Quality Control of 3-Methoxyphenylboronic acidIn 2021 ,《Nickel(II)-Catalyzed Addition of Aryl and Heteroaryl Boroxines to the Sulfinylamine Reagent TrNSO: The Catalytic Synthesis of Sulfinamides, Sulfonimidamides and Primary Sulfonamides》 was published in Journal of the American Chemical Society. The article was written by Lo, Pui Kin Tony; Willis, Michael C.. The article contains the following contents:
A redox-neutral Ni(II)-catalyzed addition of (hetero)aryl boroxines to N-sulfinyltritylamine (TrNSO) was developed to afford sulfonimidamides I [R = 2-MeC6H4, 4-FC6H4, 2-furyl, etc.; R1 = (CH2)2CN, pyrrolidin-1-yl, piperidin-1-yl, etc.] and primary sulfonamides II [R2 = 2-thienyl, 4-FC6H4, 4-MeOC6H4, etc.]. The reactions used a catalyst generated from the combination of com., air-stable NiCl2·(glyme) and a com. available bipyridine ligand. These transformations were all achieved using one-pot procedures. For larger-scale reactions, the catalyst loading could be reduced to 1 mol %. In addition to this study using 3-Methoxyphenylboronic acid, there are many other studies that have used 3-Methoxyphenylboronic acid(cas: 10365-98-7Quality Control of 3-Methoxyphenylboronic acid) was used in this study.
3-Methoxyphenylboronic acid(cas: 10365-98-7) belongs to boronic acids. Boronic acids are mild Lewis acids which are generally stable and easy to handle, making them important to organic synthesis.Quality Control of 3-Methoxyphenylboronic acid
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