《A Selectfluor-promoted oxidative reaction of disulfides and amines: access to sulfinamides》 was published in Organic & Biomolecular Chemistry in 2020. These research results belong to Mei, Haibo; Liu, Jiang; Pajkert, Romana; Roschenthaler, Gerd-Volker; Han, Jianlin. Formula: C12H10S2 The article mentions the following:
An unprecedented transition-metal-free oxidative reaction of disulfides and amines with Selectfluor as a mild oxidant under aerobic conditions was developed. This reaction was conducted under mild conditions and tolerated a wide range of coupling partners including disulfides and amines, affording the corresponding sulfinamide products in good chem. yields. Furthermore, this reaction could be used in gram-scale synthesis. This reaction enriches the research content of Selectfluor and provides a valuable vista for the convenient synthesis of sulfinamides. After reading the article, we found that the author used 1,2-Diphenyldisulfane(cas: 882-33-7Formula: C12H10S2)
1,2-Diphenyldisulfane(cas: 882-33-7) belongs to ethers.Although ethers resist hydrolysis, they are cleaved by hydrobromic acid and hydroiodic acid. Hydrogen chloride cleaves ethers only slowly. Formula: C12H10S2
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem