The author of 《Schiff-based Pd(II)/Fe(III) bimetallic self-assembly monolayer – Preparation, structure, catalytic dynamic and synergism》 were Huang, Pingping; Song, Erran; Sun, Yimeng; Li, Tiesheng; Wei, Donghui; Liu, Minghua; Wu, Yangjie. And the article was published in Molecular Catalysis in 2019. Recommanded Product: 1-Bromo-3-methoxybenzene The author mentioned the following in the article:
Graphene oxide-supported Pd(II)/Fe(III) bimetallic catalytic monolayer (denoted as GO@H-Pd/Fe) was prepared and characterized. Its catalytic performance was assessed for the Suzuki coupling reaction; its synergetic effect and catalytic mechanism were also systematically investigated. Results showed that orientation, composition and distribution of catalyst had an efficient effect on catalytic activity. Catalytic activity of [email protected]/Fe0.90 was 475 times more than that of GO@H-Pd due to the ordered catalytic monolayer immobilized on GO, proper ratio of Pd/Fe and the synergetic effect between Pd(II) and Fe(III), which could form an active cluster containing Pd and Fe. The deactivation mechanism was confirmed to be the aggregation of the active center during recycling. A heterogeneous catalytic mechanism was also proved by the poison test, hot filtration and ReactIR. The results of ReactIR presented different dynamic catalytic processes for [email protected] and homogeneous catalyst (Li2PdCl4/FeCl3·6H2O). The activation energies were 9.7 KJ/mol and 3.7 KJ/mol obtained for the heterogeneous and homogeneous catalysts, resp. The experimental process involved the reaction of 1-Bromo-3-methoxybenzene(cas: 2398-37-0Recommanded Product: 1-Bromo-3-methoxybenzene)
1-Bromo-3-methoxybenzene(cas: 2398-37-0) can be used in chemical reaction as intermediates to obtain target materials such as dyes, pharmaceuticals, perfumes, photoinitiators and agrochemicals.Recommanded Product: 1-Bromo-3-methoxybenzene
Referemce:
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Ether | (C2H5)2O – PubChem