Sun, Kai published the artcileA general electron donor-acceptor complex for photoactivation of arenes via thianthrenation, SDS of cas: 91-16-7, the publication is Chemical Science (2022), 13(19), 5659-5666, database is CAplus and MEDLINE.
General photoactivation of electron donor-acceptor (EDA) complexes between arylsulfonium salts and 1,4-diazabicyclo[2.2.2]octane with visible light or natural sunlight was discovered. This practical and efficient mode enabled the production of aryl radicals under mild conditions, providing an unrealized opportunity for two-step para-selective C-H functionalization of complex arenes. The novel mode for generating aryl radicals via an EDA complex was well supported by UV-vis absorbance measurements, NMR titration experiments, and d. functional theory (DFT) calculations The method was applied to the regio- and stereo-selective arylation of various N-heterocycles under mild conditions, yielding an assembly of challengingly linked heteroaryl-(hetero)aryl products.
Chemical Science published new progress about 91-16-7. 91-16-7 belongs to ethers-buliding-blocks, auxiliary class Benzene,Ether,Inhibitor,Inhibitor,Inhibitor, name is 1,2-Dimethoxybenzene, and the molecular formula is C12H14BNO2, SDS of cas: 91-16-7.
Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem