An article Oxidative cracking of three to five-member ring polycyclic aromatic hydrocarbons in subcritical and supercritical water WOS:000582123000012 published article about UV-FLUORESCENCE SPECTROSCOPY; EXCLUSION CHROMATOGRAPHY COLUMNS; HIGH-TEMPERATURE CHEMISTRY; REACTION-MECHANISMS; CATALYTIC CRACKING; CHEMICAL-REACTIONS; HYDROUS PYROLYSIS; VACUUM RESIDUE; WASTE-WATER; HEAVY OIL in [Daud, Ahmad Rafizan Mohamad; Berrueco, Cesar; Hellgardt, Klaus; Millan, Marcos; Kandiyoti, Rafael] Imperial Coll London, Dept Chem Engn, London SW7 2AZ, England; [Daud, Ahmad Rafizan Mohamad] Univ Teknol MARA Johor, Fac Chem Engn, Pasir Gudang Campus, Masai 81750, Johor, Malaysia in 2021.0, Cited 59.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8. Computed Properties of C12H10O
Polycyclic aromatic hydrocarbons (PAH) are refractory structures common in heavy hydrocarbons. Thermal cracking in supercritical water (SCW) is limited but PAH can be completely oxidised if an oxidant is added. By restricting oxidant supply to substoichiometric amounts, this study aims to achieve partial oxidation as a route to useful chemicals, such as mono- and bi-aromatics. Oxidative cracking reactions of anthracene, pyrene and benzo[a]pyrene in subcritical and SCW were studied. PAH conversions well above 90 % were achieved along a fast heating ramp in a batch reactor. This quick initial oxidation took place predominantly in inner rings, weakening the aromatic structure and increasing cracking reactivity. This oxidation-cracking pathway became dominant in the SCW region, producing mostly oxygenated compounds with fewer aromatic rings. On the other hand, competing reactions leading to polymerization were favoured in the subcritical water region. PAH reactivity was found to follow the order anthracene > benzo[a]pyrene > pyrene. (C) 2020 Elsevier B.V. All rights reserved.
Computed Properties of C12H10O. Welcome to talk about 101-84-8, If you have any questions, you can contact Daud, ARM; Berrueco, C; Hellgardt, K; Millan, M; Kandiyoti, R or send Email.
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