Name: 1-Iodo-2-methoxybenzeneIn 2021 ,《Design and Applications of a SO2 Surrogate in Palladium-Catalyzed Direct Aminosulfonylation between Aryl Iodides and Amines》 was published in Angewandte Chemie, International Edition. The article was written by Jia, Xiuwen; Kramer, Soeren; Skrydstrup, Troels; Lian, Zhong. The article contains the following contents:
A new SO2 surrogate is reported that is cheap, bench-stable, and can be accessed in just two steps from bulk chems. Essentially complete SO2 release is achieved in 5 min. Eight established sulfonylation reactions proceeded smoothly by ex situ formation of SO2 by utilizing a two-chamber system in combination with the SO2 surrogate. Furthermore, we report the first direct aminosulfonylation between aryl iodides and amines. Broad functional group tolerance is demonstrated, and the method is applicable to pharmaceutically relevant substrates, including heterocyclic substrates. The experimental process involved the reaction of 1-Iodo-2-methoxybenzene(cas: 529-28-2Name: 1-Iodo-2-methoxybenzene)
1-Iodo-2-methoxybenzene(cas: 529-28-2) participates in palladium catalyzed enantioselective Heck arylation of 2,3-dihydrofuran in the presence of chiral ionic liquids containing L-prolinate and L-lactate anions and non-chiral quaternary ammonium cations.Name: 1-Iodo-2-methoxybenzene
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