Dhakshinamoorthy, Amarajothi; Garcia, Cristina Valles; Concepcion, Patricia; Garcia, Hermenegildo published the artcile< Arene borylation through C-H activation using Cu3(BTC)2 as heterogeneous catalyst>, HPLC of Formula: 190788-60-4, the main research area is arene borylation carbon hydrogen activation copper MOF catalyst mechanism.
C-H borylation by diborane is an important process to access organoboron compounds Noble metals, including Ir and Rh-based complexes either in the form of homogeneous or heterogeneous catalysts, have been reported to promote arene C-H borylation. Recently, metal organic frameworks (MOFs) having Ir and Co as active sites have been used as catalysts, but they require co-catalysts. In the present study, com. available Cu3(BTC)2 (BTC: 1,3,5-benzenetricarboxylate) MOF is reported as an effective catalyst to promote borylation of arenes through C-H activation employing bis(pinacolato)diboron as reagent leading to benzylic and aromatic borylation products. Interestingly, other related MOFs like MIL-101(Cr) and Al(OH)(BDC) (BDC: 1,4-benzenedicarboxylate) do not exhibit catalytic activity under identical conditions. Mechanistic studies using in-situ IR spectroscopy reveal that Cu ions play a crucial role in activating the arene and B-B bond in bis(pinacolato)diboron.
Catalysis Today published new progress about Aromatic hydrocarbons Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 190788-60-4 belongs to class ethers-buliding-blocks, and the molecular formula is C13H19BO3, HPLC of Formula: 190788-60-4.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem