Fujio, Mizue; Taguchi, Miyako; Wada, Yoshiko; Seki, Yoji; Mishima, Masaaki; Tsuno, Yuho published the artcile< Carbon-13 NMR studies on reaction mechanisms. IV. Solvolysis of 4-aryl-n-butyl brosylates>, Reference of 52244-70-9, the main research area is solvolysis phenylbutyl brosylate kinetics; carbon NMR solvolysis kinetics; anchimeric assistance solvolysis kinetics.
The solvolysis of methoxy-substituted 4-phenylbutyl-1-13C (90% enriched) brosylate gave both open-chain ester products and isomeric products (e.g., 6- or 7-methoxytetralin-1-13C) via anchimerically-assisted pathways. The 13C NMR tracer technique was applied to the solvolysis mechanism and kinetics. Suitably positioned MeO groups accelerated the anchimerically assisted route. Transition states for the assisted pathways were discussed.
Memoirs of the Faculty of Science, Kyushu University, Series C: Chemistry published new progress about Acetolysis. 52244-70-9 belongs to class ethers-buliding-blocks, and the molecular formula is C11H16O2, Reference of 52244-70-9.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem