Chen, Junjun; Hua, Kaimin; Liu, Xiaofang; Deng, Yuchao; Wei, Baiyin; Wang, Hui; Sun, Yuhan published the artcile< Selective Production of Linear Aldehydes and Alcohols from Alkenes using Formic Acid as Syngas Surrogate>, Quality Control of 52244-70-9, the main research area is alkene formic acid rhodium regioselective hydroformylation catalyst; aldehyde linear preparation; formic acid alkene rhodium Shvo regioselective hydroxymethylation catalyst; alc linear preparation; formic acid; hydroformylation; hydroxymethylation; linear alcohol; tandem reaction.
Performing carbonylation without the use of carbon monoxide for high-value-added products is an attractive yet challenging topic in sustainable chem. Herein, effective methods for producing linear aldehydes or alcs. selectively with formic acid as both carbon monoxide and hydrogen source have been described. Linear-selective hydroformylation of alkenes proceeds smoothly with up to 88% yield and >30 regioselectivity in the presence of single Rh catalyst. Strikingly, introducing Ru into the system, the dual Rh/Ru catalysts accomplish efficient and regioselective hydroxymethylation in one pot. The present processes utilizing formic acid as syngas surrogate operate simply under mild condition, which opens a sustainable way for production of linear aldehydes and alcs. without the need for gas cylinders and autoclaves. As formic acid can be readily produced via CO2 hydrogenation, the protocols represent indirect approaches for chem. valorization of CO2.
Chemistry – A European Journal published new progress about Alcohols Role: SPN (Synthetic Preparation), PREP (Preparation). 52244-70-9 belongs to class ethers-buliding-blocks, and the molecular formula is C11H16O2, Quality Control of 52244-70-9.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem