Sunagawa, Genshun published the artcileSynthesis of organic bases. VI. Synthesis of thonzylamine, HPLC of Formula: 52818-63-0, the publication is Takamine Kenkyusho Nenpo (1952), 36-9, database is CAplus.
cf. C.A. 48, 8777d. Thonzylamine (I) was prepared by the following 3 routes: (a) Heating anisaldehyde, 2-aminopyridine (Ia), and HCO2H gave 2-(p-methoxybenzylamino)pyridine (II), m. 108-9°, which, converted to the Na salt and treated with Me2NCH2CH2Cl (III), gave 96% I, b3 191-3°. (b) 2-Formylaminopyridine and anisaldehyde in ethylene glycol gave 73.1% II which with III gave I, (lower yield than method a). (c) Ia and III in the presence of NaNH2 yielded 29.4% N,N-Dimethyl-N’-(2-pyrimidyl)ethylenediamine, b3 90-5°, which was converted to the N’-formyl compound, b6 121-5° (96.4% yield), and finally heated with anisaldehyde in glycol to give I.
Takamine Kenkyusho Nenpo published new progress about 52818-63-0. 52818-63-0 belongs to ethers-buliding-blocks, auxiliary class Pyridine,Amine,Benzene,Ether, name is N-(4-Methoxybenzyl)pyridin-2-amine, and the molecular formula is C3H6O2, HPLC of Formula: 52818-63-0.
Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem