Recently I am researching about ARYL SULFOXIDES; ALLOSTERIC INHIBITORS; ELECTRON-TRANSFER; ALPHA-ARYLATION; LIGHT; SALTS; TRANSFORMATIONS; PSEUDILINS; REDUCTION; SULFONIUM, Saw an article supported by the EPSRCUK Research & Innovation (UKRI)Engineering & Physical Sciences Research Council (EPSRC); University of Manchester; Engineering and Physical Sciences Research CouncilUK Research & Innovation (UKRI)Engineering & Physical Sciences Research Council (EPSRC) [EP/M005062/1, 1515860, EP/P001386/1] Funding Source: researchfish. Published in NATURE RESEARCH in BERLIN ,Authors: Aukland, MH; Siauciulis, M; West, A; Perry, GJP; Procter, DJ. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide. Formula: C12H10O
Aryl-aryl cross-coupling constitutes one of the most widely used procedures for the synthesis of high-value materials that range from pharmaceuticals to organic electronics and conducting polymers. The assembly of (hetero)biaryl scaffolds generally requires multiple steps; coupling partners must be functionalized before the key bond-forming event is considered. The development of selective C-H arylation processes in arenes-which sidestep the need for prefunctionalized partners-is thus crucial for streamlining the construction of these key architectures. Here we report an expedient, one-pot assembly of (hetero)biaryl motifs using photocatalysis and two non-prefunctionalized arene partners. The approach is underpinned by the functionalization of a C-H bond in an arene coupling partner using the interrupted Pummerer reaction. A unique pairing of the organic photoredox catalyst and the intermediate dibenzothiophenium salts enables highly selective reduction in the presence of sensitive functionalities. The utility of the metal-free, one-pot strategy is exemplified by the synthesis of a bioactive natural product and the modification of complex molecules of societal importance.
Welcome to talk about 101-84-8, If you have any questions, you can contact Aukland, MH; Siauciulis, M; West, A; Perry, GJP; Procter, DJ or send Email.. Formula: C12H10O
Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem