Goh, Jeffrey published the artcileCatalyst-free C-N bond formation under biocompatible reaction conditions, Formula: C8H11NO, the publication is Green Chemistry (2022), 24(8), 3321-3325, database is CAplus.
A C-N bond formation reaction under biocompatible conditions for the amination of allenic ketone compounds to access a diversity of β-keto enamines R1C(O)HC=CMeNHR2 [R1 = Ph, cyclopentyl, 4-MeOC6H4, etc.; R2 = Ph, cyclohexyl, Bn, etc.] was developed. This reaction was atom economical, green and highly regioselective and works well with many structurally important amines such as amino sugar and amino acid esters or peptides. A wide array of β-keto enamines R1C(O)HC=CMeNHR2 was obtained in modest to excellent yields with wide functional group tolerance using this protocol. A gram-scale synthesis of an anti-microbial agent was also realized using this strategy under green reaction conditions.
Green Chemistry published new progress about 6850-57-3. 6850-57-3 belongs to ethers-buliding-blocks, auxiliary class Amine,Benzene,Ether, name is (2-Methoxyphenyl)methanamine, and the molecular formula is C8H11NO, Formula: C8H11NO.
Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem