Atkinson, Robert S.; Green, Richard H. published the artcile< 1,5-Hydride shifts in acyclic systems containing α,β-unsaturated ketones and p-methoxyphenyl groups>, Reference of 52244-70-9, the main research area is ketone unsaturated rearrangement mechanism; hydride shift rearrangement ketone.
D-labeling showed that the acid-catalyzed rearrangement of p-HOC6H4(CH2)2CR2CH2CH:CHCOMe (I, R = H) to 2-(p-hydroxyphenyl)cyclohexyl Me ketone involved an intramol. H shift. A similar rearrangement was observed for I (R = Me) and its aromatic Me ether but not analogous products were obtained from p-MeOC6H4CHR(CH2)2CH:CHCOMe (R = H, p-MeOC6H4) under the same reaction conditions.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999) published new progress about Hydride shift. 52244-70-9 belongs to class ethers-buliding-blocks, and the molecular formula is C11H16O2, Reference of 52244-70-9.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem