An article DMSO-Triggered Complete Oxygen Transfer Leading to Accelerated Aqueous Hydrolysis of Organohalides under Mild Conditions WOS:000477706600013 published article about ALKYL-HALIDES; ALKOXYSULFONIUM SALTS; ARYLMETHYL BROMIDES; AEROBIC CONVERSION; FACILE SYNTHESIS; SELECTIVE METHOD; BENZYL-CHLORIDE; ORGANIC HALIDES; IONIC LIQUID; ALCOHOLS in [Liu, Haicheng; Liu, Jianping; Cheng, Xiaokai; Jia, Xiaojuan; Xu, Qing] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325035, Zhejiang, Peoples R China; [Yu, Lei; Xu, Qing] Yangzhou Univ, Inst Pesticide, Sch Chem & Chem Engn, Yangzhou 225002, Jiangsu, Peoples R China; [Yu, Lei; Xu, Qing] Yangzhou Univ, Sch Hort & Plant Protect, Yangzhou 225002, Jiangsu, Peoples R China in 2019, Cited 59. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4. Application In Synthesis of Benzyl ether
Addition of DMSO is found to greatly accelerate the aqueous hydrolysis of organohalides to alcohols, providing a neutral, more efficient, milder and more economic process. Mechanistic studies using O-18-DMSO and O-18-H2O showed that, contrary to the opinion that DMSO works as a dipolar solvent to enhance water’s nucleophilicity, the accelerating effect comes from a complete oxygen transfer from DMSO to organohalides through generation of ROS+Me2.X- salts through C-O bond formation, followed by O-S bond disassociative hydrolysis of ROS+Me2.X- with water. This method is applicable to a wide range of organohalides and thus may have potential for practical industrial application, owing to easy recovery of DMSO from the H2O/DMSO mixture by regular vacuum rectification.
Application In Synthesis of Benzyl ether. About Benzyl ether, If you have any questions, you can contact Liu, HC; Liu, JP; Cheng, XK; Jia, XJ; Yu, L; Xu, Q or concate me.
Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem