Category: ethers-buliding-blocks. Recently I am researching about ALKYL-HALIDES; ALKOXYSULFONIUM SALTS; ARYLMETHYL BROMIDES; AEROBIC CONVERSION; FACILE SYNTHESIS; SELECTIVE METHOD; BENZYL-CHLORIDE; ORGANIC HALIDES; IONIC LIQUID; ALCOHOLS, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21672163] Funding Source: Medline; Natural Science Foundation of Zhejiang Province for Distinguished Young Scholars [LR14B020002] Funding Source: Medline. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Liu, HC; Liu, JP; Cheng, XK; Jia, XJ; Yu, L; Xu, Q. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether
Addition of DMSO is found to greatly accelerate the aqueous hydrolysis of organohalides to alcohols, providing a neutral, more efficient, milder and more economic process. Mechanistic studies using O-18-DMSO and O-18-H2O showed that, contrary to the opinion that DMSO works as a dipolar solvent to enhance water’s nucleophilicity, the accelerating effect comes from a complete oxygen transfer from DMSO to organohalides through generation of ROS+Me2.X- salts through C-O bond formation, followed by O-S bond disassociative hydrolysis of ROS+Me2.X- with water. This method is applicable to a wide range of organohalides and thus may have potential for practical industrial application, owing to easy recovery of DMSO from the H2O/DMSO mixture by regular vacuum rectification.
Category: ethers-buliding-blocks. About Benzyl ether, If you have any questions, you can contact Liu, HC; Liu, JP; Cheng, XK; Jia, XJ; Yu, L; Xu, Q or concate me.
Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem