In 2022,Alberca, Saul; Velazquez, Marta; Trujillo-Sierra, Jose; Iglesias-Sigueenza, Javier; Fernandez, Rosario; Lassaletta, Jose M.; Monge, David published an article in Advanced Synthesis & Catalysis. The title of the article was 《Pd(II)-Catalyzed Asymmetric Addition of Arylboronic Acids to Aliphatic N-Carbamoyl Hydrazones》.Recommanded Product: 60656-87-3 The author mentioned the following in the article:
Catalysts generated by combinations of Pd(TFA)2 and 2-pyridinecarbohydrazone ligands have been applied to 1,2 addition of arylboronic acids ArB(OH)2 to aliphatic N-carbamoyl (Cbz) hydrazones RCH:NNR1R2 (R1R2 = phthaloyl; R1 = Cbz, R2 = H), affording protected α-aryl monoalkylhydrazines RCHArNHNR1R2 with high enantioselectivities (37-99% ee). Subsequent removal of the benzyloxy carbonyl protecting group provides a direct entry to free monosubstituted hydrazines, key building blocks for the synthesis of appealing 1,2-diaza-heterocycles, amino acid derived hydrazides and other pharmacophores thereof. The experimental process involved the reaction of 2-(Benzyloxy)acetaldehyde(cas: 60656-87-3Recommanded Product: 60656-87-3)
2-(Benzyloxy)acetaldehyde(cas: 60656-87-3) may be used in the following syntheses: (3S,5S)-methyl 6-benzyloxy-3,5-dihydroxyhexanoate ,(S)-5-benzyloxy-4-hydroxypentan-2-one, myxothiazols.Recommanded Product: 60656-87-3
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem