In 2019,Science (Washington, DC, United States) included an article by Smaligo, Andrew J.; Swain, Manisha; Quintana, Jason C.; Tan, Mikayla F.; Kim, Danielle A.; Kwon, Ohyun. Related Products of 882-33-7. The article was titled 《Hydrodealkenylative C(sp3)-C(sp2) bond fragmentation》. The information in the text is summarized as follows:
1,1-Substituted alkenyl-substituted carbocycles such as I underwent chemoselective hydrodealkenylation of C(sp3)-C(sp2) bonds by treatment with O3 in MeOH at -78° followed by FeSO4 and PhSH with warming to ambient temperature to yield carbocycles such as II. The reactions are performed in nonanhydrous solvents and open to the air, are complete within 30 min, and deliver their products in high yields, even on decagram scales. The method was used for the conversion of terpenes to synthetic intermediates not easily available by other methods; five of the intermediates were used in formal syntheses of natural products and an unnatural steroid. Methylene carbocycles and endocyclic alkenes underwent oxidative cleavage to yield Me esters or lactones and 1,3-dioxolanes (after acetalization with ethylene glycol), resp. The results came from multiple reactions, including the reaction of 1,2-Diphenyldisulfane(cas: 882-33-7Related Products of 882-33-7)
1,2-Diphenyldisulfane(cas: 882-33-7) belongs to ethers.The C-O bonds that comprise simple ethers are strong. They are unreactive toward all but the strongest bases. Although generally of low chemical reactivity, they are more reactive than alkanes. Related Products of 882-33-7
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem