Ling, Liang; He, Yuan; Zhang, Xue; Luo, Meiming; Zeng, Xiaoming published the artcile< Hydrogenation of (Hetero)aryl Boronate Esters with a Cyclic (Alkyl)(amino)carbene-Rhodium Complex: Direct Access to cis-Substituted Borylated Cycloalkanes and Saturated Heterocycles>, Computed Properties of 190788-60-4, the main research area is cyclic aminocarbene rhodium complex preparation catalyst hydrogenation heteroaryl boronate; crystal structure aminocyclohexylboronate ester cyclic aminocarbene rhodium complex; mol structure aminocyclohexylboronate ester cyclic aminocarbene rhodium complex; borylated cycloalkane preparation coupling arylation reaction; heterocycle cis borylated preparation; N-heterocyclic carbenes; boron; hydrogenation; selectivity; transition-metal catalysis.
The authors herein report the hydrogenation of substituted aryl- and heteroaryl boronate esters for the selective synthesis of cis-substituted borylated cycloalkanes and saturated heterocycles. A cyclic (alkyl)(amino)carbene-ligated Rh complex with two di-Me groups at the ortho-alkyl scaffold of the carbene showed high reactivity in promoting the hydrogenation, thereby enabling the hydrogenation of (hetero)arenes with retention of the synthetically valuable boronate group. This process constitutes a clean, atom-economic, as well as chemo- and stereoselective route for the generation of cis-configured, diversely substituted borylated cycloalkanes and saturated heterocycles that are usually elusive and difficult to prepare
Angewandte Chemie, International Edition published new progress about Aromatic compounds Role: CAT (Catalyst Use), RCT (Reactant), SPN (Synthetic Preparation), USES (Uses), RACT (Reactant or Reagent), PREP (Preparation) ((hetero)aryl boronate esters). 190788-60-4 belongs to class ethers-buliding-blocks, and the molecular formula is C13H19BO3, Computed Properties of 190788-60-4.
Referemce:
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