Roush, W. R.’s team published research in Tetrahedron Letters in 41 | CAS: 99438-28-5

Tetrahedron Letters published new progress about 99438-28-5. 99438-28-5 belongs to ethers-buliding-blocks, auxiliary class Chiral,Aliphatic cyclic hydrocarbon, name is (+)-B-Methoxydiisopinocampheylborane, and the molecular formula is C21H37BO, COA of Formula: C21H37BO.

Roush, W. R. published the artcile[(E)-γ-(Dimethylphenylsilyl)allyl]diisopinocampheylborane: a highly enantioselective reagent for the synthesis of anti-β-hydroxyallylsilanes, COA of Formula: C21H37BO, the publication is Tetrahedron Letters (2000), 41(49), 9413-9417, database is CAplus.

Anti-β-Hydroxyallylsilanes, MeCH(OH)CH(CH:CH2)SiMe2Ph for example, were prepared with 88-95% e.e. via asym. allylboration reactions of aldehydes, MeCHO for example, with [(E)-γ-(dimethylphenylsilyl)allyl]diisopinocampheylborane.

Tetrahedron Letters published new progress about 99438-28-5. 99438-28-5 belongs to ethers-buliding-blocks, auxiliary class Chiral,Aliphatic cyclic hydrocarbon, name is (+)-B-Methoxydiisopinocampheylborane, and the molecular formula is C21H37BO, COA of Formula: C21H37BO.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem