Cas: 2657-87-6 was involved in experiment | Materials Today Communications 2021

3-(4-Aminophenoxy)aniline is one of ethers-buliding-blocks. Ethers lack the hydroxyl groups of alcohols. Without the strongly polarized O―H bond, ether molecules cannot engage in hydrogen bonding with each other. Synthetic Route of C12H12N2OEthers do have nonbonding electron pairs on their oxygen atoms, however, and they can form hydrogen bonds with other molecules (alcohols, amines, etc.) that have O―H or N―H bonds.

Synthetic Route of C12H12N2OIn 2021, Winters, Jonas;Dehaen, Wim;Binnemans, Koen published 《N-butyl pyrrolidone/ionic liquid mixtures as benign alternative solvents to N-methyl pyrrolidone for the synthesis of polyaramids》. 《Materials Today Communications》published the findings. The article contains the following contents:

N-Me pyrrolidone (NMP) is a polar aprotic solvent that is critical for the production of polyaramids. However, due to its reprotoxicity and pending REACH restrictions, a benign alternative is needed. A mixture of N-Bu pyrrolidone (NBP) and the ionic liquid [C8MIm][Cl] is proposed as a promising candidate to replace NMP. This organic electrolyte solution provides a green approach to polyaramid synthesis. The experimental procedure involved many compounds, such as 3-(4-Aminophenoxy)aniline (cas: 2657-87-6) .

3-(4-Aminophenoxy)aniline is one of ethers-buliding-blocks. Ethers lack the hydroxyl groups of alcohols. Without the strongly polarized O―H bond, ether molecules cannot engage in hydrogen bonding with each other. Synthetic Route of C12H12N2OEthers do have nonbonding electron pairs on their oxygen atoms, however, and they can form hydrogen bonds with other molecules (alcohols, amines, etc.) that have O―H or N―H bonds.

Reference:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem