Category: 103-50-4

Formula: C14H14O. In 2021 CHEM PAP published article about COMMERCIAL ZINC-OXIDE; ONE-POT SYNTHESIS; ACYLATIVE CLEAVAGE; ACID-CHLORIDES; ACYCLIC ETHERS; CYCLIC ETHERS; EFFICIENT; HALIDES; 2-AMINOTHIOPHENES; MILD in [Tang, Yuqi; Yang, Wanfeng; Wang, Wei; Chen, Junqing] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Jiangsu, Peoples R China; [Feng, Chengliang] Jiangsu Coll Engn & Technol, Inst Pharmaceut Engn, Nantong 226000, Jiangsu, Peoples R China; [Ji, Min] Southeast Univ, Sch Biol Sci & Med Engn, Nanjing 211189, Jiangsu, Peoples R China in 2021, Cited 31. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

An efficient method for the synthesis of chloroesters by the reaction of ethers with acyl chlorides catalyzed by nano-ZnO under solvent-free condition at room temperature was described. The method is compatible with a range of ethers including tricyclic ethers, tetracyclic ethers, pentacyclic ethers and hexacyclic ethers and have afforded the products with moderate to good yields. The ZnO could be reused up to three times and the product yield after three cycles is 87%.

Formula: C14H14O. About Benzyl ether, If you have any questions, you can contact Tang, YQ; Feng, CL; Yang, WF; Ji, M; Wang, W; Chen, JQ or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Category: ethers-buliding-blocks. Recently I am researching about CATALYTIC PERFORMANCE; SPATIAL-DISTRIBUTION; ACID SITES; ALKYLATION; BEHAVIOR; POROSITY, Saw an article supported by the Science and Technology Program of Guangzhou, China [201804010172]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21576094, 21576221, 21276052]; Science and Technology Planning Project of Guangdong Province, China [2012A090300006]; National Key Technology RD ProgramNational Key Technology R&D Program [2015BAK45B01]. Published in ELSEVIER in AMSTERDAM ,Authors: Liu, BY; Chen, ZP; Huang, JJ; Chen, HY; Fang, YX. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether

The MFI zeolites with nanosheet assemblies morphology were prepared by a seed-assisted strategy using specially designed bolaform surfactant [C6H13-N+ (CH3)(2)-C6H12-N+ (CH3)(2)-(CH2)(12)-O-(p-C6H4)(2)-O-(CH2)(12)-N+(CH3)(2)-C6H12-N+(CH3)(2)-C6H13] [Br-](4) (C6-12-diphe) as a structure-directing agent. The MFI zeolite nanosheet assemblies were composed of MFI nanosheets with randomly organized structure, exhibiting a narrow mesopore distribution. By tuning the Si/AI ratios of MFI zeolite nanosheet assemblies from 60 to 10, the morphology of resultant zeolites changed from nanosheet stacks to house-of-cards-like structures, and to nanosponges. In addition, the porosity and Bronsted acid/Lewis acid ratio exhibited a parabola-type dependence on the Si/Al ratios of obtained zeolites, indicating that meso-/microporosity and acidity of MFI nanosheet assemblies can be systematically tailored by changing the constituents of zeolites. Catalytic performance of MFI zeolite nanosheet assemblies was investigated in the benzylation of benzyl alcohol with mesitylene. The results revealed that MFI zeolite nanosheet assemblies exhibited extraordinary catalytic activity compared to conventional ZSM-5 zeolite. The conversion of benzyl alcohol and selectivity (1,3,5-trimethyl-2-benzylbenzene vs dibenzyl ether) of zeolite catalysts were linearly dependent on the 81-misted acid/Lewis acid ratio, and they exhibited a parabola-type dependence on the S-ext/S-BET, indicating that a balance between acidity and porosity of zeolites can be realized to modulate the catalytic properties of MFI zeolite nanosheet assemblies guided by C6-12-diphe.

Category: ethers-buliding-blocks. About Benzyl ether, If you have any questions, you can contact Liu, BY; Chen, ZP; Huang, JJ; Chen, HY; Fang, YX or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Authors Parker, BF; Hosoya, H; Arnold, J; Tsurugi, H; Mashima, K in AMER CHEMICAL SOC published article about O-ACYLATIVE CLEAVAGE; BOND; ACTIVATION; CHLORIDE; LIGANDS; REAGENT; HALIDES in [Parker, Bernard F.; Hosoya, Hiromu; Tsurugi, Hayato; Mashima, Kazushi] Osaka Univ, Grad Sch Engn Sci, Dept Chem, Toyonaka, Osaka 5608531, Japan; [Parker, Bernard F.; Arnold, John] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA in 2019, Cited 34. SDS of cas: 103-50-4. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

alpha-Diimine niobium complexes serve as catalysts for deoxygenation of benzyl ethers by silicon tetrachloride (SiCl4) to cleanly give two equivalents of the corresponding benzyl chlorides, where SiCl4 has the dual function of oxygen scavenger and chloride source with the formation of a silyl ether or silica as the only byproduct. The reaction mechanism has two successive trans-etherification steps that are mediated by the niobium catalyst, first forming one equivalent of benzyl chloride along with the corresponding silyl ether intermediate that undergoes the same reaction pathway to give the second equivalent of benzyl chloride and silyl ether.

About Benzyl ether, If you have any questions, you can contact Parker, BF; Hosoya, H; Arnold, J; Tsurugi, H; Mashima, K or concate me.. SDS of cas: 103-50-4

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Authors Martinez-Ferrate, O; Chatterjee, B; Werle, C; Leitner, W in ROYAL SOC CHEMISTRY published article about ASYMMETRIC TRANSFER HYDROGENATION; METAL-COMPLEXES; ENANTIOSELECTIVE HYDROSILYLATION; SELECTIVE REDUCTION; MANGANESE COMPLEXES; IRON COMPLEXES; KETONES; ALDEHYDES; EFFICIENT; HYDROSILATION in [Martinez-Ferrate, Oriol; Chatterjee, Basujit; Werle, Christophe; Leitner, Walter] Max Planck Inst Chem Energy Convers, Stiftstr 34-36, D-45470 Mulheim, Germany; [Leitner, Walter] Rhein Westfal TH Aachen, ITMC, Worringer Weg 2, D-52074 Aachen, Germany in 2019, Cited 111. Quality Control of Benzyl ether. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

Manganese(i) complexes bearing triazole ligands are reported as catalysts for the hydrosilylation of carbonyl and carboxyl compounds. The desired reaction proceeds readily at 80 degrees C within 3 hours at catalyst loadings as low as 0.25 to 1 mol%. Hence, good to excellent yields of alcohols could be obtained for a wide range of substrates including ketones, esters, and carboxylic acids illustrating the versatility of the metal/ligand combination.

Quality Control of Benzyl ether. About Benzyl ether, If you have any questions, you can contact Martinez-Ferrate, O; Chatterjee, B; Werle, C; Leitner, W or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

Recently I am researching about PROTEIN ADSORPTION; HYDROXYAPATITE; NANOPARTICLES; BINDING; SILICA; SCIENCE; GROWTH; ACIDS, Saw an article supported by the . Recommanded Product: 103-50-4. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Chen, S; Knaus, J; Luo, J; Spinnrock, A; Sturm, EV; Colfen, H. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether

Magnesium-stabilized amorphous calcium carbonate (Mg-ACC), amorphous magnesium calcium silicate hydrate (MCSH), and hydroxyapatite (HAp) are prepared by a precipitation method. By cold-pressing these particles, it is possible to produce porous bulk discs with a narrow pore size distribution. These porous inorganic discs (Mg-ACC, MCSH, and HAp) are investigated as stationary phases to study the chromatographic behavior and adsorption ability of rhodamine B, methylene blue, and ribonuclease. The adsorption affinities of different biomolecules can be easily observed and evaluated through this method. Furthermore, by infiltrating fabricated opaque porous discs with benzyl ether, which has a similar refractive index as the used inorganic particles (Mg-ACC, MCSH, and HAp), their optical properties significantly change and the discs become translucent. Moreover, by infiltrating the MCSH discs with a light-curing polymer, translucent composites with good surface hardness are fabricated. By doping particles with ions such as Ni2+, Co2+ , Fe3+, and Eu3+, the color and UV-visible spectrum of the bulk discs can be adjusted. Typically, by using iron-doped MCSH particles as the inorganic matrix, nanocomposites, which show a steep UV-absorption edge at 400 nm, are fabricated. Our work provides a simple and economical method to evaluate the affinity of biomolecules to inorganic materials and a novel way to fabricate translucent hard composite materials. The fabricated nanocomposite discs show a great UV shielding effect and superior surface hardness compared to polymethyl methacrylate and commercial sunglasses, suggesting their potential as new sunglass materials.

About Benzyl ether, If you have any questions, you can contact Chen, S; Knaus, J; Luo, J; Spinnrock, A; Sturm, EV; Colfen, H or concate me.. Recommanded Product: 103-50-4

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

An article Synergic Effect of Novel WS2 Carriers Holding Spherical Cobalt Ferrite @cubic Fe3O4 (WS2/s-CoFe2O4@c-Fe3O4) Nanocomposites in Magnetic Resonance Imaging and Photothermal Therapy for Ocular Treatments and Investigation of Corneal Endothelial Cell Migration WOS:000602528700001 published article about HYPERTHERMIA THERAPY; NANOPARTICLES; GRAPHENE; NANOFLUIDS; NANOSHEETS; CURCUMIN; SHEETS; AGENT; MOS2 in [Hatamie, Shadie; Wang, I-Jong] Natl Taiwan Univ, Coll Med, Taipei 10048, Taiwan; [Hatamie, Shadie; Shih, Po-Jen; Young, Tai-Horng] Natl Taiwan Univ, Dept Biomed Engn, Taipei 10617, Taiwan; [Chen, Bo-Wei; Yao, Da-Jeng] Natl Tsing Hua Univ, Inst Nanoengn & Microsyst, Hsinchu 30013, Taiwan in 2020, Cited 62. Formula: C14H14O. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

The design of novel materials to use simultaneously in an ocular system for driven therapeutics and wound healing is still challenging. Here, we produced nanocomposites of tungsten disulfide carriers with spherical cobalt ferrite nanoparticles (NPs) as core inside a cubic iron oxide NPs shell (WS2/s-CoFe2O4@c-Fe3O4). Transmission electron microscopy (TEM) confirmed that 10 nm s-CoFe2O4@c-Fe3O4 NPs were attached on the WS2 sheet surfaces. The cytotoxicity of the WS2 sheets and nanocomposites were evaluated on bovine cornea endothelial cells (BCECs) using 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assay for a duration of three days. The MTT assay results showed low toxicity of the WS2 sheets on BCECs by 67% cell viability at 100 mu g/mL in 24 h, while the nanocomposites show 50% cell viability in the same conditions. The magnetic resonance imaging (MRI) of nanocomposites revealed the excellent T-2-weighted imaging with an r(2) contrast of 108 mM(-1) S-1. The in vitro photothermal therapy based on WS2 sheets and WS2/s-CoFe2O4 @c-Fe3O4 nanocomposites using 808 nm laser showed that the maximum thermal energy dispatched in medium at different applied power densities (1200 mw, 1800, 2200, 2600 mW) was for 0.1 mg/mL of the sample solution. The migration assay of BCECs showed that the wound healing was approximately 20% slower for the cell exposed by nanocomposites compared with the control (no exposed BCECs). We believe that WS2/s-CoFe2O4@c-Fe3O4 nanocomposites have a synergic effect as photothermal therapy agents for eye diseases and could be a target in an ocular system using MRI.

Formula: C14H14O. About Benzyl ether, If you have any questions, you can contact Hatamie, S; Shih, PJ; Chen, BW; Wang, IJ; Young, TH; Yao, DJ or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

An article Direct synthesis of hierarchically structured MFI zeolite nanosheet assemblies with tailored activity in benzylation reaction WOS:000448091200028 published article about CATALYTIC PERFORMANCE; SPATIAL-DISTRIBUTION; ACID SITES; ALKYLATION; BEHAVIOR; POROSITY in [Liu, Baoyu; Chen, Zhipeng; Huang, Jiajin; Fang, Yanxiong] Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Guangdong, Peoples R China; [Chen, Huiyong] Northwest Univ, Sch Chem Engn, Xian 710069, Shaanxi, Peoples R China in 2019, Cited 42. Safety of Benzyl ether. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

The MFI zeolites with nanosheet assemblies morphology were prepared by a seed-assisted strategy using specially designed bolaform surfactant [C6H13-N+ (CH3)(2)-C6H12-N+ (CH3)(2)-(CH2)(12)-O-(p-C6H4)(2)-O-(CH2)(12)-N+(CH3)(2)-C6H12-N+(CH3)(2)-C6H13] [Br-](4) (C6-12-diphe) as a structure-directing agent. The MFI zeolite nanosheet assemblies were composed of MFI nanosheets with randomly organized structure, exhibiting a narrow mesopore distribution. By tuning the Si/AI ratios of MFI zeolite nanosheet assemblies from 60 to 10, the morphology of resultant zeolites changed from nanosheet stacks to house-of-cards-like structures, and to nanosponges. In addition, the porosity and Bronsted acid/Lewis acid ratio exhibited a parabola-type dependence on the Si/Al ratios of obtained zeolites, indicating that meso-/microporosity and acidity of MFI nanosheet assemblies can be systematically tailored by changing the constituents of zeolites. Catalytic performance of MFI zeolite nanosheet assemblies was investigated in the benzylation of benzyl alcohol with mesitylene. The results revealed that MFI zeolite nanosheet assemblies exhibited extraordinary catalytic activity compared to conventional ZSM-5 zeolite. The conversion of benzyl alcohol and selectivity (1,3,5-trimethyl-2-benzylbenzene vs dibenzyl ether) of zeolite catalysts were linearly dependent on the 81-misted acid/Lewis acid ratio, and they exhibited a parabola-type dependence on the S-ext/S-BET, indicating that a balance between acidity and porosity of zeolites can be realized to modulate the catalytic properties of MFI zeolite nanosheet assemblies guided by C6-12-diphe.

Safety of Benzyl ether. About Benzyl ether, If you have any questions, you can contact Liu, BY; Chen, ZP; Huang, JJ; Chen, HY; Fang, YX or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

In 2019 RSC ADV published article about PHOTOREDOX CATALYSIS; SELECTIVE OXIDATION; OXYGEN-EVOLUTION; BENZYL ALCOHOL; OXIDES; WATER; NANOCOMPOSITES; NANOCRYSTALS; BINARY; RUTILE in [McDonald, Kori D.; Bartlett, Bart M.] Univ Michigan, Dept Chem, 930 North Univ Ave, Ann Arbor, MI 48109 USA in 2019, Cited 35. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. Name: Benzyl ether

With the aid of direct heating through microwave irradiation in non-aqueous media, nanocrystalline tungsten(vi) oxide is achievable in 30 minutes at 200 degrees C, faster and at a lower temperature than conventional synthesis methods. Forming in a platelet morphology, these particles are as small as 20 nm with a BET surface area of 37 m(2) g(-1) WO3. These nanoplatelets are active for the photocatalytic oxidation of the 1 degrees alcohols benzyl alcohol (rate constant, k of 2.6 x 10(-3) h(-1)) and 5-(hydroxymethyl)-2-furfural (k of 0.01 h(-1)) using 10 mg of WO3 with 2 mL of 0.250 M substrate in acetonitrile and a 150 mW cm(-2) 460 nm blue LED source. As expected, these rate constants are larger than those observed for commercially prepared, micron-sized WO3. XPS analysis shows that during catalysis, the concentration of W5+ on the surface increases, but the nanoplatelets are stable under these reaction conditions. The overall morphology and size of the particles are retained through the reactions. Moreover, the nanoplatelets are recyclable-showing no loss in activity for four reaction cycles.

Name: Benzyl ether. About Benzyl ether, If you have any questions, you can contact McDonald, KD; Bartlett, BM or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

An article Preparation of hierarchical SAPO-18 via alkaline/acid etching WOS:000527329400019 published article about MOLECULAR-SIEVES; MORDENITE ZEOLITES; MESOPOROSITY; DESILICATION; PERFORMANCE; CRYSTALS; METHANOL in [Fan, Dong; Cao, Kaipeng; Sun, Lijing; Xu, Shutao; Tian, Peng; Liu, Zhongmin] Chinese Acad Sci, Dalian Inst Chem Phys, Natl Engn Lab Methanol Olefins, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China; [Qiao, Yuyan] China Natl Chem Engn Co Ltd CNCEC, China Chem Technol Res Inst, Beijing 100007, Peoples R China; [Cao, Kaipeng; Sun, Lijing] Chinese Acad Sci, Univ Chinese Acad Sci, Beijing 100049, Peoples R China in 2020, Cited 32. HPLC of Formula: C14H14O. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

Hierarchical SAPO-18 molecular sieve was successfully post-synthesized in the alkaline tetraethyl ammonium hydroxide (TEAOH) solution and hydrochloride (HCl) acid solution. In the TEAOH solution, preferential dissolution occurs surrounding the defect sites in a controlled manner, leading to hierarchical SAPO-18 with wellpreserved chemical compositions and crystallinities. In acidic solution, the dissolution is revealed to be sensitive to both the defects and the chemical compositions (selective dissolution of the Si-O-Al domains), which cooperatively contribute to the generation of meso-/macropores in the crystals. The crystallization of SAPO-18 precursor is thus inferred to proceed via an oriented nanoparticle attachment mechanism in the early stage. The twinning and intergmwth of nanoparticles occur in an ordered way, leading to the oriented arrangement of the crystallite boundaries. The defects located at the intergrowth interface are prone to acid/alkaline attacks, and play crucial role in the development of hierarchical pore systems. The hierarchical SAPO-18 sample exhibits excellent catalytic reaction performance in the liquid phase benzylation reaction of benzene and benzyl alcohol.

About Benzyl ether, If you have any questions, you can contact Fan, D; Qiao, YY; Cao, KP; Sun, LJ; Xu, ST; Tian, P; Liu, ZM or concate me.. HPLC of Formula: C14H14O

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem

An article Collective Behavior of Reconfigurable Magnetic Droplets via Dynamic Self-Assembly WOS:000455561200176 published article about PARTICLES; PROPULSION; MOTION in [Wang, Qianqian; Yang, Lidong; Wang, Ben; Yu, Edwin; Yu, Jiangfan; Zhang, Li] Chinese Univ Hong Kong, Dept Mech & Automat Engn, Shatin, Hong Kong, Peoples R China; [Zhang, Li] Chinese Univ Hong Kong, Chow Yuk Ho Technol Ctr Innovat Med, Shatin, Hong Kong, Peoples R China; [Zhang, Li] Chinese Univ Hong Kong, T Stone Robot Inst, Shatin, Hong Kong, Peoples R China; [Wang, Ben] Chinese Univ Hong Kong, Dept Biomed Engn, Shatin, Hong Kong, Peoples R China in 2019, Cited 42. Quality Control of Benzyl ether. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

Dynamic self-assembly represents an effective approach to form energy-dissipative structures by introducing interactions among multiple building blocks with a continuous energy supply. Time-dependent magnetic fields are treated as convenient energy inputs to construct such a dynamic self assembled system. The induced interactions can be further tuned by modulating the input field, resulting in a diversity of assembled patterns. However, formation of a functional dynamic pattern with controllability remains a challenge. Herein, we report the formation and pattern control of dynamically self-assembled magnetic droplets at an air liquid interface, energized by a precessing magnetic field. The formation process involves the assembly of magnetic microparticles into particle chains inside droplets, and then highly ordered patterns are generated by balancing the induced interactions among droplets. By modulating the input field, the interactions and collective behaviors are adjusted and the pattern can be reversibly tuned, i.e., expand and shrink, in a controlled manner. Furthermore, the assembled droplets are able to be steered in two-dimensional as an entity by applying a magnetic field gradient. Utilizing dynamic pattern control and steerability of the assembled structure, cargoes are successfully trapped, transported, and released in a noncontact fashion, indicating that the dynamically assembled droplets can act as a reconfigurable untethered robotic end-effector for manipulation.

Quality Control of Benzyl ether. About Benzyl ether, If you have any questions, you can contact Wang, QQ; Yang, LD; Wang, B; Yu, E; Yu, JF; Zhang, L or concate me.

Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem