Karmakar, Ujjwal; Hwang, Ho Seong; Lee, Yunjeong; Cho, Eun Jin published the artcile< Photocatalytic para-Selective C-H Functionalization of Anilines with Diazomalonates>, Synthetic Route of 10541-78-3, the main research area is photocatalytic para selective alkylation aniline diazomalonate.
Visible-light-induced para-selective C-H functionalization of anilines over N-H insertion was developed using diazomalonates with the help of an Ir(III) photocatalyst. The para-selective radical-radical cross coupling proceeded via C-centered radical intermediates generated from both anilines and diazomalonates. The photochem. of anilines could be extended to other N-heterocycles, such as indole and carbazole. The reaction pathway for the selective C-C coupling was validated by electrochem. and photophys. experiments as well as computational studies.
Organic Letters published new progress about Alkylation, regioselective (photocatalytic). 10541-78-3 belongs to class ethers-buliding-blocks, and the molecular formula is C8H11NO, Synthetic Route of 10541-78-3.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem