Recently I am researching about CATALYTIC TRANSFER HYDROGENOLYSIS; TRANSFER HYDROGENATION; CHEMICALS; MONTMORILLONITE; DEPOLYMERIZATION; LIGNOCELLULOSE; TRANSFORMATION; FRACTIONATION; NANOPARTICLES; CONVERSION, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21773307, 21873012] Funding Source: Medline. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Xue, ZM; Yu, HT; He, J; Zhang, YB; Lan, X; Liu, RD; Zhang, LY; Mu, TC. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide. Recommanded Product: 101-84-8
Cleavage of ether bonds is a crucial but challenging step for lignin valorization. To efficiently realize this transformation, the development of robust catalysts or catalytic systems is required. In this study, montmorillonite (MMT)-supported Ru (denoted as Ru/MMT) is fabricated as a dual-functional heterogeneous catalyst to cleave various types of ether bonds through transfer hydrogenolysis without using any additional acids or bases. The prepared Ru/MMT material is found to efficiently catalyze the cleavage of various lignin models and lignin-derived phenols; cyclohexanes (fuels) and cyclohexanols (key intermediates) are the main products. The synergistic effect between electron-enriched Ru and the acidic sites on MMT contributes to the excellent performance of Ru/MMT. Systematic studies reveal that the reaction proceeds through two possible reaction pathways, including the direct cleavage of ether bonds and the formation of intermediates with one hydrogenated benzene ring, for all examined types of ether bonds, namely, 4-O-5, alpha-O-4, and beta-O-4.
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Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem