In 2019.0 J AM CHEM SOC published article about IRON-SILICON BOND; SILYL COMPLEXES; CYCLIC ETHERS; TRANSITION; CLEAVAGE; PALLADIUM; ALKYL; ARYL; HYDROSILATION; MECHANISM in [Wierschen, Andreas L.; Romano, Neyen; Gagne, Michel R.] Univ N Carolina, Dept Chem, Caudill Labs, Chapel Hill, NC 27599 USA; [Lee, Stephen J.] US Army, Res Off, POB 12211, Res Triangle Pk, NC 27709 USA in 2019.0, Cited 63.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8. Quality Control of Diphenyl oxide
The synthesis and characterization of the room-temperature and solution-stable silylpalladium cations (PCy3)(2)Pd-SiR3+(C6F5)(4)B- (SiR3 = SiMe2Et, SiHEt2) and (Xantphos)Pd-SiR3+(BAr4f) (SiR3 = SiMe2Et, SiHEt2; Xant-phos = 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; BAr4f = (3,5-(CF3)(2)C6H3)(4)B-) are reported. Spectroscopic and ligand addition experiments suggest that silylpalladium complexes of the type (PCy3) Pd-SiR3+ are three-coordinate and T-shaped. Addition of dialkyl ethers to both the PCy3 and Xantphos-based silylpalladium cations resulted in the cleavage of C(sp(3))-O bonds and the generation of cationic Pd-alkyl complexes. Mechanistically enabling is the ability of silylpalladium cations to behave as sources of both electrophilic silylium ions and nucleophilic LnPd(0).
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Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem