Recently I am researching about C-O BOND; MODEL COMPOUNDS; M-CRESOL; SELECTIVE HYDRODEOXYGENATION; ARYL ETHERS; IRON-OXIDES; CATALYSTS; GUAIACOL; CONVERSION; ANISOLE, Saw an article supported by the U.S. Department of Energy (DOE), Office of Science, Basic Energy Sciences (BES)United States Department of Energy (DOE); Division of Chemical SciencesUnited States Department of Energy (DOE) [DE-FG02-05ER15712]. Published in ELSEVIER in AMSTERDAM ,Authors: Zhang, JH; Sun, JM; Sudduth, B; Hernandez, XP; Wang, Y. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide. Computed Properties of C12H10O
Although Pd/Fe bimetallic catalysts have been extensively studied in vapor-phase hydrodeoxygenation of phenolics (i.e., guaiacol, cresol), little is yet known about their performance in liquid-phase reactions. In this work, we present a mechanistic study on the Pd/Fe bimetallic catalysts in liquid-phase hydrodeoxygenation of phenolics. The role of tautomerization in hydrodeoxygenation of the lignin-derived phenolics, particularly for ring saturation, is systematically studied by employing two representative modeling compounds: phenol (a molecule that is keto-enol tautomeric) and diphenyl ether (a molecule that does not allow ketol-enol tautomerization). It was found that although the addition of oxyphilic Fe inhibits the direct aromatic ring saturation reaction typically occurring on Pd, tautomerization opens another reaction pathway toward ring saturation products (i.e. cyclohexanone, cyclohexanol, cyclohexane et al.), where both tautomerization and the hydrogenation of keto isomers are significantly enhanced to produce cyclohexanol followed by direct hydrogenolysis of the cyclohexanol to cyclohexane.
Computed Properties of C12H10O. Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem