Category: 103-50-4

An article Direct synthesis of hierarchically structured MFI zeolite nanosheet assemblies with tailored activity in benzylation reaction WOS:000448091200028 published article about CATALYTIC PERFORMANCE; SPATIAL-DISTRIBUTION; ACID SITES; ALKYLATION; BEHAVIOR; POROSITY in [Liu, Baoyu; Chen, Zhipeng; Huang, Jiajin; Fang, Yanxiong] Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Guangdong, Peoples R China; [Chen, Huiyong] Northwest Univ, Sch Chem Engn, Xian 710069, Shaanxi, Peoples R China in 2019, Cited 42. COA of Formula: C14H14O. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

The MFI zeolites with nanosheet assemblies morphology were prepared by a seed-assisted strategy using specially designed bolaform surfactant [C6H13-N+ (CH3)(2)-C6H12-N+ (CH3)(2)-(CH2)(12)-O-(p-C6H4)(2)-O-(CH2)(12)-N+(CH3)(2)-C6H12-N+(CH3)(2)-C6H13] [Br-](4) (C6-12-diphe) as a structure-directing agent. The MFI zeolite nanosheet assemblies were composed of MFI nanosheets with randomly organized structure, exhibiting a narrow mesopore distribution. By tuning the Si/AI ratios of MFI zeolite nanosheet assemblies from 60 to 10, the morphology of resultant zeolites changed from nanosheet stacks to house-of-cards-like structures, and to nanosponges. In addition, the porosity and Bronsted acid/Lewis acid ratio exhibited a parabola-type dependence on the Si/Al ratios of obtained zeolites, indicating that meso-/microporosity and acidity of MFI nanosheet assemblies can be systematically tailored by changing the constituents of zeolites. Catalytic performance of MFI zeolite nanosheet assemblies was investigated in the benzylation of benzyl alcohol with mesitylene. The results revealed that MFI zeolite nanosheet assemblies exhibited extraordinary catalytic activity compared to conventional ZSM-5 zeolite. The conversion of benzyl alcohol and selectivity (1,3,5-trimethyl-2-benzylbenzene vs dibenzyl ether) of zeolite catalysts were linearly dependent on the 81-misted acid/Lewis acid ratio, and they exhibited a parabola-type dependence on the S-ext/S-BET, indicating that a balance between acidity and porosity of zeolites can be realized to modulate the catalytic properties of MFI zeolite nanosheet assemblies guided by C6-12-diphe.

About Benzyl ether, If you have any questions, you can contact Liu, BY; Chen, ZP; Huang, JJ; Chen, HY; Fang, YX or concate me.. COA of Formula: C14H14O

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Recently I am researching about BENZYLATION; AROMATICS; DIPHENYLMETHANE; ALCOHOLS; BENZENE; ARENES, Saw an article supported by the Qing Lan Project of Jiangsu Province; Top-notch Academic Programs Project of Jiangsu Higher Education Institutions [TAPP PPZY2015C221]; Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD); Jiangsu student’s platform for innovation training program [SPITP 201910298014Z]. Published in MDPI in BASEL ,Authors: Huang, YB; Luo, YJ; Wang, F. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether. Formula: C14H14O

The development of an efficient solid catalyst for Friedel-Crafts (FC) reactions is of great importance to organic synthetic chemistry. Herein, we reported the hafnium-doped mesoporous silica catalyst Hf/SBA-15 and its first use for Friedel-Crafts alkylation reactions. Catalysts with different Si/Hf ratios were prepared and characterized, among which Hf/SBA-15(20) (Si/Hf = 20:1) was the most active catalyst, offering up to 99.1% benzylated product under mild reaction conditions. The influences of reaction conditions on the product were systematically investigated and compared. Pyridine-IR characterization of the catalyst showed that Lewis acid formed the primary active sites for the Friedel-Crafts alkylation reaction. X-ray photoelectron spectroscopy (XPS) characterization revealed that the electron shift from the Hf center to the silica framework resulted in a more active Lewis metal center for FC reactions. Moreover, the catalyst was successfully applied to the alkylation reaction with different alcohols and aromatic compounds. Finally, the Hf/SBA-15(20) catalyst also showed good recyclability in the recycling runs, demonstrating its high potential of being used for large scale FC reactions in the industry.

Formula: C14H14O. About Benzyl ether, If you have any questions, you can contact Huang, YB; Luo, YJ; Wang, F or concate me.

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Product Details of 103-50-4. I found the field of Science & Technology – Other Topics very interesting. Saw the article FDISCO: Advanced solvent-based clearing method for imaging whole organs published in 2019, Reprint Addresses Zhu, D (corresponding author), Huazhong Univ Sci & Technol, Wuhan Natl Lab Optoelect, Britton Chance Ctr Biomed Photon, Wuhan, Hubei, Peoples R China.; Zhu, D (corresponding author), Huazhong Univ Sci & Technol, Sch Engn Sci, Collaborat Innovat Ctr Biomed Engn, MoE,Key Lab Biomed Photon, Wuhan, Hubei, Peoples R China.. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether.

Various optical clearing methods have emerged as powerful tools for deep biological imaging. Organic solvent-based clearing methods, such as three-dimensional imaging of solvent-cleared organs (3DISCO), present the advantages of high clearing efficiency and size reduction for panoptic imaging of large samples such as whole organs and even whole bodies. However, 3DISCO results in a rapid quenching of endogenous fluorescence, which has impeded its application. Here, we propose an advanced method named FDISCO to overcome this limitation. FDISCO can effectively preserve the fluorescence of various fluorescent probes and can achieve a long storage time of months while retaining potent clearing capability. We used FDISCO for high-resolution imaging and reconstruction of neuronal and vascular networks. Moreover, FDISCO is compatible with labeling by multiple viruses and enables fine visualization of neurons with weak fluorescence labeling in the whole brain. FDISCO represents an effective alternative to the three-dimensional mapping of whole organs and can be extensively used in biomedical studies.

About Benzyl ether, If you have any questions, you can contact Qi, YS; Yu, TT; Xu, JY; Wan, P; Ma, YL; Zhu, JT; Li, YS; Gong, H; Luo, QM; Zhu, D or concate me.. Product Details of 103-50-4

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Recently I am researching about BARIUM FERRITE NANOPARTICLES; IRON-OXIDE NANOPARTICLES; FEPT NANOPARTICLES; NONAQUEOUS SYNTHESIS; COBALT NANOCRYSTALS; EXCHANGE BIAS; COERCIVITY; PHASE; COPT, Saw an article supported by the . Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Preller, T; Menzel, D; Knickmeier, S; Temel, B; Garnweitner, G. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether. Computed Properties of C14H14O

The combination of materials with different magnetic properties at the nanoscale can lead to phenomena such as exchange bias via coupling effects, which shows huge potential for applications, e.g., in storage media or magnetic sensors. Whilst such structures so far are obtained via complex processes of alternating deposition from the gas phase hampering their application, their preparation from nanoparticle dispersions would not only be simplified but also enable a broad variety of possible material combinations and structures. Thereby, the processing of hard magnetic nanoparticles is challenging but can be circumvented by the use of precursor materials with subsequent phase transformation.

Computed Properties of C14H14O. About Benzyl ether, If you have any questions, you can contact Preller, T; Menzel, D; Knickmeier, S; Temel, B; Garnweitner, G or concate me.

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Recommanded Product: Benzyl ether. I found the field of Chemistry; Energy & Fuels; Engineering very interesting. Saw the article A Bifunctional Metal/Acid Catalyst for One-pot Multistep Synthesis of Pharmaceuticals published in 2020, Reprint Addresses Sabater, MJ (corresponding author), Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Ave Naranjos S-N, E-46022 Valencia, Spain.. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether.

One inhibitor of the fatty acid transporter FATP4 was synthesized in a three steps one-pot process in the presence of a bifunctional metal/acid catalyst. This molecule which has potential interest for the treatment of the obesity in orlistat (Xenical(TM)) analogue-based therapies has a 3,4-dihydropyrimidin-2(1H)-one (DHPM) scaffold and was obtained by means of a three one-pot process through successive oxidation, cyclocondensation and transesterification reactions. The one-pot strategy was extended to the synthesis of a series of related ester DHPM derivatives.

Recommanded Product: Benzyl ether. About Benzyl ether, If you have any questions, you can contact Lopez-Prado, MV; Sabater, MJ; Corma, A or concate me.

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Recommanded Product: 103-50-4. I found the field of Engineering very interesting. Saw the article Fine-Tuned Hierarchical Architecture of MWW Zeolites for Highly Efficient Alkylation via Suitable Accommodation published in 2020, Reprint Addresses Liu, BY (corresponding author), Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou Key Lab Clean Transportat Energy Chem, Guangzhou 510006, Guangdong, Peoples R China.; Chen, HY (corresponding author), Northwest Univ, Sch Chem Engn, Xian 710069, Shaanxi, Peoples R China.; Chen, HY (corresponding author), Northwest Univ, Chem Engn Res Ctr, Minist Educ Adv Use Technol Shanbei Energy, Shaanxi Res Ctr Engn Technol Clean Coal Convers, Xian 710069, Shaanxi, Peoples R China.. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether.

The hierarchical structure of zeolites plays a crucial role in determining their catalytic performance. Here, the effect of the hierarchical architecture and surface topology of pillared MWW zeolites on the catalytic properties of liquid alkylation between mesitylene and benzyl alcohol was investigated. Pillared MWW zeolite catalysts exhibited excellent activity (similar to 100% conversion) due to their elegant pore architecture, which could largely improve the accessibility of bulk molecules toward active sites on the external surface. In addition, molecular simulation showed that lamellar MWW zeolites with a 12-membered ring semicup surface topology could more effectively accommodate and stabilize the large intermediates formed in alkylation reactions compared with MFI zeolites, resulting in outstanding selectivity for 2-benzyl-1,3,5-trimethylbenzene (similar to 100%). The Thiele modulus (phi) and effectiveness factor (eta) verified that the resultant pillared MWW zeolites possessed a high degree of utilization without internal diffusion constraints under the present reaction conditions.

Recommanded Product: 103-50-4. About Benzyl ether, If you have any questions, you can contact Liu, BY; Liao, ZT; Xiao, X; Gan, SZ; Luo, RC; Wu, Y; Chen, HY; Fang, YX; Dong, JX or concate me.

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In 2019 MACROMOLECULES published article about DENSITY-FUNCTIONAL THEORY; SYNDIOTACTIC POLYSTYRENE; GAS SORPTION; POLY(PHENYLENE OXIDE); POLYMERIC MEMBRANES; SINGLE-CRYSTALS; X-RAY; TRANSPORT; FILMS; PPO in [Nagendra, Baku; Cozzolino, Antonietta; Daniel, Christophe; Rizzo, Paola; Guerra, Gaetano] Univ Salerno, Dipartimento Chim & Biol, Via Ponte Don Melillo, I-84084 Fisciano, Italy; [Nagendra, Baku; Cozzolino, Antonietta; Daniel, Christophe; Rizzo, Paola; Guerra, Gaetano] Univ Salerno, INSTM Res Unit, Via Ponte Don Melillo, I-84084 Fisciano, Italy; [Auriemma, Finizia; De Rosa, Claudio; D’Alterio, Massimo Christian; Tarallo, Oreste] Univ Napoli Federico II, Dipartimento Sci Chim, Via Cintia Complesso Monte St Angelo 21, I-80126 Naples, Italy; [Nuzzo, Anna] SAES Getters SpA, Viale Italia 77, I-20020 Milan, Italy in 2019, Cited 61. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. Recommanded Product: Benzyl ether

Extensive characterizations, mainly by wide-angle X-ray diffraction (WAXD) and Fourier transform infrared (FTIR) techniques, are reported for co-crystalline (CC) poly(2,6-dimethyl-1,4-phenylene)-oxide (PPO) films with many different low-molecular-mass guest molecules. These characterizations are also reported for the corresponding nanoporous crystalline (NC) phases, as obtained by suitable guest-removal procedures. Two well-separated NC forms, hereafter named alpha and beta, are obtained by guest removal from two well-separated groups of CC forms. alpha and beta NC forms can be easily recognized by reflections in WAXD patterns as well as by suitable FTIR crystalline peaks. Density and degree of crystallinity measurements confirm that both NC phases exhibit a density definitely smaller than for the amorphous phase (rho(am) = 1.04 g/cm(3) rho(beta) = 0.95 g/cm(3) > rho(alpha) = 0.93 g/cm(3)). Density functional theory calculations combined with geometrical analysis on PPO model systems indicate conformations suitable to fit the observed chain periodicities of the two crystalline forms (c = 5.28 and 5.47 angstrom, for alpha and beta NC forms, respectively).

About Benzyl ether, If you have any questions, you can contact Nagendra, B; Cozzolino, A; Daniel, C; Rizzo, P; Guerra, G; Auriemma, F; De Rosa, C; D’Alterio, MC; Tarallo, O; Nuzzo, A or concate me.. Recommanded Product: Benzyl ether

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COA of Formula: C14H14O. Martinez-Ferrate, O; Chatterjee, B; Werle, C; Leitner, W in [Martinez-Ferrate, Oriol; Chatterjee, Basujit; Werle, Christophe; Leitner, Walter] Max Planck Inst Chem Energy Convers, Stiftstr 34-36, D-45470 Mulheim, Germany; [Leitner, Walter] Rhein Westfal TH Aachen, ITMC, Worringer Weg 2, D-52074 Aachen, Germany published Hydrosilylation of carbonyl and carboxyl groups catalysed by Mn(i) complexes bearing triazole ligands in 2019, Cited 111. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

Manganese(i) complexes bearing triazole ligands are reported as catalysts for the hydrosilylation of carbonyl and carboxyl compounds. The desired reaction proceeds readily at 80 degrees C within 3 hours at catalyst loadings as low as 0.25 to 1 mol%. Hence, good to excellent yields of alcohols could be obtained for a wide range of substrates including ketones, esters, and carboxylic acids illustrating the versatility of the metal/ligand combination.

About Benzyl ether, If you have any questions, you can contact Martinez-Ferrate, O; Chatterjee, B; Werle, C; Leitner, W or concate me.. COA of Formula: C14H14O

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Ether – Wikipedia,
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Formula: C14H14O. In 2020 MICROPOR MESOPOR MAT published article about MOLECULAR-SIEVES; MORDENITE ZEOLITES; MESOPOROSITY; DESILICATION; PERFORMANCE; CRYSTALS; METHANOL in [Fan, Dong; Cao, Kaipeng; Sun, Lijing; Xu, Shutao; Tian, Peng; Liu, Zhongmin] Chinese Acad Sci, Dalian Inst Chem Phys, Natl Engn Lab Methanol Olefins, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China; [Qiao, Yuyan] China Natl Chem Engn Co Ltd CNCEC, China Chem Technol Res Inst, Beijing 100007, Peoples R China; [Cao, Kaipeng; Sun, Lijing] Chinese Acad Sci, Univ Chinese Acad Sci, Beijing 100049, Peoples R China in 2020, Cited 32. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.

Hierarchical SAPO-18 molecular sieve was successfully post-synthesized in the alkaline tetraethyl ammonium hydroxide (TEAOH) solution and hydrochloride (HCl) acid solution. In the TEAOH solution, preferential dissolution occurs surrounding the defect sites in a controlled manner, leading to hierarchical SAPO-18 with wellpreserved chemical compositions and crystallinities. In acidic solution, the dissolution is revealed to be sensitive to both the defects and the chemical compositions (selective dissolution of the Si-O-Al domains), which cooperatively contribute to the generation of meso-/macropores in the crystals. The crystallization of SAPO-18 precursor is thus inferred to proceed via an oriented nanoparticle attachment mechanism in the early stage. The twinning and intergmwth of nanoparticles occur in an ordered way, leading to the oriented arrangement of the crystallite boundaries. The defects located at the intergrowth interface are prone to acid/alkaline attacks, and play crucial role in the development of hierarchical pore systems. The hierarchical SAPO-18 sample exhibits excellent catalytic reaction performance in the liquid phase benzylation reaction of benzene and benzyl alcohol.

Formula: C14H14O. About Benzyl ether, If you have any questions, you can contact Fan, D; Qiao, YY; Cao, KP; Sun, LJ; Xu, ST; Tian, P; Liu, ZM or concate me.

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Ether – Wikipedia,
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Name: Benzyl ether. Authors Chen, ZJ; Han, S; Zhang, JH; Zheng, P; Liu, XD; Zhang, YY; Jia, G in ROYAL SOC CHEMISTRY published article about in [Chen, Zhangjian; Han, Shuo; Zhang, Jiahe; Zheng, Pai; Jia, Guang] Peking Univ, Sch Publ Hlth, Dept Occupat & Environm Hlth Sci, 38 Xueyuan Rd, Beijing 100191, Peoples R China; [Liu, Xiaodong; Zhang, Yuanyuan] Beijing Inst Occupat Dis Prevent & Treatment, 50 Yikesong Xiangshan, Beijing 100093, Peoples R China in 2021, Cited 44. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4

Many experimental studies have demonstrated that titanium dioxide nanoparticles (TiO2 NPs) could induce adverse health effects in vivo and in vitro. But epidemiological evidence and biomarkers related to early health effects are still lacking. This study aimed to explore biomarkers in the urine samples of workers occupationally exposed to a relatively low concentration of TiO2 NPs. A cross-sectional study was conducted in Jinan, China, involving 132 employees of a TiO2 NP manufacturing plant, among which the exposed group and control group were 1 : 1 matched by confounding factors such as gender, age, BMI, smoking and drinking. Untargeted metabolomics was performed in urine samples using high performance liquid chromatography-mass spectrometry (HPLC-MS) technology. The differential metabolites between the TiO2 NP exposed group and the control group were analyzed and then screened for potential biomarkers using bioinformatics methods. Metabolomics found a total of 1760 differentially expressed metabolites in the TiO2 NP exposed group, of which 60 differential metabolites were simultaneously confirmed by one-dimensional and multi-dimensional statistical analysis. Among these 60 differential metabolites, the relative expression of 27 metabolites increased, and the remaining 33 decreased. Pathway enrichment analysis further found that the metabolic pathway of long chain acyl-coa dehydrogenase deficiency (Lcad) was significantly enriched. Ten differential metabolites were selected as potential biomarkers of occupational exposure to TiO2 NPs using machine learning methods, including dibenzyl ether, quassimarin, tryptophan, etc. The receiver operating characteristic curves (ROCs) of these potential biomarkers showed good sensitivity and specificity. These potential biomarkers also had biological basis for occupational exposure to TiO2 NPs. Therefore, urine metabolites represented by dibenzyl ether are considered as good biomarkers of early health effects for occupational exposure to TiO2 NPs.

About Benzyl ether, If you have any questions, you can contact Chen, ZJ; Han, S; Zhang, JH; Zheng, P; Liu, XD; Zhang, YY; Jia, G or concate me.. Name: Benzyl ether

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Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem