Ding, Y.-F.; La, Y.-T.; Li, W.-D.; Yao, G.-X.; Wang, L.; Dong, W.-K. published an article in 2021. The article was titled 《Experimental and Theoretical Studies of Two New Trinuclear Ni(II) Asymmetric Salamo-Based Complexes》, and you may find the article in Russian Journal of General Chemistry.Recommanded Product: 2-Hydroxy-4-methoxybenzaldehyde The information in the text is summarized as follows:
Two new trinuclear Ni(II) complexes, [{Ni(L)(DMF)(μ-OAc)}2Ni] (1) and [{Ni(L)(EtOH)(μ-OAc)}2Ni]·2CH2Cl2 (2), have been successfully synthesized from a new asym. salamo-based hexa-dentate chelating ligand (H2L) and Ni(OAc)2·4H2O, and characterized by elemental anal., IR and UV-Vis spectra, and X-ray crystallog. The binding ratio of H2L and Ni(II) ion has been confirmed by UV-Vis titration All Ni(II) atoms are hexa-coordinated, and the complexes have octahedral configuration, though with difference in the solvent mols. (DMF/EtOH) involved in the coordination, composition of the hydrogen bond and chem. stability. This conclusion is confirmed by Hirshfeld surfaces analyses and D. Functional Theory (DFT). In the part of experimental materials, we found many familiar compounds, such as 2-Hydroxy-4-methoxybenzaldehyde(cas: 673-22-3Recommanded Product: 2-Hydroxy-4-methoxybenzaldehyde)
2-Hydroxy-4-methoxybenzaldehyde(cas: 673-22-3) is the main component of root bark essential oil of Periploca sepium Bunge. It is a potential tyrosinase inhibitor present in African medicinal plants. 2-Hydroxy-4-methoxybenzaldehyde was used in the synthesis of Schiff base ligand.Recommanded Product: 2-Hydroxy-4-methoxybenzaldehyde
Referemce:
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