehui] South China Univ Technol, Sch Chem & Chem Engn, State Key Lab Pulp & Paper Engn, Guangzhou 510640, Guangdong, Peoples R China in 2019, Cited 57. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. Name: Benzyl ether

Bulk chemicals produced from renewable resources are receiving considerable attention due to the increase in sustainable practices. In this study, a novel, efficient, and sustainable strategy has been proposed to produce versatile petroleum based monophenols from the natural aromatic polymer, lignin, via the selective cleavage of its specific chemical linkages by a cost-effective catalyst, Ni/MgO. The results demonstrate that 93.4% of lignin is converted, yielding 15.0% monophenols in the presence of 20% Ni/MgO. Importantly, 42.3% of these volatile chemicals are found to be 4-ethyl phenol (the yield is 6.31%), a widely used fine chemical currently obtained from the petrochemical industry. Further comparative investigations on the raw and recovered lignin using heteronuclear single quantum correlation-nuclear magnetic resonance (HSQC-NMR), Fourier transform infrared (FT-IR), quantitative C-13 NMR, and the alkaline nitrobenzene oxidation method reveal that the selective breakage of the ester bond between the p-hydroxyphenyl structural unit and the other fragments followed by decarboxylation is responsible for the good performance of the 4-ethyl phenol formation process. Therefore, the results of this work would provide new insights for producing value-added petrochemicals from renewable lignin.

About Benzyl ether, If you have any questions, you can contact Zhao, WJ; Li, X; Li, HW; Zheng, XL; Ma, HW; Long, JX; Li, XH or concate me.. Name: Benzyl ether

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

I found the field of Chemistry; Science & Technology – Other Topics; Materials Science; Physics very interesting. Saw the article Hadron Therapy, Magnetic Nanoparticles and Hyperthermia: A Promising Combined Tool for Pancreatic Cancer Treatment published in 2020. Computed Properties of C14H14O, Reprint Addresses Brero, F; Lascialfari, A (corresponding author), Univ Pavia, Dipartimento Fis, I-27100 Pavia, Italy.; Brero, F; Lascialfari, A (corresponding author), Univ Pavia, Ist Nazl Fis Nucl, I-27100 Pavia, Italy.. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether

A combination of carbon ions/photons irradiation and hyperthermia as a novel therapeutic approach for the in-vitro treatment of pancreatic cancer BxPC3 cells is presented. The radiation doses used are 0-2 Gy for carbon ions and 0-7 Gy for 6 MV photons. Hyperthermia is realized via a standard heating bath, assisted by magnetic fluid hyperthermia (MFH) that utilizes magnetic nanoparticles (MNPs) exposed to an alternating magnetic field of amplitude 19.5 mTesla and frequency 109.8 kHz. Starting from 37 degrees C, the temperature is gradually increased and the sample is kept at 42 degrees C for 30 min. For MFH, MNPs with a mean diameter of 19 nm and specific absorption rate of 110 +/- 30 W/g(Fe3)o(4) coated with a biocompatible ligand to ensure stability in physiological media are used. Irradiation diminishes the clonogenic survival at an extent that depends on the radiation type, and its decrease is amplified both by the MNPs cellular uptake and the hyperthermia protocol. Significant increases in DNA double-strand breaks at 6 h are observed in samples exposed to MNP uptake, treated with 0.75 Gy carbon-ion irradiation and hyperthermia. The proposed experimental protocol, based on the combination of hadron irradiation and hyperthermia, represents a first step towards an innovative clinical option for pancreatic cancer.

Computed Properties of C14H14O. About Benzyl ether, If you have any questions, you can contact Brero, F; Albino, M; Antoccia, A; Arosio, P; Avolio, M; Berardinelli, F; Bettega, D; Calzolari, P; Ciocca, M; Corti, M; Facoetti, A; Gallo, S; Groppi, F; Guerrini, A; Innocenti, C; Lenardi, C; Locarno, S; Manenti, S; Marchesini, R; Mariani, M; Orsini, F; Pignoli, E; Sangregorio, C; Veronese, I; Lascialfari, A or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Name: Benzyl ether. In 2020 CATALYSTS published article about EFFECTIVE CATALYST; CARBONYL-COMPOUNDS; BENZYLIC ALCOHOLS; BROMOSUCCINIMIDE; ALKYLATION; STRATEGY; NBS in [Ajvazi, Njomza; Stavber, Stojan] Jozef Stefan Int Postgrad Sch, Jamova 39, Ljubljana 1000, Slovenia; [Stavber, Stojan] Jozef Stefan Inst, Jamova 39, Ljubljana 1000, Slovenia in 2020, Cited 42. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

N-halosuccinimides (chloro, bromo, and iodo, respectively) were introduced, tested, and applied as efficient and non-metal precatalysts for C-, N-, O-, and X-nucleophilic substitution reactions of alcohols under solvent-free reaction conditions (SFRC) or under high substrate concentration reaction conditions (HCRC) efficiently and selectively, into the corresponding products.

About Benzyl ether, If you have any questions, you can contact Ajvazi, N; Stavber, S or concate me.. Name: Benzyl ether

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Authors Zakhtser, A; Naitabdi, A; Benbalagh, R; Rochet, F; Salzemann, C; Petit, C; Giorgio, S in AMER CHEMICAL SOC published article about in [Zakhtser, Alter; Naitabdi, Ahmed; Benbalagh, Rabah; Rochet, Francois; Salzemann, Caroline; Petit, Christophe] Sorbonne Univ, F-75005 Paris, France; [Giorgio, Suzanne] Aix Marseille Univ, F-13288 Marseille, France in 2021, Cited 65. Recommanded Product: 103-50-4. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

We report on the shape, composition (from Pt95Zn5 to Pt77Zn23), and surface chemistry of Pt-Zn nanoparticles obtained by reduction of precursors M2+(acac) (-)(2) (M2+: Pt2+ and Zn2+) in oleylamine, which serves as both solvent and ligand. We show first that the addition of phenyl ether or benzyl ether determines the composition and shape of the nanoparticles, which point to an adsorbate-controlled synthesis. The organic (ligand)/inorganic (nanoparticles) interface is characterized on the structural and chemical level. We observe that the particles, after washing with ethanol, are coated with oleylamine and the oxidation products of the latter, namely, an aldimine and a nitrile. After exposure to air, the particles oxidize, covering themselves with a few monolayer thick ZnO film, which is certainly discontinuous when the particles are low in zinc. Pt-Zn particles are unstable and prone to losing Zn. We have strong indications that the driving force is the preferential oxidation of the less noble metal. Finally, we show that adsorption of CO on the surface of nanoparticles modifies the oxidation state of amine ligands and attribute it to the displacement of hydrogen adsorbed on Pt. All the structural and chemical information provided by the combination of electron microscopy and X-ray photoelectron spectroscopy allows us to give a fairly accurate picture of the surface of nanoparticles and to better understand why Pt-Zn alloys are efficient in certain electrocatalytic reactions such as the oxidation of methanol.

Recommanded Product: 103-50-4. About Benzyl ether, If you have any questions, you can contact Zakhtser, A; Naitabdi, A; Benbalagh, R; Rochet, F; Salzemann, C; Petit, C; Giorgio, S or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

HPLC of Formula: C14H14O. I found the field of Chemistry; Science & Technology – Other Topics; Materials Science; Physics very interesting. Saw the article Hadron Therapy, Magnetic Nanoparticles and Hyperthermia: A Promising Combined Tool for Pancreatic Cancer Treatment published in 2020, Reprint Addresses Brero, F; Lascialfari, A (corresponding author), Univ Pavia, Dipartimento Fis, I-27100 Pavia, Italy.; Brero, F; Lascialfari, A (corresponding author), Univ Pavia, Ist Nazl Fis Nucl, I-27100 Pavia, Italy.. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether.

A combination of carbon ions/photons irradiation and hyperthermia as a novel therapeutic approach for the in-vitro treatment of pancreatic cancer BxPC3 cells is presented. The radiation doses used are 0-2 Gy for carbon ions and 0-7 Gy for 6 MV photons. Hyperthermia is realized via a standard heating bath, assisted by magnetic fluid hyperthermia (MFH) that utilizes magnetic nanoparticles (MNPs) exposed to an alternating magnetic field of amplitude 19.5 mTesla and frequency 109.8 kHz. Starting from 37 degrees C, the temperature is gradually increased and the sample is kept at 42 degrees C for 30 min. For MFH, MNPs with a mean diameter of 19 nm and specific absorption rate of 110 +/- 30 W/g(Fe3)o(4) coated with a biocompatible ligand to ensure stability in physiological media are used. Irradiation diminishes the clonogenic survival at an extent that depends on the radiation type, and its decrease is amplified both by the MNPs cellular uptake and the hyperthermia protocol. Significant increases in DNA double-strand breaks at 6 h are observed in samples exposed to MNP uptake, treated with 0.75 Gy carbon-ion irradiation and hyperthermia. The proposed experimental protocol, based on the combination of hadron irradiation and hyperthermia, represents a first step towards an innovative clinical option for pancreatic cancer.

About Benzyl ether, If you have any questions, you can contact Brero, F; Albino, M; Antoccia, A; Arosio, P; Avolio, M; Berardinelli, F; Bettega, D; Calzolari, P; Ciocca, M; Corti, M; Facoetti, A; Gallo, S; Groppi, F; Guerrini, A; Innocenti, C; Lenardi, C; Locarno, S; Manenti, S; Marchesini, R; Mariani, M; Orsini, F; Pignoli, E; Sangregorio, C; Veronese, I; Lascialfari, A or concate me.. HPLC of Formula: C14H14O

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Nagendra, B; Rizzo, P; Daniel, C; Guerra, G in [Nagendra, Baku; Rizzo, Paola; Daniel, Christophe; Guerra, Gaetano] Univ Salerno, Dipartimento Chim & Biol, INSTM Res Unit, I-84084 Fisciano, SA, Italy published Planar Orientation and Transparency of Nanoporous-Crystalline Polymer Films in 2021, Cited 51. Application In Synthesis of Benzyl ether. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

The dependence of polymer film transparency on different kinds of planar orientations of nanoporous-crystalline (NC) phases of syndiotactic polystyrene (sPS) and poly(2,6-dimethyl-1,4-phenylene)oxide (PPO) is described. The two polymers exhibit opposite behavior: film transparency is improved for sPS and PPO by orientations of the chain axes of the NC phases being parallel (c(parallel to)) and perpendicular (c(perpendicular to)) to the film plane, respectively. This behavior can be rationalized by the negative and positive birefringence of sPS and PPO chains, respectively. In fact, to maximize transparency, the refractive index of the NC phase along the perpendicular to the film plane has to be increased to come closer to that of the corresponding amorphous phase. This can be pursued by controlling the orientation of the NC phases and hence of the associated refractive index ellipsoids.

Application In Synthesis of Benzyl ether. About Benzyl ether, If you have any questions, you can contact Nagendra, B; Rizzo, P; Daniel, C; Guerra, G or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

HPLC of Formula: C14H14O. In 2019 SCI ADV published article about SINGLE-CELL RESOLUTION; GREEN FLUORESCENT PROTEIN; TISSUE; BODY; DENATURATION; NETWORKS; VOLUME; SIZE; GFP in [Qi, Yisong; Yu, Tingting; Xu, Jianyi; Wan, Peng; Ma, Yilin; Zhu, Jingtan; Li, Yusha; Gong, Hui; Luo, Qingming; Zhu, Dan] Huazhong Univ Sci & Technol, Wuhan Natl Lab Optoelect, Britton Chance Ctr Biomed Photon, Wuhan, Hubei, Peoples R China; [Qi, Yisong; Yu, Tingting; Xu, Jianyi; Wan, Peng; Ma, Yilin; Zhu, Jingtan; Li, Yusha; Gong, Hui; Luo, Qingming; Zhu, Dan] Huazhong Univ Sci & Technol, Sch Engn Sci, Collaborat Innovat Ctr Biomed Engn, MoE,Key Lab Biomed Photon, Wuhan, Hubei, Peoples R China in 2019, Cited 48. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

Various optical clearing methods have emerged as powerful tools for deep biological imaging. Organic solvent-based clearing methods, such as three-dimensional imaging of solvent-cleared organs (3DISCO), present the advantages of high clearing efficiency and size reduction for panoptic imaging of large samples such as whole organs and even whole bodies. However, 3DISCO results in a rapid quenching of endogenous fluorescence, which has impeded its application. Here, we propose an advanced method named FDISCO to overcome this limitation. FDISCO can effectively preserve the fluorescence of various fluorescent probes and can achieve a long storage time of months while retaining potent clearing capability. We used FDISCO for high-resolution imaging and reconstruction of neuronal and vascular networks. Moreover, FDISCO is compatible with labeling by multiple viruses and enables fine visualization of neurons with weak fluorescence labeling in the whole brain. FDISCO represents an effective alternative to the three-dimensional mapping of whole organs and can be extensively used in biomedical studies.

About Benzyl ether, If you have any questions, you can contact Qi, YS; Yu, TT; Xu, JY; Wan, P; Ma, YL; Zhu, JT; Li, YS; Gong, H; Luo, QM; Zhu, D or concate me.. HPLC of Formula: C14H14O

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Formula: C14H14O. Authors Zakhtser, A; Naitabdi, A; Benbalagh, R; Rochet, F; Salzemann, C; Petit, C; Giorgio, S in AMER CHEMICAL SOC published article about in [Zakhtser, Alter; Naitabdi, Ahmed; Benbalagh, Rabah; Rochet, Francois; Salzemann, Caroline; Petit, Christophe] Sorbonne Univ, F-75005 Paris, France; [Giorgio, Suzanne] Aix Marseille Univ, F-13288 Marseille, France in 2021, Cited 65. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

We report on the shape, composition (from Pt95Zn5 to Pt77Zn23), and surface chemistry of Pt-Zn nanoparticles obtained by reduction of precursors M2+(acac) (-)(2) (M2+: Pt2+ and Zn2+) in oleylamine, which serves as both solvent and ligand. We show first that the addition of phenyl ether or benzyl ether determines the composition and shape of the nanoparticles, which point to an adsorbate-controlled synthesis. The organic (ligand)/inorganic (nanoparticles) interface is characterized on the structural and chemical level. We observe that the particles, after washing with ethanol, are coated with oleylamine and the oxidation products of the latter, namely, an aldimine and a nitrile. After exposure to air, the particles oxidize, covering themselves with a few monolayer thick ZnO film, which is certainly discontinuous when the particles are low in zinc. Pt-Zn particles are unstable and prone to losing Zn. We have strong indications that the driving force is the preferential oxidation of the less noble metal. Finally, we show that adsorption of CO on the surface of nanoparticles modifies the oxidation state of amine ligands and attribute it to the displacement of hydrogen adsorbed on Pt. All the structural and chemical information provided by the combination of electron microscopy and X-ray photoelectron spectroscopy allows us to give a fairly accurate picture of the surface of nanoparticles and to better understand why Pt-Zn alloys are efficient in certain electrocatalytic reactions such as the oxidation of methanol.

About Benzyl ether, If you have any questions, you can contact Zakhtser, A; Naitabdi, A; Benbalagh, R; Rochet, F; Salzemann, C; Petit, C; Giorgio, S or concate me.. Formula: C14H14O

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem