Xu, Ming-xian published the artcileOne-pot synthesis of dimethyl carbonate in supercritical CO2, COA of Formula: C4H10O2, the publication is Gaoxiao Huaxue Gongcheng Xuebao (2014), 28(6), 1334-1339, database is CAplus.
The synthesis of di-Me carbonate (DMC) was studied with carbon dioxide, propylene oxide (PO) and methanol as raw material, potassium methoxide (CH3OK) as catalyst, calcium chloride (CaCl2) as dehydration agent. The effects of factors such as the volume ratio of methanol and PO (1-12), stirring speed (0-500 r·min-1), pressure (5.0-10.0 MPa), temperature (110-190°) and reaction time (0.25-3.0 h) on the synthesis of DMC were investigated. A possible reaction mechanism of one-pot synthesis of di-Me carbonate on CH3OK was proposed. The results show that the conversion of methanol and the yield of DMC could reach 22.0% and 45.5% resp. under optimized reaction conditions (VCH3OH : VPO = 10 : 1, stirring speed 300 r·min-1, pressure 7.0 MPa, temperature 140°, reaction time 1 h).
Gaoxiao Huaxue Gongcheng Xuebao published new progress about 1589-47-5. 1589-47-5 belongs to ethers-buliding-blocks, auxiliary class Aliphatic hydrocarbon chain,Alcohol,Ether, name is 2-Methoxypropan-1-ol, and the molecular formula is C4H6F3NOS, COA of Formula: C4H10O2.
Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem