Breno, Kerry L. published the artcileAqueous Phase Organometallic Catalysis Using (MeCp)2Mo(OH)(H2O)+. Intramolecular Attack of Hydroxide on Organic Substrates, Quality Control of 16332-06-2, the publication is Organometallics (2004), 23(8), 1738-1746, database is CAplus.
The hydrolysis of esters and difunctional ethers catalyzed by Cp’2Mo(OH)(H2O)+ (1) (Cp’ = η5-C5H4CH3) and the stoichiometric oxidation of CO to CO2 in the presence of 1 are described. These reactions, combined with the previously reported nitrile hydrations and phosphate esters hydrolyzes catalyzed by 1, demonstrate that 1 is an effective homogeneous catalyst for hydration, hydrolysis, and oxidation reactions in aqueous solution under mild conditions (pH ∼ 7, ∼ 80°). Each reaction is proposed to proceed by intramol. attack of the hydroxide ligand on a bound substrate. The intramol. nature of the reaction is supported by the ester hydrolysis activation parameters (ΔH⧧ = 5.9 ± 0.7 kcal/mol and ΔS⧧ = -48 ± 9 eu), the lack of H/D exchange, and the significant increase (106-108) in the rate of hydrolysis over uncatalyzed hydrolysis.
Organometallics published new progress about 16332-06-2. 16332-06-2 belongs to ethers-buliding-blocks, auxiliary class Amine,Aliphatic hydrocarbon chain,Amide,Ether, name is 2-Methoxyacetamide, and the molecular formula is C3H7NO2, Quality Control of 16332-06-2.
Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem