Chen, Fenglin; Chen, Ke; Zhang, Yao; He, Yuli; Wang, Yi-Ming; Zhu, Shaolin published the artcile< Remote Migratory Cross-Electrophile Coupling and Olefin Hydroarylation Reactions Enabled by in Situ Generation of NiH>, Related Products of 52244-70-9, the main research area is nickel catalyzed reductive cross electrophile coupling; migratory electrophile coupling olefin hydroarylation ligand nickel controlled; diarylalkane structurally diverse preparation regioselectivity.
A highly efficient strategy for remote reductive cross-electrophile coupling has been developed through the ligand-controlled nickel migration/arylation. This general protocol allows the use of abundant and bench-stable alkyl bromides and aryl bromides for the synthesis of a wide range of structurally diverse 1,1-diarylalkanes in excellent yields and high regioselectivities under mild conditions. Authors also demonstrated that alkyl bromide could be replaced by the proposed olefin intermediate while using Pr bromide/Mn0 as a potential hydride source.
Journal of the American Chemical Society published new progress about Alkanes Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation) (1,1-diarylalkanes). 52244-70-9 belongs to class ethers-buliding-blocks, and the molecular formula is C11H16O2, Related Products of 52244-70-9.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem