Sahin, Neslihan published the artcileNovel N-Alkylbenzimidazole-Ruthenium (II) complexes: Synthesis and catalytic activity of N-alkylating reaction under solvent-free medium, Synthetic Route of 52818-63-0, the publication is Applied Organometallic Chemistry (2019), 33(2), n/a, database is CAplus.
In this article, direct N-alkylation reactions of amines with alcs. derivatives have been investigated. For this purpose, a new series ruthenium (II) complexes bearing N-coordinated benzimidazole complexes with have been synthesized and fully characterized by elemental anal., FT-IR, 1H NMR and, 13C NMR spectroscopies. Addnl., the structures of the complexes have been confirmed by X-ray crystallog. Although the N-alkylating reaction is usually performed in toluene, the catalytic study of complexes has carried out no addnl. solvent and alc. acted both as solvent and reactant of alkylating by using a little excess of alcs. Surprisingly, conversion and selectivity of amine product for alkylation reaction have been seen high in medium solvent-free relative to in toluene.
Applied Organometallic Chemistry published new progress about 52818-63-0. 52818-63-0 belongs to ethers-buliding-blocks, auxiliary class Pyridine,Amine,Benzene,Ether, name is N-(4-Methoxybenzyl)pyridin-2-amine, and the molecular formula is C13H14N2O, Synthetic Route of 52818-63-0.
Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem